Long-Term Behavior of Bitumen Waste Form

1999 ◽  
Vol 608 ◽  
Author(s):  
I.A. Sobolev ◽  
A.S. Barinov ◽  
M.I. Ojovan ◽  
N.V. Ojovan ◽  
I.V. Startceva ◽  
...  
Keyword(s):  
Waste Form ◽  
Long Term Behavior

Natural Analogues: Their Application to the Prediction of the Long-Term Behavior of Nuclear Waste Forms

1986 ◽  
Vol 84 ◽  
Author(s):  
Rodney C. Ewing ◽  
Michael J. Jercinovic
Keyword(s):  
Nuclear Waste ◽  
Borosilicate Glass ◽  
Large Scale ◽  
Laboratory Data ◽  
Waste Form ◽  
Long Time ◽  
Natural Analogues ◽  
Long Term Behavior ◽  
Nuclear Waste Forms

AbstractOne of the unique and scientifically most difficult aspects of nuclear waste isolation is the extrapolation ofshot-term laboratory data (hours to years) to the long time periods (103-105 years) required by regulatory agencies for performance assessment. The direct verification of these extrapolations is not possible, but methods must be developed to demonstrate compliance with government regulations and to satisfy the lay public that there is a demonstrable and reasonable basis for accepting the long-term extrapolations. Natural analogues of both the repository environment (e.g. radionuclide migration at Oklo) and nuclear waste form behavior (e.g. alteration of basaltic glasses and radiation damage in minerals) have been used to demonstrate the long-term behavior of large scale geologic systems and, on a smaller scale, waste form durability. This paper reviews the use of natural analogues to predict the long-term behavior of nuclear waste form glasses. Particular emphasis is placed on the inherent limitations of any conclusions that are based on “proof” by analogy. An example -- corrosion of borosilicate glass -- is discussed in detail with specific attention to the proper and successful use of natural analogues (basaltic glass) in understanding the long-term corrosion behavior of borosilicate glass.

Mobilization/Retention of Radionuclides during Corrosion of High Burnup Spent Fuel and Backfill Materials in Salt Brines

2002 ◽  
Vol 757 ◽  
Author(s):  
Andreas Loida ◽  
Bernhard Kienzler ◽  
Horst Geckeis
Keyword(s):  
Near Field ◽  
Waste Form ◽  
Spent Fuel ◽  
The Matrix ◽  
Backfill Materials ◽  
Salt Brine ◽  
Solid Phases ◽  
Long Term Behavior ◽  
The Impact

ABSTRACTWith respect to the assessment of the long-term behavior of the waste form spent fuel it is of high importance to study the fuel alteration in contact with groundwater and near field materials. The aim of this work is to evaluate the impact of candidate backfill materials hydroxylapatite and magnetite on the overall corrosion behavior of this waste form in salt brine; both materials are used in corrosion tests together with spent fuel. The instant releases and the matrix dissolution rates appear to be similar in presence and in absence of any backfill material under study. However, Am,Np,Pu,U and Sr are retained at different ratios on the hydroxylapatite, on the magnetite and on the fuel sample, indicating possibly the formation of different radionuclide containing new solid phases.

scholarly journals Plutonium-Doped Monazite and Other Orthophosphates—Thermodynamics and Experimental Data on Long-Term Behavior

2021 ◽  
Vol 13 (3) ◽  
pp. 1203
Author(s):  
Polina Mikhailova ◽  
Boris Burakov ◽  
Nikolai Eremin ◽  
Alexei Averin ◽  
Andrey Shiryaev
Keyword(s):  
Current Data ◽  
Waste Form ◽  
Atmospheric Moisture ◽  
Gibbs Energies ◽  
Structural Types ◽  
Crystalline Crust ◽  
Acidic Compounds ◽  
Short Time ◽  
Long Term Behavior

The paper consists of two main parts: a microscopic and spectroscopic investigation of the single crystal of 17-year-old 238Pu-doped Eu-monazite, and a theoretical calculation of the properties of several structural types of orthophosphates. It is shown that actinide-doped monazite is prone to the formation of mechanically weak, poorly crystalline crust, presumably consisting of rhabdophane. Its formation is likely promoted by the formation of peroxides and, potentially, acidic compounds, due to the radiolysis of atmospheric moisture. The calculations of mixing the enthalpies and Gibbs energies of binary solid solutions of Pu and rare earth element (REE) phosphates that were performed for the principal structural types—monazite, xenotime, rhabdophane—show that, in the case of light REEs, the plutonium admixture is preferentially redistributed into the rhabdophane. This process strongly affects the behavior of actinides, leached from a monazite-based waste form. The applications of these results for the development of actinide waste forms are discussed. The current data on the behavior of real actinide-doped monazite suggest that this type of ceramic waste form is not very resistant, even in relatively short time periods.

