Phonon Dispersion in Suspensions of Hard Sphere Colloids*

1990 ◽  
Vol 195 ◽  
Author(s):  
D.A. Weitz ◽  
J. Liu ◽  
L. Ye ◽  
Ping Sheng

ABSTRACTWe use Brillouin scattering to measure the dispersion of the propagating acoustic modes in a suspension of hard sphere colloids. We find two distinct longitudinal modes when the sound wavelength becomes comparable to the sphere diameter. The higher frequency mode has a velocity intermediate between those of the pure solid and the pure liquid phases, and its velocity increases with increasing volume fraction, ø. The lower frequency mode has a velocity less than the velocities in either the pure fluid or pure solid phases, and its velocity decreases with increasing ø. We interpret the higher frequency mode as a compressional wave which propagates through both the solid and the fluid, as expected for a composite medium. The lower frequency mode has not been observed before, and is interpreted as a surface acoustic mode, which propagates between adjacent spheres through a decaying portion of the excitation in the fluid.

BIBECHANA ◽  
2016 ◽  
Vol 14 ◽  
pp. 16-29
Author(s):  
B K Singh ◽  
Sudhir Singh ◽  
Golak Kumar Mandal ◽  
Dhiraj Kumar Singh

A semi-empirical approach has been considered to study the temperature dependence of entropy of mixing, (ΔsM), for various alkai-alkali alloys using hard-sphere model. The most important physical parameters occurring here is the hard-sphere diameter (σ) and the packing fraction (η). For pure liquid metals, this is usually determined empirically from the observed entropy as a function of temperature which in turn are utilised to compute ΔSM for Na-K, K-Rb, Na-Rb, NaCs, Rb-Cs and K-Cs alloys as a function of concentration at five different temperature ranging from 400°K-800°K. The study reveals that entropy of mixing for Na-K, Na-Rb and K-Rb systems decreases with increasing temperature. But the result for Cs-based alloys exhibit a mixed behaviour.BIBECHANA 14 (2017) 16-29


Author(s):  
Luis San Andrés ◽  
Xueliang Lu

Wet gas compression systems and multiphase pumps are enabling technologies for the deep sea oil and gas industry. This extreme environment determines both machine types have to handle mixtures with a gas in liquid volume fraction (GVF) varying over a wide range (0 to 1). The gas (or liquid) content affects the system pumping (or compression) efficiency and reliability, and places a penalty in leakage and rotordynamic performance in secondary flow components, namely seals. In 2015, tests were conducted with a short length smooth surface annular seal (L/D = 0.36, radial clearance = 0.127 mm) operating with an oil in air mixture whose liquid volume fraction (LVF) varied to 4%. The test results with a stationary journal show the dramatic effect of a few droplets of liquid on the production of large damping coefficients. This paper presents further measurements and predictions of leakage, drag power, and rotordynamic force coefficients conducted with the same test seal and a rotating journal. The seal is supplied with a mixture (air in ISO VG 10 oil), varying from a pure liquid to an inlet GVF = 0.9 (mostly gas), a typical range in multiphase pumps. For operation with a supply pressure (Ps) up to 3.5 bar (a), discharge pressure (Pa) = 1 bar (a), and various shaft speed (Ω) to 3.5 krpm (ΩR = 23.3 m/s), the flow is laminar with either a pure oil or a mixture. As the inlet GVF increases to 0.9 the mass flow rate and drag power decrease monotonically by 25% and 85% when compared to the pure liquid case, respectively. For operation with Ps = 2.5 bar (a) and Ω to 3.5 krpm, dynamic load tests with frequency 0 < ω < 110 Hz are conducted to procure rotordynamic force coefficients. A direct stiffness (K), an added mass (M) and a viscous damping coefficient (C) represent well the seal lubricated with a pure oil. For tests with a mixture (GVFmax = 0.9), the seal dynamic complex stiffness Re(H) increases with whirl frequency (ω); that is, Re(H) differs from (K-ω2M). Both the seal cross coupled stiffnesses (KXY and −KYX) and direct damping coefficients (CXX and CYY) decrease by approximately 75% as the inlet GVF increases to 0.9. The finding reveals that the frequency at which the effective damping coefficient (CXXeff = CXX-KXY/ω) changes from negative to positive (i.e., a crossover frequency) drops from 50% of the rotor speed (ω = 1/2 Ω) for a seal with pure oil to a lesser magnitude for operation with a mixture. Predictions for leakage and drag power based on a homogeneous bulk flow model match well the test data for operation with inlet GVF up to 0.9. Predicted force coefficients correlate well with the test data for mixtures with GVF up to 0.6. For a mixture with a larger GVF, the model under predicts the direct damping coefficients by as much as 40%. The tests also reveal the appearance of a self-excited seal motion with a low frequency; its amplitude and broad band frequency (centered at around ∼12 Hz) persist and increase as the gas content in the mixture increase. The test results show that an accurate quantification of wet seals dynamic force response is necessary for the design of robust subsea flow assurance systems.


