The size of firn crystals as a function of age has been investigated in thin sections to a depth of 49 m at the South Pole. Grain cross-sections increased in size from 0.24 mm2 at 0.1 m depth to 0.63 mm2 at 10 m. Crystals, as distinct from grains, increased in size from 0.18 to 0.43 mm2 over the same interval, implying that grains are generally composed of just one or two crystals rather than several as is frequently contended. The mean crystal cross-section increased linearly with the age of the firn at a rate of 0.0006 mm2 year−1; in 388 year old firn at 49 m the crystal size measured 0.63 mm2. Analysis of crystal-growth data from other locations in Antarctica and Greenland also revealed a strong linear relationship between the mean cross-sectional arcas (D2) of crystals (in mm2) and their ages in years (t), i.e. . The fact that the temperature dependence of the crystal growth rate K can be expressed very satisfactorily in an equation of the form K = K0 exp (E/RT) confirms predictions that crystal growth in firn is essentially analogous to grain growth in metallic and ceramic sinters. An extrapolation of available data indicates that crystal growth rates in dry firn could be expected to vary by two orders of magnitude (0.0003 to 0.03 mm2 year−1) over the temperature range −60° to −15°C. A method of utilizing crystal growth-mean annual temperature data to determine accumulation rates in snow is demonstrated.
Recent Results in the Crystal Growth of GaN at High N2 Pressure