Anisotropy in the Far Infrared Conductivity of Magnetically-Oriented YBa2Cu3O7-δ Between 50–300K

1989 ◽  
Vol 169 ◽  
Author(s):  
F. Lu ◽  
C.H. Perry ◽  
K. Chen ◽  
R.S. Markiewicz

AbstractThe far infrared reflectance of magnetically-oriented YBa2Cu3O7-δ has been measured from 30–600 cm-1 over the temperature range 300–50 K. A strongly temperature dependent optical anisotropy is observed in this region. The low energy Ē⊥c spectrum displays a high reflectivity associated with the dominant free carrier contribution. Peaks corresponding to phonons are present in the spectrum associated with the direction perpendicular to the high conductivity Cu - O planes. However the reflectivity for Ē∥c is not characteristic of an insulating material but rather shows a metallic-like rise with decreasing photon energy. The plasma frequencies for both polarizations, obtained from fits to the reflectance data, decrease with decreasing temperature. There is some evidence in the parallel conductivity data taken below Tc, for the onset of an energy gap that is substantially smaller than that deduced for the in-plane value; such a result suggests a large gap anisotropy. The parameters describing a number of low frequency phonon modes for Ē∥c have been determined from fits to the R∥ data. Most show a slight softening as Tc is traversed.

Author(s):  
Валерий Александрович Рыжов

На терагерцовых частотах либрационно-колебательное движение связано с диэлектрической релаксацией в неупорядоченных твердых телах с водородными связями. Взаимодействие между этими процессами ещё мало изучено, особенно при температурах ниже температуры стеклования, что особенно существенно для молекулярной подвижности в полимерах. Изучены полимеры с водородными связями (полиамид-6 и поливинилхлорид) при температурах от 90 до 4000К в диапазоне 0,25 - 4 ТГц с использованием дальней ИК-спектроскопии. Три общих особенностей наблюдались в спектре диэлектрических потерь, Ɛ"(ν):(а) при температурах значительно ниже стеклования (T) эти потери представлены низкочастотным крылом пика поглощения, обусловленного либрацией мономерных звеньев полимеров. (б) При 0.7 T < T < T наблюдаются дополнительные температурно-зависимые потери, которые могут быть связаны с проявлением вторичных релаксационных процессов. (с) При температурах выше T преобладающим вкладом в терагерцовые потери становятся первичные процессы α-релаксации. Полученные результаты показывают, что эволюция терагерцовых потерь с температурой вызвана изменением структуры водородных связей, которое, по-видимому, является универсальным для систем с подобными межмолекулярными взаимодействиями At terahertz frequencies, torsional-vibrational motion is associated with dielectric relaxation in disordered solids with hydrogen bonds. The interaction between these processes has not been studied much, especially at temperatures below the glass transition temperature, which is especially important for molecular mobility in polymers. Polymers with hydrogen bonds (polyamide-6 and polyvinyl chloride) were studied at temperatures from 90 to 4000 K in the range 0.25 - 4 THz using far-infrared spectroscopy. Three common features were observed in the spectrum of dielectric losses, Ɛ"(ν):(А)at temperatures well below glass transition (T), these losses are represented by the low-frequency wing of the absorption peak due to libration of the monomer units of the polymers. (B) At 0.7 T < T < T , additional temperature-dependent losses are observed, which may be associated with the manifestation of secondary relaxation processes. (C) At temperatures above T, the primary relaxation processes become the dominant contribution to terahertz losses. The results show that the evolution of terahertz losses with temperature is caused by a change in the structure of hydrogen bonds, which, apparently, is universal for systems with similar intermolecular interactions.


2017 ◽  
Vol 111 (20) ◽  
pp. 201903 ◽  
Author(s):  
Daming Zhao ◽  
Jonathan M. Skelton ◽  
Hongwei Hu ◽  
Chan La-o-vorakiat ◽  
Jian-Xin Zhu ◽  
...  

1973 ◽  
Vol 27 (1) ◽  
pp. 22-26 ◽  
Author(s):  
S. M. Craven ◽  
F. F. Bentley ◽  
D. F. Pensenstadler

The low frequency infrared spectra from 450 to 75 cm−1 of seven oximes and five aldoximes have been recorded for pure samples and for dilute solutions in cyclohexane. An intense characteristic band is present in the solution spectra at 367 ± 10 cm−1. This characteristic band shifts to 275 ± 10 cm−1 in the spectra of the OD compounds. The 367 ± 10 cm−1 and 275 ± 10 cm−1 bands are assigned to OH and OD torsional vibrations. A comparison of the solution spectra with spectra of the solid samples indicated that the OH … N hydrogen bond stretch of oximes and aldoximes occurs in 300 to 200 cm−1 region. Strong bands also are present in 140 to 100 cm−1 region which are due to OH … N bending modes or perhaps lattice vibrations.


Author(s):  
C. Ballesteros ◽  
J. A. Garci´a ◽  
M. I. Orti´z ◽  
R. Rodri´guez ◽  
M. Varela

A detailed tribological characterization of low-energy, nitrogen implanted V5 at. %Ti alloy is presented. Samples were nitrogen-implanted at an accelerating voltage of 1.2 kV and 1 mA/cm2, up to a dose of 1E19 ions/cm2. The tribological properties of the alloys: microhardness, friction coefficient and wear resistance, have improved after ion implantation and this improvement increases as the implantation temperature increases. The microstructure of the alloys were analysed by transmission electron microscopy. A direct correlation between structural modifications of the nitrogen implanted layer and the improvement in their tribological properties is obtained. For samples implanted at 848 K a nanocomposite layer where the reinforcement particles are TiN precipitates forms. TiN precipitation appears as the responsible of the improvement in the tribological properties.


1992 ◽  
Vol 69 (18) ◽  
pp. 2666-2669 ◽  
Author(s):  
S. Huant ◽  
J. B. Robert ◽  
G. Chouteau ◽  
P. Bernier ◽  
C. Fabre ◽  
...  

2009 ◽  
Vol 479 (4-6) ◽  
pp. 211-217 ◽  
Author(s):  
Masae Takahashi ◽  
Yoshiyuki Kawazoe ◽  
Yoichi Ishikawa ◽  
Hiromasa Ito

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