Electrical Properties of Coevaporated CuInS2 Films by in-situ Conductivity Measurements

1996 ◽  
Vol 426 ◽  
Author(s):  
R. Scheer ◽  
M. Alt ◽  
I. Luck ◽  
R. Schieck ◽  
H. J. Lewerenz

AbstractThe conductivity σ of CuInS2 films grown by coevaporation is investigated by in-situ measurements during the deposition and ex-situ measurements. During the controlled cool-down period of the grown films, σ vs l/T data are obtained for films with Cu-rich and In-rich composition. Furthermore, first experiments on the effect of extrinsic dopants such as P, N, and Na on the conductivity of In-rich films are reported.

2018 ◽  
Vol 165 (10) ◽  
pp. F883-F890
Author(s):  
Hyun-Seok Cho ◽  
Won-Chul Cho ◽  
J. W. Van Zee ◽  
Chang-Hee Kim

2021 ◽  
Author(s):  
Amanda T. Nylund ◽  
Rickard Bensow ◽  
Mattias Liefvendahl ◽  
Arash Eslamdoost ◽  
Anders Tengberg ◽  
...  

<p>This interdisciplinary study with implications for fate and transport of pollutants from shipping, investigates the previously overlooked phenomenon of ship induced mixing. When a ship moves through water, the hull and propeller induce a long-lasting turbulent wake. Natural waters are usually stratified, and the stratification influences both the vertical and horizontal extent of the wake. The altered turbulent regime in shipping lanes governs the distribution of discharged pollutants, e.g. PAHs, metals, nutrients and non-indigenous species. The ship related pollutant load follows the trend in volumes of maritime trade, which has almost tripled since the 1980s. In heavily trafficked areas there may be one ship passage every ten minutes; today shipping constitutes a significant source of pollution.</p><p>To understand the environmental impact of shipping related pollutants, it is essential to know their fate following regional scale transport. However, previous modelling efforts assuming discharge at the surface will not adequately reflect the input values in the regional models. Therefore, it is urgent to bridge the gaps between the spatiotemporal scales from high-resolution numerical modeling of the flow hydrodynamics around the ship, mixing processes and interaction of the ship and wake with stratification, and parameterization in regional oceanographic modeling. Here this knowledge gap is addressed by combining an array of methods; in situ measurements, remote sensing and numerical flow modeling.</p><p>A bottom-mounted Acoustic Doppler Current Profiler was placed under a ship lane, for <em>in-situ</em> measurements of the vertical and temporal expansion of turbulent wakes. In addition, <em>ex-situ</em> measurements with Landsat 8 Thermal Infrared Sensor were used to estimate the longevity and spatial extent of the thermal signal from ship wakes. The computational modelling was conducted using well resolved 3D RANS modelling for the hull and the near wake (up to five ship lengths aft), a method typically used for the near wake behaviour in analysing the propulsion system. As this is not feasible to use for a far wake analysis, the predicted wake is then used as input for a 2D+time modelling for the sustained wake up to 30min after the ship passage. These results, both from measurements and numerical models, are then combined to analyse how ship-induced turbulence influence at what depth discharged pollutants will be found.</p><p>This first step to cover the mesoscales of the turbulent ship wake is necessary to assess the impact of ship related pollution. In-situ measurements show median wake depth 13.5m (max 31.5m) and median longevity 10min (max 29min). Satellite data show median thermal wake signal 13.7km (max 62.5km). A detailed simulation model will only be possible to use for the first few 100m of the ship wake, but the coupling to a simplified 2D+time modelling shows a promising potential to bridge our understanding of the impact of the ship wake on the larger scales. Our model results indicate that the natural stratification affects the distribution and retention of pollutants in the wake region. The depth of discharge and the wake turbulence characteristics will in turn affect the fate and transport of pollutants on larger spatiotemporal scales.</p>


2020 ◽  
Author(s):  
Joao Pedro Veiga ◽  
Fernanda Carvalho ◽  
Hugo Aguas ◽  
Giampiero Montesperelli ◽  
Elissavet Kavoulaki ◽  
...  

