scholarly journals Synthesis and application of a composite NaA zeolite/gamma-alumina membrane for oil-water separation process

Cerâmica ◽  
2020 ◽  
Vol 66 (378) ◽  
pp. 137-144 ◽  
Author(s):  
T. L. A. Barbosa ◽  
F. M. N. Silva ◽  
A. S. Barbosa ◽  
E. G. Lima ◽  
M. G. F. Rodrigues

Abstract This study proposed the development of an efficient membrane composed of zeolite-alumina to be used for water-oil separation of wastewater effluents contaminated by oil extraction processes. The efforts made to care for the environment and to decontaminate bodies of water are extremely valuable and constantly being updated. Little research has been done on this subject and this study contributed to remedying this lack. Membrane technology is a reasonable alternative to conventional procedures if economics and eco-sustainability are considered. The objective of this study was to examine the performance of a composite membrane produced through mechanical mixing. The potential of the composite membrane (NaA zeolite/gama-alumina) to separate oil-water emulsions was tested. The results obtained demonstrated that the composite membrane is an excellent alternative for the oil/water emulsion separation process; the membranes are efficient and low-cost alternatives for treating oily wastewater.

Nanomaterials ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 3434
Author(s):  
Haodong Zhao ◽  
Yali He ◽  
Zhihua Wang ◽  
Yanbao Zhao ◽  
Lei Sun

Emulsified oily wastewater threatens human health seriously, and traditional technologies are unable to separate emulsion containing small sized oil droplets. Currently, oil–water emulsions are usually separated by special wettability membranes, and researchers are devoted to developing membranes with excellent antifouling performance and high permeability. Herein, a novel, simple and low-cost method has been proposed for the separation of emulsion containing surfactants. Polyacrylonitrile (PAN) nanofibers were prepared via electrospinning and then coated by polydopamine (PDA) by using self-polymerization reactions in aqueous solutions. The morphology, structure and oil-in-water emulsion separation properties of the as-prepared PDA@PAN nanofibrous membrane were tested. The results show that PDA@PAN nanofibrous membrane has superhydrophilicity and almost no adhesion to crude oil in water, which exhibits excellent oil–water separation ability. The permeability and separation efficiency of n-hexane/water emulsion are up to 1570 Lm−2 h−1 bar−1 and 96.1%, respectively. Furthermore, after 10 cycles of separation, the permeability and separation efficiency values do not decrease significantly, indicating its good recycling performance. This research develops a new method for preparing oil–water separation membrane, which can be used for efficient oil-in-water emulsion separation.


2020 ◽  
Vol 44 (48) ◽  
pp. 20999-21006
Author(s):  
Junda Wu ◽  
Atian Xie ◽  
Jin Yang ◽  
Jiangdong Dai ◽  
Chunxiang Li ◽  
...  

A facile modification of a PVDF membrane using CaCO3 inorganic particles via a layer-by-layer self-assembly process for efficient oil/water separation.


2020 ◽  
Vol 11 (2) ◽  
pp. 364
Author(s):  
Bambang Poerwadi ◽  
Christina W. Kartikowati ◽  
Rama Oktavian ◽  
Oyong Novareza

NANO ◽  
2021 ◽  
pp. 2150025
Author(s):  
Yilin Wu ◽  
Yan Yan ◽  
Jian Lu ◽  
Zhixin Yu ◽  
Junda Wu ◽  
...  

A new multifunctional KGM/PDA/PVDF composite membrane was successfully prepared via facile nonsolvent induced phase inversion method. Here, the KGM component consisted of numerous covalent bonds, which could improve the corrosion resistance of membrane materials. The dopamine, as a natural “glue” between PVDF substantial and KGM, is capable of integrating different materials together suitably. The as-prepared membrane possessed superior superhydrophilic/underwater superoleophobic property, great corrosion resistance and antifouling property. The separation efficiency was as high as 99.01%, and could stay relatively stable even in the acid, alkali or high salty environment. Additionally, the membrane had great regeneration performance and could keep stable after 15 cyclic separation, which was appropriate for efficient various oil–water separation process. Moreover, the composite membrane could also effectively separate dyes in different environments and the efficiencies were all more than 91%. All in all, the multifunctional composite membrane with facile preparation method might provide a promising strategy and significant theoretical basis for the efficient separation of oil–water emulsions and dyes.


2014 ◽  
Vol 2 (30) ◽  
pp. 11830-11838 ◽  
Author(s):  
Xiaoyu Li ◽  
Dan Hu ◽  
Kun Huang ◽  
Chuanfang Yang

Stainless steel felt modified with hierarchically structured coatings and hydrophobicity can achieve a removal efficiency of greater than 99% for oil-in-water emulsion separation.


2019 ◽  
Vol 31 (5) ◽  
pp. 538-547 ◽  
Author(s):  
Qiong Du ◽  
Zheng Chen ◽  
Xiangyu Jiang ◽  
Jinhui Pang ◽  
Zhenhua Jiang ◽  
...  

A new nanofibrous membrane (NFM) was prepared by blending polyethersulfone (PES) and sulfonated poly(ether ether ketone) (SPEEK) via electrospinning. The membrane exhibits good thermal stability and high mechanical strength. The hydrophilicity of the membrane could be controlled by adjusting the mass ratio of PES to SPEEK. PES acts as the backbone fiber and provides high mechanical strength, while SPEEK provides hydrophilic functional groups due to the strong hydrophilicity of the sulfonic group. The test results show that the composite NFM integrates the advantages of the two polymers. Simple adjustment of the weight ratios of the two polymers can enable an adjustable flux so that the membrane can be used for different kinds of oil/water separation. The results show that NFMs can not only separate immiscible oil/water systems but also separate oil-in-water emulsions. The immiscible oil/water separation process was driven only by gravity and had a high flux of 1119.63 Lm−2 h−1. This separation process conserves energy, which is beneficial for environmental protection. The separation flux of the oil-in-water emulsion was 758.71 Lm−2 h−1 bar−1 based on measurements under different pressures, and the separation purity total organic carbon was below 50 ppm. This work indicates that a membrane comprised of PES and SPEEK has excellent performance and can be used in different fields.


2015 ◽  
Vol 17 (5) ◽  
pp. 3093-3099 ◽  
Author(s):  
Gang Wang ◽  
Yi He ◽  
He Wang ◽  
Lin Zhang ◽  
Quanyao Yu ◽  
...  

A cellulose sponge with properties of superhydrophilicity and under-water superoleophobicity gives 99.94% separation efficiency in oil–water emulsion separation.


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