Inorganic-organic hybrid materials for polymer electronic applications

2003 ◽  
Vol 769 ◽  
Author(s):  
R. Houbertz ◽  
J. Schulz ◽  
L. Fröhlich ◽  
G. Domann ◽  
M. Popall
Keyword(s):  
Thin Film ◽  
Water Vapor ◽  
Transition Rates ◽  
Electronic Circuits ◽  
Hybrid Polymers ◽  
Organic Hybrid ◽  
Wide Range ◽  
Polymer Electronics ◽  
Organic Functional Groups ◽  
Inorganic Content

AbstractFor applications in polymer electronics, suitable passivation coatings are searched for. Inorganic-organic hybrid polymers (ORMOCER®.s) have proven to be tunable in a wide range with respect to their physical properties. Their synthesis can be controlled such that the resulting materials show very low water vapor transition rates (WVTR) which is one of the most important key properties for passivation applications. Besides, ORMOCER®.s can be patterned by UV lithography due to their organic functional groups thus yielding the possibility of selectively passivate electronic circuits. Typical WVTR values which have been achieved so far for individual thin-film layers range between approximately 1 and 5 g/m2d (calculated for 100 μm layer thickness). The passivation properties will be discussed with respect to variations of the inorganic content and to the network formed upon processing.

Warm and freeze-fracture of cotton seed radicles

1987 ◽  
Vol 45 ◽  
pp. 984-985
Author(s):  
E. L. Vigil ◽  
E. F. Erbe
Keyword(s):  
Thin Film ◽  
Water Vapor ◽  
Fracture Surface ◽  
Membrane Structure ◽  
Room Temperature ◽  
Freeze Fracture ◽  
Longitudinal Axis ◽  
Fracture Plane ◽  
Cotton Seeds ◽  
Condensed Water

In cotton seeds the radicle has 12% moisture content which makes it possible to prepare freeze-fracture replicas without fixation or cryoprotection. For this study we have examined replicas of unfixed radicle tissue fractured at room temperature to obtain data on organelle and membrane structure.Excised radicles from seeds of cotton (Gossyplum hirsutum L. M-8) were fractured at room temperature along the longitudinal axis. The fracture was initiated by spliting the basal end of the excised radicle with a razor. This procedure produced a fracture through the tissue along an unknown fracture plane. The warm fractured radicle halves were placed on a thin film of 100% glycerol on a flat brass cap with fracture surface up. The cap was rapidly plunged into liquid nitrogen and transferred to a freeze- etch unit. The sample was etched for 3 min at -95°C to remove any condensed water vapor and then cooled to -150°C for platinum/carbon evaporation.

Wide range modulation of synaptic weight in thin-film transistors with hafnium oxide gate insulator and indium-zinc oxide channel layer for artificial synapse application

Nanoscale ◽  
2021 ◽  
Author(s):  
Keonwon Beom ◽  
Jimin Han ◽  
Hyun-Mi Kim ◽  
Tae-Sik Yoon
Keyword(s):  
Thin Film ◽  
Zinc Oxide ◽  
Thin Film Transistors ◽  
Hafnium Oxide ◽  
Synaptic Weight ◽  
Drain Current ◽  
Gate Insulator ◽  
Channel Layer ◽  
Indium Zinc Oxide ◽  
Wide Range

Wide range synaptic weight modulation with a tunable drain current was demonstrated in thin-film transistors (TFTs) with a hafnium oxide (HfO2−x) gate insulator and an indium-zinc oxide (IZO) channel layer...