Study of Natural Minerals of U-Ryrochlore-Type Structure as Analogues of Plutonium Ceramic Waste-form

2002 ◽  
Vol 713 ◽  
Author(s):  
Roman V. Bogdanov ◽  
Yuri F. Batrakov ◽  
Elena V. Puchkova ◽  
Andrey S. Sergeev ◽  
Boris E. Burakov
Keyword(s):  
Chemical Shifts ◽  
Pyrochlore Structure ◽  
Type Structure ◽  
Waste Form ◽  
X Ray ◽  
Ceramic Waste ◽  
Natural Minerals ◽  
The Us ◽  
Pyrochlore Type

ABSTRACTAt present, crystalline ceramic based on titanate pyrochlore, (Ca,Gd,Hf,Pu,U)2Ti2O7, is considered as the US candidate waste form for the immobilization of weapons grade plutonium. Naturally occuring U-bearing minerals with pyrochlore-type structure: hatchettolite, betafite, and ellsworthite, were studied in orders to understand long-term radiation damage effects in Pu ceramic waste forms. Chemical shifts (δ) of U(Lδ1)– and U(Lβ1) – X-ray emission lines were measured by X-ray spectrometry. Calculations were performed on the basis of a two-dimensional δLá1- and δLδ1- correlation diagram. It was shown that 100% of uranium in hatchettolite and, probably, 95-100% of uranium in betafite are in the form of (UO2)2+. formal calculation shows that in ellsworthite only 20% of uranium is in the form of U4+ and 80% of the rest is in the forms of U5+ and U6+. The conversion of the initial U4+ ion originally occurring in the pyrochlore structure of natural minerals to (UO2)2+ due to metamict decay causes a significant increase in uranium mobility.

Effects of acute seizures on cell proliferation, synaptic plasticity and long-term behavior in adult zebrafish

2021 ◽  
Vol 1756 ◽  
pp. 147334
Author(s):  
Charles Budaszewski Pinto ◽  
Natividade de Sá Couto-Pereira ◽  
Felipe Kawa Odorcyk ◽  
Kamila Cagliari Zenki ◽  
Carla Dalmaz ◽  
...  
Keyword(s):  
Cell Proliferation ◽  
Synaptic Plasticity ◽  
Adult Zebrafish ◽  
Acute Seizures ◽  
Long Term Behavior

Using Generalized Cell Mapping to Approximate Invariant Measures on Compact Manifolds

1997 ◽  
Vol 07 (11) ◽  
pp. 2487-2499 ◽  
Author(s):  
Rabbijah Guder ◽  
Edwin Kreuzer
Keyword(s):  
Dynamical Systems ◽  
Invariant Measures ◽  
Nonlinear Dynamical Systems ◽  
Powerful Method ◽  
Cell Mapping ◽  
Generalized Cell Mapping ◽  
Nonlinear Dynamical ◽  
Long Term Behavior ◽  
Mapping Theory

In order to predict the long term behavior of nonlinear dynamical systems the generalized cell mapping is an efficient and powerful method for numerical analysis. For this reason it is of interest to know under what circumstances dynamical quantities of the generalized cell mapping (like persistent groups, stationary densities, …) reflect the dynamics of the system (attractors, invariant measures, …). In this article we develop such connections between the generalized cell mapping theory and the theory of nonlinear dynamical systems. We prove that the generalized cell mapping is a discretization of the Frobenius–Perron operator. By applying the results obtained for the Frobenius–Perron operator to the generalized cell mapping we outline for some classes of transformations that the stationary densities of the generalized cell mapping converges to an invariant measure of the system. Furthermore, we discuss what kind of measures and attractors can be approximated by this method.

Long-Term Behavior of Wood-Concrete Composite Floor/Deck Systems with Shear Key Connection Detail

2007 ◽  
Vol 133 (9) ◽  
pp. 1307-1315 ◽  
Author(s):  
M. Fragiacomo ◽  
R. M. Gutkowski ◽  
J. Balogh ◽  
R. S. Fast
Keyword(s):  
Shear Key ◽  
Long Term Behavior

Attractors for multi-valued lattice dynamical systems with nonlinear diffusion terms

2021 ◽  
Author(s):  
Panpan Zhang ◽  
Anhui Gu
Keyword(s):  
Dynamical Systems ◽  
Nonlinear Diffusion ◽  
Upper Semicontinuity ◽  
Growth Conditions ◽  
Pullback Attractor ◽  
Random Lattice ◽  
Lipschitz Continuous ◽  
Lattice Dynamical Systems ◽  
Long Term Behavior

This paper is devoted to the long-term behavior of nonautonomous random lattice dynamical systems with nonlinear diffusion terms. The nonlinear drift and diffusion terms are not expected to be Lipschitz continuous but satisfy the continuity and growth conditions. We first prove the existence of solutions, and establish the existence of a multi-valued nonautonomous cocycle. We then show the existence and uniqueness of pullback attractors parameterized by sample parameters. Finally, we establish the measurability of this pullback attractor by the method based on the weak upper semicontinuity of the solutions.

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