Synthesis and Characterization of Cr, Eggshell and Grinding Sludge Reinforced Aluminum Based Metal Matrix Composites: An Ingenious Experimental Approach

This investigation deals with the utilization of industrial waste to develop aluminum-based composite. Waste eggshell (ES) generated from the food industry has been used as primary reinforcement material. Waste grinding sludge (GS) produced from the iron forging sector was utilized as secondary reinforcement content. Cr content has been further encapsulated to the composite material to prevent the composite material's grain growth. The composite material was developed by the stir casting process. Experimental results concluded that tensile strength, compressive strength, and hardness of base material (AA5052 alloy) had been improved by about 18.02 %, 23.40 %, and 49.53 respectively, by adding 4.5 % of ES, 4.5 % of GS, and 1.5 % of Cr. Microstructural analysis of the AA5052/4.5 % ES/4.5 % GS/1.5 % Cr composite shows the fair distribution of reinforcement content. XRD of the Al/4.5 % ES/4.5 % GS/1.5 % Cr composite shows the occurrence of Al, Fe2O3, CaCO3, CaO, and Cr phases. Corrosion weight loss and thermal expansion behavior of developed composite have also been explored to observe the ES, GS, and Cr addition in the aluminum alloy.

Pyrolysis of Waste Polyolefin’s and E-component to Produce Renewable Green Fuel (RGF) Over CdCO3

The interest and relevance of the present paper is in the current waste plastics valorization scenario. The rapid depletion of fossil sources carbon as crude oil and their ever-increasing costs has led to an intensive search for alternative fuels. The renewable green fuel (RGF) or alternative fuel was obtained from waste low and high-density polyethylene (LD-PE, HD-PE) or polyolefin’s and computer-body through pyrolysis process using a CdCO3 from 23 °C to 400 °C. Five types of hydrocarbons were observed through 2D GCxGC/TOFMS, such as 7.621 % paraffin’s, 53.66 % branched / cyclic hydrocarbons, 14.83 % aromatics, 0.37 % phenanthrenes, and some unclassified compounds were 27.11 %. The research octane number of RGF was 88.29. The bromine number of RGF is 34.03 %. RGF was suitable for diesel engines and diesel furnaces without any upgrading. During the first, second and third pyrolysis experiments, 98 g, 95 g and 100 g (wt %) waste granules with 2 g, 5 g and 0 g (wt %) CdCO3 into RGFs were 85 %, 89 % and 80 % collected; uncondensed gases were 14.22 %, 10.15 % and 19.52 % collected; the residue were 0.78 %, 0.85 % and 0.48 % collected.