Annealing in water vapor as a new method for improvement of silicon thin film properties

2006 ◽  
Vol 352 (9-20) ◽  
pp. 955-958 ◽  
Author(s):  
S. Honda ◽  
A. Fejfar ◽  
J. Kočka ◽  
T. Yamazaki ◽  
A. Ogane ◽  
...  
Keyword(s):  
Thin Film ◽  
Water Vapor ◽  
New Method ◽  
Silicon Thin Film ◽  
Film Properties

Helical, Nonracemic Inorganic−Organic Hybrid Polymers of Cadmium Halides with Pentadentate Bis(oxazoline) Ligands

2004 ◽  
Vol 126 (37) ◽  
pp. 11426-11427 ◽  
Author(s):  
Michael Seitz ◽  
Anja Kaiser ◽  
Sabine Stempfhuber ◽  
Manfred Zabel ◽  
Oliver Reiser
Keyword(s):  
Hybrid Polymers ◽  
Organic Hybrid ◽  
Oxazoline Ligands

Plasticity contributions to interface adhesion in thin-film interconnect structures

2000 ◽  
Vol 15 (12) ◽  
pp. 2758-2769 ◽  
Author(s):  
Michael Lane ◽  
Reinhold H. Dauskardt ◽  
Anna Vainchtein ◽  
Huajian Gao
Keyword(s):  
Thin Film ◽  
Film Thickness ◽  
Fracture Energy ◽  
Fracture Resistance ◽  
Work Of Adhesion ◽  
Interface Fracture ◽  
Cohesive Stress ◽  
Wide Range ◽  
Macroscopic Fracture ◽  
Metal Layers

The effects of plasticity in thin copper layers on the interface fracture resistance in thin-film interconnect structures were explored using experiments and multiscale simulations. Particular attention was given to the relationship between the intrinsic work of adhesion, Go, and the measured macroscopic fracture energy, Gc. Specifically, the TaN/SiO2 interface fracture energy was measured in thin-film Cu/TaN/SiO2 structures in which the Cu layer was varied over a wide range of thickness. A continuum/FEM model with cohesive surface elements was employed to calculate the macroscopic fracture energy of the layered structure. Published yield properties together with a plastic flow model for the metal layers were used to predict the plasticity contribution to interface fracture resistance where the film thickness (0.25–2.5 μm) dominated deformation behavior. For thicker metal layers, a transition region was identified in which the plastic deformation and associated plastic energy contributions to Gc were no longer dominated by the film thickness. The effects of other salient interface parameters including peak cohesive stress and Go are explored.

scholarly journals Differential absorption lidar measurements of water vapor by the High Altitude Lidar Observatory (HALO): Retrieval framework and validation

2021 ◽  
Author(s):  
Brian J. Carroll ◽  
Amin R. Nehrir ◽  
Susan Kooi ◽  
James Collins ◽  
Rory A. Barton-Grimley ◽  
...  
Keyword(s):  
Water Vapor ◽  
High Altitude ◽  
Dynamic Range ◽  
Precipitable Water ◽  
Spatiotemporal Variability ◽  
High Spectral Resolution ◽  
Atmospheric Conditions ◽  
Differential Absorption ◽  
Differential Absorption Lidar ◽  
Wide Range

Abstract. Airborne differential absorption lidar (DIAL) offers a uniquely capable solution to the problem of measuring water vapor (WV) with high precision, accuracy, and resolution throughout the troposphere and lower stratosphere. The High Altitude Lidar Observatory (HALO) airborne WV DIAL was recently developed at NASA Langley Research Center and was first deployed in 2019. It uses four wavelengths at 935 nm to achieve sensitivity over a wide dynamic range, and simultaneously employs 1064 nm backscatter and 532 nm high spectral resolution lidar (HSRL) measurements for aerosol and cloud profiling. A key component of the WV retrieval framework is flexibly trading resolution for precision to achieve optimal data sets for scientific objectives across scales. A technique for retrieving WV in the lowest few hundred meters of the atmosphere using the strong surface return signal is also presented. The five maiden flights of the HALO WV DIAL spanned the tropics through midlatitudes with a wide range of atmospheric conditions, but opportunities for validation were sparse. Comparisons to dropsonde WV profiles were qualitatively in good agreement, though statistical analysis was impossible due to systematic error in the dropsonde measurements. Comparison of HALO to in situ WV measurements onboard the aircraft showed no substantial bias across three orders of magnitude, despite variance (R2 = 0.66) that may be largely attributed to spatiotemporal variability. Precipitable water vapor measurements from the spaceborne sounders AIRS and IASI compared very well to HALO with R2 > 0.96 over ocean and R2 = 0.86 over land.

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