2019 ◽  
Vol 104 (11) ◽  
pp. 1650-1655
Author(s):  
Wei Wei ◽  
Xinyang Li ◽  
Ningyu Sun ◽  
Sergey N. Tkachev ◽  
Zhu Mao

Abstract In this study, we have determined the combined effect of pressure and temperature on the compressional-wave velocity (VP) of Ne up to 53 GPa and 1100 K using Brillouin scattering in externally heated diamond-anvil cells. The phase transition from the supercritical fluid to solid phase was observed to cause a 10.5–11% jump in VP, and the magnitude in the VP contrast across the phase transition increases with temperature. In addition, we have observed an abnormal reduced increase rate of VP with pressure in the supercritical Ne fluid at both 800 and 1100 K before the transition to the solid phase. VP of the solid Ne exhibits a nonlinear increase with pressure at all the investigated temperatures. The elevating temperature was noted to cause an apparent reduction in VP, yet the reduction in VP caused by increasing temperature dramatically decreases at higher pressures. At 20 GPa, increasing temperature by 100 K can lower the VP of Ne by 2.4%. Yet elevating temperature by 100 K can only reduce the VP by 0.4% at 50 GPa. We further compare VP of Ne to that of other rare gases, including Ar, Kr, and Xe. At 300 K, VP of Ne shows a stronger dependence on pressure than both Kr and Xe. Moreover, increasing temperature can produce a greater reduction in VP of Ne than that of Ar below 50 GPa. Our measured VP of Ne is also useful for understanding the velocity structure of giant planets, such as Jupiter.


1980 ◽  
Vol 35 (4) ◽  
pp. 412-414
Author(s):  
K. N. Swamy ◽  
P. C. Wankhede

Abstract The optimised cluster theory of Andersen and Chandler has been applied to calculate the radial distribution functions of a triangular well fluid with the width a the hard sphere diameter The results agree well with Monte Carlo Calculations of Card and Walkley.


1987 ◽  
Vol 65 (9) ◽  
pp. 2198-2202 ◽  
Author(s):  
María Asunción Gallardo ◽  
José María Melendo ◽  
José Santiago Urieta ◽  
Celso Gutierrez Losa

Solubility measurements of several non-polar gases (He, Ne, Ar, Kr, Xe, H2, D2, N2, O2, C2H4, C2H6, CF4, SF6, andCO2) in cyclohexanone at 273.15 to 303.15 K and a partial pressure of gas of 101.32 kPa, are reported. Gibbs energy, enthalpy, and entropy of solution at 298.15 K and 101.32 kPa partial pressure of gas were evaluated. Effective hard-sphere diameter temperature dependence has been studied and its effect on the calculated SPT (Scaled Particle Theory) solubilities, and enthalpies and entropies of solution was also examined.


1989 ◽  
Vol 177 ◽  
Author(s):  
L. Ye ◽  
D. A. Weitz ◽  
Ping Sheng ◽  
J. S. Huang

ABSTRACTWe study the acoustic properties of AOT micelles and microemulsions by measuring the velocity of sound as a function of droplet volume fraction and of frequency, using Brillouin scattering and ultrasonic techniques. These weakly attractive interparticle interactions lead to the formation of short–lived networks of droplets, which can support shear and result in a pronounced increase in the speed of sound at high frequencies. These networks do not persist for sufficiently long times to affect the sound velocity at lower frequencies. The increased rigidity due to the networks exhibits a percolation behavior with volume fraction, while the frequency dependence of the interactions depends on hydrocarbon chain length of the solvent. Increasing the water concentration results in an increase in interaction energy, but a decrease in the intrinsic droplet rigidity, which affects the magnitude and frequency dependence of the contribution of the microemulsion networks to the elastic constant of the suspension. A consistent picture of the viscoelastic behavior of these suspensions is obtained.


Author(s):  
Sahand Pirouzpanah ◽  
Sujan Reddy Gudigopuram ◽  
Gerald L. Morrison

Electrical Submersible Pumps (ESPs) are used in upstream petroleum industry for pumping liquid-gas mixtures. The presence of gas in the flow reduces the efficiency of ESPs. To investigate the effect of gas in the flow medium, Electrical Resistance Tomography (ERT) is performed on the two diffuser stages in a three-stage ESP which was manufactured by Baker Hughes Company. In an ERT system, the relative conductivity of the two-phase fluid mixture in comparison with the conductivity of pure liquid is measured which is used to obtain the Gas Volume Fraction (GVF) and mixture concentration. The measured GVF and concentration is used to characterize the flow for different flow rates of water and air, inlet pressures and rotating speeds.


Sign in / Sign up

Export Citation Format

Share Document