scholarly journals Incorporation of N in the TiO2 Lattice Versus Oxidation of TiN: Influence of the Deposition Method on the Energy Gap of N-Doped TiO2 Deposited by Reactive Magnetron Sputtering

2017 ◽  
Vol 20 (2) ◽  
pp. 549-554 ◽  
Author(s):  
Diego Alexandre Duarte ◽  
Marcos Massi
Vacuum ◽  
2007 ◽  
Vol 82 (3) ◽  
pp. 328-335 ◽  
Author(s):  
Wenjie Zhang ◽  
Shenglong Zhu ◽  
Ying Li ◽  
Fuhui Wang

2005 ◽  
Vol 475-479 ◽  
pp. 1223-1226 ◽  
Author(s):  
Ming Zhao ◽  
Da Ming Zhuang ◽  
Gong Zhang ◽  
Ling Fang ◽  
Min Sheng Wu

The nitrogen-doped TiO2 thin films were prepared by mid-frequency alternative reactive magnetron sputtering technique. The N concentration of the nitrogen-doped TiO2 thin films was analyzed by XPS. And the absorption spectra of the films in ultraviolet and visible region were also investigated. The results show that the mid-frequency alternative reactive magnetron sputtering technique is a convenient method for growing TiO2-xNx. Annealing the nitrogen-doped TiO2 thin film in nitrogen atmosphere under 380°C is helpful for increase the concentration of nitrogen in the film, but the ratio of N2 in reactive gas is mainly influence the concentration of nitrogen in the Ti-N bond in the TiO2 film. The increase of the thickness of nitrogen-doped TiO2 films will enhance the absorbability of the film in the ultraviolet and visible region. The wavelength of the absorption edge of TiO2-xNx film with 1.5% nitrogen shift to 441nm from 387nm, which is the absorption edge for undoped TiO2 films.


2009 ◽  
Vol 155 (1-2) ◽  
pp. 83-87 ◽  
Author(s):  
Wenjie Zhang ◽  
Kuanling Wang ◽  
Shenglong Zhu ◽  
Ying Li ◽  
Fuhui Wang ◽  
...  

2006 ◽  
Vol 910 ◽  
Author(s):  
Isao Nakamura ◽  
Toru Ajiki ◽  
Masao Isomura

AbstractMicrocrystalline silicon germanium films (μc-SiGe) were fabricated on Corning #7059 glass substrates by the RF reactive magnetron sputtering method. The μc-SiGe films with Ge fraction of 0.7-0.8 could be crystallized at of 200 °C by H2 introduction into the sputtering gases. The absorption coefficients of the films decrease in long wavelength region corresponding to the photon energies below the energy gap by the decrease in the substrate temperature and become close to those of single crystal Si0.25Ge0.75. The dark conductivities show lower values of 10-7 S/cm at 200 °C and 300 °C with H2 introduction. Besides, the photosensitivities are observed in these samples. These results indicate that the H2 introduction into the sputtering gas has two important effects to decrease the crystallization temperature of the μc-SiGe and to improve the film properties by reducing the dangling bond defects.


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