The Optical and Morphological Properties of Fluorinated Polymer Dispersed Liquid Crystals

1999 ◽  
Vol 559 ◽  
Author(s):  
M.D. Schulte ◽  
S.J. Clarson ◽  
L.V. Natarajan ◽  
V.P. Tondiglia ◽  
T.J. Bunning

ABSTRACTPolymer dispersed liquid crystal (PDLC) films with a partially fluorinated polymer matrix were investigated. The optical and morphological properties of fluorinated PDLC's were different from non-fluorinated films. The incremental addition of a fluorine-substituted monofunctional methacrylate monomer to a pentaacrylate-based standard PDLC formulation resulted in significant improvement in contrast ratio. In addition, results suggest that fluorine decreased compatibility between the polymer and liquid crystal phases. Scanning electron microscopy (SEM) was employed to elucidate morphological differences between fluorinated host matrices and non-fluorinated control films.

2001 ◽  
Vol 709 ◽  
Author(s):  
Michael D. Schulte ◽  
Stephen J. Clarson ◽  
Lalgudi V. Natarajan ◽  
C. Allan Guymon ◽  
Timothy J. Bunning

ABSTRACTHolographic polymer dispersed liquid crystal (H-PDLC) films with partially fluorinated matrices were investigated. Electro-optical and morphological studies revealed that fluorinated composites were substantially different from non-fluorinated analogues. The addition of a fluorinated monofunctional acrylate monomer to a pentaacrylate-derived polymer matrix resulted in improved diffraction efficiency. These findings suggest that the partial fluorination of the host polymer decreases the compatibility between the matrix and liquid crystal phase. Morphological differences between fluorinated films and non-fluorinated control specimens were verified using low-voltage, high-resolution scanning electron microscopy (LVHRSEM).


Molecules ◽  
2020 ◽  
Vol 25 (23) ◽  
pp. 5510 ◽  
Author(s):  
Mohsin Hassan Saeed ◽  
Shuaifeng Zhang ◽  
Yaping Cao ◽  
Le Zhou ◽  
Junmei Hu ◽  
...  

Polymer dispersed liquid crystals (PDLCs) have kindled a spark of interest because of their unique characteristic of electrically controlled switching. However, some issues including high operating voltage, low contrast ratio and poor mechanical properties are hindering their practical applications. To overcome these drawbacks, some measures were taken such as molecular structure optimization of the monomers and liquid crystals, modification of PDLC and doping of nanoparticles and dyes. This review aims at detailing the recent advances in the process, preparations and applications of PDLCs over the past six years.


1996 ◽  
Vol 425 ◽  
Author(s):  
S. J. Chang ◽  
Y. C. Yin ◽  
C. M. Lin ◽  
A. Y. G. Fuh

AbstractPolymer dispersed liquid crystals ( PDLC ) are potentially useful as new types of display devices. By applying an electric field, one can switch the PDLC cell from a highly scattering opaque state to a transparent state. Normal PDLC cells consist of liquid crystal droplets, having sizes on the order of micrometers, embedded in a transparent polymer matrix. In this paper, we report the development of a new kind of PDLC cell with a distinct type of polymer morphology, teferred to as “reverse ” or “polymer ball ” type. The electro-optical behavior and the micro structure of the PDLC films were investigated by a He-Ne laser and the scanning electron microscopy ( SEA ) respectively.


2014 ◽  
Vol 2 (40) ◽  
pp. 8501-8506 ◽  
Author(s):  
Li Yu ◽  
Zhangxiang Cheng ◽  
Zhijiao Dong ◽  
Yihe Zhang ◽  
Haifeng Yu

Recyclable, fast and visible-light responsive polymer-dispersed liquid crystal/graphene oxide nanocomposite films were fabricated by solution casting and mechanical stretching.


2011 ◽  
Vol 181-182 ◽  
pp. 79-82
Author(s):  
Xing Fang Jiang ◽  
Shu Xin Wu

Polymer-dispersed liquid crystals are one kind of important devices. With a He-Ne laser and a photoelectric detector, we measured the driving-voltage dependent and viewing-angle dependent transmission for a polymer-dispersed liquid crystal device. Our results showed that the polymer-dispersed liquid crystal device worked at the driving voltage of 4 V and the effective viewing angle of about 65 degree.


2018 ◽  
Vol 6 (35) ◽  
pp. 9517-9522 ◽  
Author(s):  
Lijuan Liu ◽  
Xiaobo Kong ◽  
Qidong Wang ◽  
Yonggang Liu ◽  
Li Xuan

We report on the fabrication and characterization of a surface-emitting distributed feedback (DFB) organic semiconductor laser based on a holographic polymer dispersed liquid crystal (HPDLC) transmission grating.


2010 ◽  
Vol 428-429 ◽  
pp. 356-362
Author(s):  
Ji Hong Zheng ◽  
Ken Wen ◽  
Ling Juan Gu ◽  
Song Lin Zhuang

Micro/nanoscale liquid crystal (LC) droplets are dispersed within polymer matrix, known as polymer-dispersed liquid crystals (PDLCs). LC molecules can be reoriented under an applied voltage, which makes PDLC-based devices have wide applications in optical communications, integrated optics, and panel displays, etc. In this paper, we summarized our work on holographic PDLC (H-PDLC) devices including variable attenuators, dynamic gain equalizers and focus-switchable lenses. More importantly, a specially designed H-PDLC chopper array was demonstrated, which will be applied in the new-born frequency division multiplexed high-speed fluorescence confocal microscope system.


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