AC impedance and dielectric studies of biopolymer electrolytes based on I-carrageenan

2021 ◽  
pp. 1-8
Author(s):  
Thirupathi Mahalakshmi ◽  
Chandran Sankareswari ◽  
Santhana Krishnan Jayanthi
2015 ◽  
Vol 1107 ◽  
pp. 230-235 ◽  
Author(s):  
N.A.M. Noor ◽  
M.I.N. Isa

In this work, solid biopolymer electrolytes (SBE) containing carboxymethyl cellulose (CMC) doped with ammonium thiocyanate (NH4SCN) were prepared via solution casting method. The ionic conductivity and dielectric properties of CMC-NH4SCN system were investigated by electrical impedance spectroscopy in the temperature range of 303-353 K. The dc conductivity shows that the highest ionic conductivity of 6.48 x 10-5 Scm-1 at ambient temperature was obtained when 25 wt.% of NH4SCN was incorporated. The temperature dependence of ionic conductivity revealed that CMC-NH4SCN system was discovered to obey Arrhenius law where the regression value is almost unity (R2≈1). Activation energy of CMC-NH4SCN system was found to decrease with the increment of NH4SCN concentration. The dielectric behaviour of the CMC-NH4SCN system have been analyzed using dielectric permittivity (ε*) and electrical modulus (M*) spectra. Results from dielectric studies showed a non-Debye behaviour of CMC-NH4SCN system.


2017 ◽  
Vol 11 (1) ◽  
pp. 52-59 ◽  
Author(s):  
Unikoth Megha ◽  
George Varghese ◽  
Karakat Shijina

2018 ◽  
Vol 218 ◽  
pp. 197-200 ◽  
Author(s):  
M. Vahini ◽  
M. Muthuvinayagam

2019 ◽  
Vol 61 (7) ◽  
pp. 685-689 ◽  
Author(s):  
Özden Aslan Çataltepe ◽  
Zeynep Güven Özdemir ◽  
Mehmet Kılıç ◽  
Ülker Onbaşlı

2005 ◽  
Vol 30 (1) ◽  
pp. 55-65 ◽  
Author(s):  
Anouar Gargouri ◽  
Slaheddine Chaaboui ◽  
Abdelhamid Ben Salah

Polymer ◽  
1981 ◽  
Vol 22 (8) ◽  
pp. 1048-1053 ◽  
Author(s):  
Derek J. Crofton ◽  
Richard A. Pethrick

2020 ◽  
Vol 9 (1) ◽  
pp. 1445-1455
Author(s):  
Song Gao ◽  
Jianlin Luo ◽  
Jigang Zhang ◽  
Fei Teng ◽  
Chao Liu ◽  
...  

Abstract Water and sand were used as the medium of multiwall carbon nanotube (MCNT) and prepared MCNT aqueous suspension and MCNT suspension-coated sand, respectively; afterwards, they were introduced into cement mortar (MNT/CM, MNTSM), respectively. Next, mechanical strengths and piezoresistive properties (DC resistivities (ρ v), AC impedances (Z r)) under cyclic loadings (σ c) of two types of MNT/CM and MNTSM nanocomposites were investigated to explore the intrinsic and self-sensing behaviors. Results reveal that MCNT can be evenly and well-coated on sand, which favors to achieve its intrinsic self-sensing property. Although the fraction changes in ρ v and Z r under the same σ c of MNTSM are both lower than those of MNT/CM, the stress sensitivity of MNTSM is only −1.16%/MPa (DC resistivity), −1.55%/MPa (AC impedance); its sensing linearity and stability (2.53, 2.45%; 2.73, 2.67%) are superior to those of MNT/CM (4.94, 2.57%; 3.78, 2.96%). Piezoresistivity using AC impedance technique is helpful to acquire balanced sensing sensitivity and stability while applied as intrinsic sensors in infrastructure.


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