<div> <p>The Minoan Palace of Knossos and the Venetian coastal fortress “Rocca a mare” (Koules), located in Heraklion, Crete, Greece, are two important monuments for the history of mankind particularly vulnerable to environmental conditions, since they are located in an island subjected to strong variations in humidity and, as in the case of the Venetian fortress, in direct contact with sea water. In this type of surrounding environment, the formation of salt efflorescence as well as various other soluble salts crusts is a common situation. They occur according to the existing solubilization and crystallization conditions and can happen either in exterior or interior areas of the monuments. Their presence may stimulate further degradation, either due to the chemical dissolution of the substrate materials or due to the mechanical actions created by the formation of crystals, which may result in the decay of the substrate.</p> <p>A set of samples from both monuments were analysed using various laboratory (ex-situ) analytical methods such as optical microscopy (OM), X-ray diffraction (XRD), Fourier Transform Infrared spectroscopy (FTIR), Raman spectroscopy and Laser-Induced Breakdown Spectroscopy (LIBS). In-situ measurements using portable Raman and LIBS instruments were also performed. The comparative results from ex-situ analysis and in-situ measurements will be presented with emphasis to the chemical composition of the crusts and their origin. Results indicate that observed stalactites and salt efflorescence are directly related to the type of supporting material and the conditions of the surrounding environment. In general, the formation of crusts and salts are due to processes of alteration of the supporting material while the high impact of sea salt on the formation of the efflorescence at the Venetian coastal fortress was also confirmed.</p> <p> </p> <p>[1] This work was supported by the European Union’s Framework Programme for Research and Innovation HORIZON 2020 under Grant Agreement 700395 project HERACLES.</p> <p>Acknowledgment to the Portuguese Foundation for Science and Technology (FCT) UID/EAT/00729/2013 and EAT/00729-3 by FEDER funds through the COMPETE 2020 Programme and National Funds through FCT—Portuguese Foundation for Science and Technology under the project number POCI-01-0145-FEDER-007688, Reference UID/CTM/50025/2013 NOVA.ID.FCT, and the PhD Scholarship SFRH/BD/145308/2019.</p> </div>


1986 ◽  
Vol 43 (12) ◽  
pp. 2450-2454 ◽  
Author(s):  
Kenneth J. Hall ◽  
Thomas G. Northcote

Studies on seasonal changes in micro-stratification in meromictic Mahoney Lake required investigation of appropriate temperature–conductivity (T–C) adjustments and conductivity – dissolved solids relationships. In situ conductivity measurements were adjusted to 25 °C using a series of T–C relationships determined in the laboratory for Mahoney Lake water collected from different depths and at different times. Comparisons were made between conductivity determined from in situ measurements, conductivity in diluted water, and chemical analysis. Conductivity measurements were evaluated as estimates of the dissolved solids content of the water. T–C relationships were found to change considerably with depth and season in salt-stratified lakes, and errors as high as 15% could occur in Mahoney Lake unless several T–C plots were used to adjust field conductivity measurements to a constant temperature. Corrected in situ measurements underestimated conductivity as determined from the chemical composition. Diluted conductivity provided a more consistent estimate of dissolved solids content by eliminating most effects of ion–ion interactions upon ion mobility.


2011 ◽  
Vol 77 (6) ◽  
pp. 903-913 ◽  
Author(s):  
Hsueh-Jung Lu ◽  
Myounghee Kang ◽  
Hsing-Han Huang ◽  
Chi-Chang Lai ◽  
Long-Jin Wu

2021 ◽  
Vol 287 ◽  
pp. 112284
Author(s):  
Asish Saha ◽  
Subodh Chandra Pal ◽  
Alireza Arabameri ◽  
Indrajit Chowdhuri ◽  
Fatemeh Rezaie ◽  
...  

2020 ◽  
Vol 106 ◽  
pp. 104757
Author(s):  
Mohamad Raqif Mahat ◽  
Noor Azrina Talik ◽  
Mohd Nazri Abd Rahman ◽  
Mohd Afiq Anuar ◽  
Kamarul Allif ◽  
...  

2019 ◽  
Vol 216 (17) ◽  
pp. 1900298 ◽  
Author(s):  
Hadjer Ouaddah ◽  
Isabelle Périchaud ◽  
Damien Barakel ◽  
Olivier Palais ◽  
Marisa Di Sabatino ◽  
...  

Author(s):  
Michael H. Ramsey

Abstract In situ measurements are made without the removal of a physical sample and have many advantages over traditional ex situ measurements, made on a removed sample usually in a remote laboratory. The quality of ex situ measurements is usually expressed primarily in terms of their measurement uncertainty, including that arising during the sampling process. However, estimates of uncertainty for in situ measurement values have not usually included this uncertainty from sampling (UfS). It is argued that the making of an in situ measurement inevitably includes the taking of an ‘undisturbed sample’ that generates UfS, which should be included in the estimate of measurement uncertainty. Because undisturbed samples are not prepared or mixed, as is usual for removed samples, the heterogeneity of the analyte concentration in the sampling target is the primary source of UfS. Existing methods for estimating UfS for ex situ measurements can broadly be applied to in situ measurements. However, four extra challenges that limit the design and uptake of uncertainty estimation for in situ methods are identified, and possible solutions and actions required are discussed. Examples of in situ measurements considered include Pb in top soil by hand-held PXRF, 137Cs at a nuclear site by portable gamma-ray spectrometry, and bilirubin in new-born infants by hand-held reflectance photometry.


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