Photonic Cavity Effects for Enhanced Efficiency in Layered Perovskite-Based Light-Emitting Diodes

Layered architectures for light-emitting diodes (LEDs) are the standard approach for solution-processable materials such as metal-halide perovskites. Upon designing the composition and thicknesses of the layers forming the LED, the primary focus is typically on the optimization of charge injection and balance. However, this approach only considers the process until electrons and holes recombine to generate photons, while for achieving optimized LED performance, the generated light must also be efficiently outcoupled. Our work focuses on the latter aspect. We assume efficient photon generation and analyze the effects of the geometrical configuration together with the dipole orientation, mimicking the light emission, on the main characteristics defining the LED, such as the Purcell effect and the outcoupling efficiency. We find that in-plane dipoles result in significantly increased outcoupling efficiency. Furthermore, the mismatch in refractive index among the layers and their different thicknesses can be tuned to maximize the Purcell effect and minimize internal losses. The combined optimization of dipole orientation and layer thicknesses can improve the efficiency of the LED up to a factor 10, hence highlighting the importance of considering also the photonic properties of the LED structures if the objective is to maximize the LED performance.

Modeling tilt noise caused by atmospheric processes at long periods for several horizontal seismometers at BFO - a reprise

Summary Tilting of the ground due to loading by the variable atmosphere is known to corrupt very long-period horizontal seismic records (below 10 mHz) even at the quietest stations. At BFO (Black Forest Observatory, SW-Germany) the opportunity arose to study these disturbances on a variety of simultaneously operated state-of-the-art broadband sensors. A series of time windows with clear atmospherically caused effects was selected and attempts were made to model these “signals” in a deterministic way. This was done by simultaneously least squares fitting the locally recorded barometric pressure and its Hilbert transform to the ground accelerations in a bandpass between 100 and 3600 s periods. Variance reductions of up to 97 per cent were obtained. We show our results by combining the “specific pressure induced accelerations” for the two horizontal components of the same sensor as vectors on a horizontal plane, one for direct pressure and one for its Hilbert transform. It turned out that at BFO the direct pressure effects are large, strongly position dependent, and largely independent of atmospheric events for instruments installed on piers, while three posthole sensors are only slightly affected. The infamous “cavity effects” are invoked to be responsible for these large effects on the pier sensors. On the other hand, in the majority of cases all sensors showed very similar magnitudes and directions for the vectors obtained for the regression with the Hilbert transform, but highly variable from event to event especially in direction. Therefore this direction most certainly has to do with the gradient of the pressure field moving over the station which causes a larger scale deformation of the crust. The observations are very consistent with these two fundamental mechanisms of how fluctuations of atmospheric surface pressure causes tilt noise. The results provide a sound basis for further improvements of the models for these mechanisms. The methods used here can already help to reduce atmospherically induced noise in long period horizontal seismic records .

Arrays of Plasmonic Nanostructures for Absorption Enhancement in Perovskite Thin Films

We report optical characterization and theoretical simulation of plasmon enhanced methylammonium lead iodide (MAPbI 3 ) thin-film perovskite solar cells. Specifically, various nanohole (NH) and nanodisk (ND) arrays are fabricated on gold/MAPbI 3 interfaces. Significant absorption enhancement is observed experimentally in 75 nm and 110 nm-thick perovskite films. As a result of increased light scattering by plasmonic concentrators, the original Fabry–Pérot thin-film cavity effects are suppressed in specific structures. However, thanks to field enhancement caused by plasmonic resonances and in-plane interference of propagating surface plasmon polaritons, the calculated overall power conversion efficiency (PCE) of the solar cell is expected to increase by up to 45.5%, compared to its flat counterpart. The role of different geometry parameters of the nanostructure arrays is further investigated using three dimensional (3D) finite-difference time-domain (FDTD) simulations, which makes it possible to identify the physical origin of the absorption enhancement as a function of wavelength and design parameters. These findings demonstrate the potential of plasmonic nanostructures in further enhancing the performance of photovoltaic devices based on thin-film perovskites.