The Chemical Environment in Cement Matrices

1985 ◽  
Vol 50 ◽  
Author(s):  
M. J. Angus ◽  
F. P. Glasser

AbstractGeneral progress in modelling the behaviour of cement matrices and their interactions with wastes is reviewed in terms of appropriate model-ling concepts and their formulation in terms of parameters Which are susceptible to evaluation. The redox behaviour, particularly of slag-cement blends is shown to differ sharply from that of Portland cement matrices. Experimental methods of measuring Eh and poising capacities are described and the composition of pore fluids determined. Slag cements contain appreciable soluble Sn− species as well as S2O32− and SO42−

2017 ◽  
Vol 71 (1) ◽  
pp. 308-314
Author(s):  
Shingo YOSHIMOTO ◽  
Tatsuo SHINMI ◽  
Hiroyoshi KATO ◽  
Takatoshi MOTOORI

Buildings ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 10 ◽  
Author(s):  
Gökhan Kaplan ◽  
Hasbi Yaprak ◽  
Selçuk Memiş ◽  
Abdoslam Alnkaa

The use of mineral admixtures and industrial waste as a replacement for Portland cement is recognized widely for its energy efficiency along with reduced CO2 emissions. The use of materials such as fly ash, blast-furnace slag or limestone powder in concrete production makes this process a sustainable one. This study explored a number of hardened concrete properties, such as compressive strength, ultrasonic pulse velocity, dynamic elasticity modulus, water absorption and depth of penetration under varying curing conditions having produced concrete samples using Portland cement (PC), slag cement (SC) and limestone cement (LC). The samples were produced at 0.63 and 0.70 w/c (water/cement) ratios. Hardened concrete samples were then cured under three conditions, namely standard (W), open air (A) and sealed plastic bag (B). Although it was found that the early-age strength of slag cement was lower, it was improved significantly on 90th day. In terms of the effect of curing conditions on compressive strength, cure W offered the highest compressive strength, as expected, while cure A offered slightly lower compressive strength levels. An increase in the w/c ratio was found to have a negative impact on pozzolanic reactions, which resulted in poor hardened concrete properties. Furthermore, carbonation effect was found to have positive effects on some of the concrete properties, and it was observed to have improved the depth of water penetration. Moreover, it was possible to estimate the compressive strength with high precision using artificial neural networks (ANN). The values of the slopes of the regression lines for training, validating and testing datasets were 0.9881, 0.9885 and 0.9776, respectively. This indicates the high accuracy of the developed model as well as a good correlation between the predicted compressive strength values and the experimental (measured) ones.


2018 ◽  
Vol 203 ◽  
pp. 06004
Author(s):  
Ramesh Babu Chokkalingam ◽  
Manikandan Rajakannu

Literature review indicates that the usage of mineral admixtures (Fly ash, Ground Granulated Blast Furnace Slag, Silica Fume and Rice Husk ash) significantly improves the durability of concrete structures. Though it is reported as best alternative materials for improving durability of concrete structures, it was not very well received in government projects in India till 1990. However, for the past two decades, the usage of mineral admixtures directly or in the form of blended cement in concrete have significantly increased. Major concern of using mineral admixtures which was persisting among majority of the Ordinary Portland Cement (OPC) users are (i) delayed setting and strength gain, affecting the rate of construction, (ii) inconsistent in quality of mineral admixtures, mostly happened in site blending (iii) no established results pertains to Indian condition. In India, mostly the usage of mineral admixtures in concrete are used as a replacement for OPC, specifically in Ready Mix Concrete and site batching plant. However, few literature have reported that usage of mineral admixtures in the form of blended cement which is made at cement manufacturing plant by either intergrinding or blending will exhibits better concrete properties due to consistent quality and better quality control practice followed. Hence, the authors have undertaken this study to investigate the performance of mineral admixtures (only GGBFS) as direct replacement materials and as blended cement in concrete. In order to understand in detail, both as replacement of OPC and in the form of PSC, was undertaken on various cement content in concrete, i.e., 300, 320, 340, 360, 380 kg/m3. Results of compressive strength at various age of curing indicates that usage of GGBFS in the form of Portland Slag Cement (PSC) shows better performance than as a replacement of OPC in concrete.


2013 ◽  
Vol 753-755 ◽  
pp. 525-528
Author(s):  
Chun Mei Wang ◽  
Jing Wang ◽  
Li Rong Yang ◽  
Guang Dong Cao ◽  
Dan Yang Dong

The effects of amounts of the kiln dust-activated coal gangue on the setting time and compressive strength of high-content slag cement were investigated. The performance of sulphate resistance of cement with 30 wt.% kiln dust-activated coal gangue was evaluated. The results reveal that the setting time of high-content slag cement is prolonged. Appropriate kiln dust-activated coal gangue amounts can increase the compressive strength, while too much activated coal gangue (>30 wt.%) leads to the decrease in compressive strength. Cement with 10 wt.% kiln dust-activated coal gangue exhibits a good compressive strength. The performance of sulphate resistance of Portland cement with 30 wt.% kiln dust-activated coal gangue is distinctly enhanced, while that of high-content slag cement is improved to some extent.


2006 ◽  
Vol 26 (16) ◽  
pp. 3789-3797 ◽  
Author(s):  
I. Lecomte ◽  
C. Henrist ◽  
M. Liégeois ◽  
F. Maseri ◽  
A. Rulmont ◽  
...  

2013 ◽  
Vol 845 ◽  
pp. 814-818 ◽  
Author(s):  
Pouyan Rezvan ◽  
Amir Hossein Azadnia ◽  
Mohd Yusof Noordin ◽  
Seyed Navid Seyedi

Sustainability assessment of concrete manufacturing processes has recently received great attention among scholars and practitioners. While most of the studies on sustainability assessment of concrete manufacturing processes focus on economic and environmental issues, those which consider all three dimensions of sustainability (social, economic, and environmental) simultaneously are rather limited. In this study, a hybrid approach of fuzzy inference system and analytical hierarchy process (AHP) is proposed in order to evaluate the sustainability level of concrete manufacturing processes based on Life Cycle Assessment (LCA) principals. AHP is applied to weight the selected sustainability elements and sub elements. Afterward, fuzzy inference system is used to evaluate the sustainability level of concrete manufacturing processes. The practicality and applicability of the proposed approach are examined by conducting sustainability assessments of four different concrete manufacturing processes: (1) 100% of Portland cement (2) 35 % slag cement and 65% Portland cement (3) 50% slag cement and 50% Portland cement (4) 20% fly ash and 80% Portland cement. The results disclose the more sustainable concrete manufacturing process which is 50 % of Slag cement and 50% Portland cement.


2015 ◽  
Vol 824 ◽  
pp. 61-64
Author(s):  
Kirill Polozhiy ◽  
Jamal Akhter Siddique ◽  
Pavel Reiterman

In this article Portland-slag cement was step by step replaced with pozzolana (fine red-clay ceramics) in concrete. This is first step of research that is why the only measured characteristics were consistency of mixtures and compressive strength. There were designed four mixtures with increasing replacement of Portland cement by 10 % each (CR, C1, C2, C3) where complete activity of pozzolana was assumed. Mixtures C4, C5 and C6 were designed with respect to presumed just partial activity of the used pozzolana (set as 40 %). The water/cement coefficient was decided to be taken according to the consistence of the mortar.


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