scholarly journals Investigation of Click Reaction at an Oil-Water Interface Using Hydrophobic and Hydrophilic Polymers

2013 ◽  
Vol 11 ◽  
pp. 31-39 ◽  
Author(s):  
Md Ashaduzzaman ◽  
Shu Hei Kai ◽  
Masashi Kunitake
Keyword(s):  
Click Reaction ◽  
Copper Catalyst ◽  
Phase Interface ◽  
Hydrophilic Polymers ◽  
Hydrophilic Polymer ◽  
Composite Polymer ◽  
Click Reactions ◽  
Styrene Sulfonate ◽  
Oil Water ◽  
Hydrophilic Shell

Cu(I)-catalyzed Huisgen click reactions between lipophilic polymer (tri-arm azidofunctionalized polystyrene) and hydrophilic polymer (copolymer of styrene sulfonate sodium and propargyl methacrylate) were investigated and hollow capsules, consisting of composite polymer nanofilms were obtained in chloroform-water biphasic solution. Since the lipophilic polymer, or hydrophilic polymer and copper catalyst were present in the oil or aqueous phase, respectively, the cross-linking reaction proceeded only at the phase interface. The combination of lipophilic and hydrophilic polymers produced hollow capsules consisting of nanofilms with lipophilic core and hydrophilic shell.

Composite Polymer Materials Consisting of Nanofilms Formed by Click Reaction between Polymers at an Oil–Water Interface

2011 ◽  
Vol 40 (3) ◽  
pp. 270-272 ◽  
Author(s):  
Shuhei Kai ◽  
Md. Ashaduzzaman ◽  
Shinobu Uemura ◽  
Masashi Kunitake
Keyword(s):  
Click Reaction ◽  
Polymer Materials ◽  
Water Interface ◽  
Composite Polymer ◽  
Oil Water

scholarly journals SYNTHESIS OF AN AZIDE–THIOL LINKER FOR HETEROGENEOUS POLYMER FUNCTIONALIZATION VIA THE “CLICK” REACTION

2018 ◽  
Vol 55 (1B) ◽  
pp. 152
Author(s):  
Thuy Thu Truong
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Click Reaction ◽  
Proton Nuclear Magnetic Resonance ◽  
Reaction Yield ◽  
Reaction Conditions ◽  
Click Reactions ◽  
Heterogeneous Polymer ◽  
Ft Ir ◽  
First Time ◽  
Layer Chromatography

In this study, the synthesis of a telechelic linker bearing both azide and thiol functional groups was described. The reaction conditions were investigated to optimize the reaction yield. The product was analyzed using thin layer chromatography (TLC) and proton nuclear magnetic resonance (1H NMR). The employment of the obtained azide–thiol linker in heterogeneous polymer “click” functionalization was demonstrated for the first time, which was monitored by an online FT–IR method. The obtained telechelic azide–thiol linker is envisioned to be useful chemical tools to link macromolecular chains via orthogonal click reactions.

Copper(i) complexes bearing mesoionic carbene ligands: influencing the activity in catalytic halo-click reactions

2020 ◽  
Vol 49 (43) ◽  
pp. 15504-15510
Author(s):  
Lisa Suntrup ◽  
Julia Beerhues ◽  
Oliver Etzold ◽  
Biprajit Sarkar
Keyword(s):  
Click Reaction ◽  
Carbene Ligands ◽  
Click Reactions ◽  
Dicopper Complexes

A series of mono- and dicopper complexes with mesoionic carbenes are tested as pre-catalysts for the halo-click reaction.

scholarly journals Silver-catalysed azide–alkyne cycloaddition (AgAAC): assessing the mechanism by density functional theory calculations

2016 ◽  
Vol 3 (9) ◽  
pp. 160090 ◽  
Author(s):  
Biswadip Banerji ◽  
K. Chandrasekhar ◽  
Sunil Kumar Killi ◽  
Sumit Kumar Pramanik ◽  
Pal Uttam ◽  
...  
Keyword(s):  
Density Functional ◽  
Click Reaction ◽  
Cycloaddition Reaction ◽  
Triazole Ring ◽  
Density Functional Theory Calculations ◽  
Dipolar Cycloaddition ◽  
Reaction Conditions ◽  
Functional Theory ◽  
Click Reactions ◽  
Counter Ions

‘Click reactions’ are the copper catalysed dipolar cycloaddition reaction of azides and alkynes to incorporate nitrogens into a cyclic hydrocarbon scaffold forming a triazole ring. Owing to its efficiency and versatility, this reaction and the products, triazole-containing heterocycles, have immense importance in medicinal chemistry. Copper is the only known catalyst to carry out this reaction, the mechanism of which remains unclear. We report here that the ‘click reactions’ can also be catalysed by silver halides in non-aqueous medium. It constitutes an alternative to the well-known CuAAC click reaction. The yield of the reaction varies on the type of counter ion present in the silver salt. This reaction exhibits significant features, such as high regioselectivity, mild reaction conditions, easy availability of substrates and reasonably good yields. In this communication, the findings of a new catalyst along with the effect of solvent and counter ions will help to decipher the still obscure mechanism of this important reaction.

Highly compression-tolerant and durably hydrophobic macroporous silicone sponges synthesized by a one-pot click reaction for rapid oil/water separation

2018 ◽  
Vol 6 (37) ◽  
pp. 18025-18030 ◽  
Author(s):  
Jinfeng Cao ◽  
Dengxu Wang ◽  
Peng An ◽  
Jie Zhang ◽  
Shengyu Feng
Keyword(s):  
Thermal Insulation ◽  
Click Reaction ◽  
Low Density ◽  
One Pot ◽  
Water Separation ◽  
Oil Water Separation ◽  
Oil Water

Macroporous silicone sponges were first synthesized via a one-pot click reaction, which have controllable porosity, low density, durable hydrophobicity, superoleophilicity, good thermal insulation, and excellent compressibility.

Synthesis of allyl cellulose in NaOH/urea aqueous solutions and its thiol–ene click reactions

2015 ◽  
Vol 6 (18) ◽  
pp. 3543-3548 ◽  
Author(s):  
Haoze Hu ◽  
Jun You ◽  
Weiping Gan ◽  
Jinping Zhou ◽  
Lina Zhang
Keyword(s):  
Aqueous Solutions ◽  
Click Reaction ◽  
Allyl Chloride ◽  
Cellulose Derivatives ◽  
Click Reactions

Allyl cellulose can be synthesized from cellulose and allyl chloride in NaOH/urea aqueous solutions and is further used to synthesize a variety of new cellulose derivatives through the thiol–ene click reaction.

scholarly journals Mild Covalent Functionalization of Transition Metal Dichalcogenides with Maleimides: A “Click” Reaction for TMDCs

2018 ◽  
Author(s):  
Mariano Vera-Hidalgo ◽  
Emerson Giovanelli ◽  
Cristina Navío ◽  
Emilio Pérez
Keyword(s):  
Transition Metal ◽  
Chemical Modification ◽  
Biomedical Applications ◽  
Click Reaction ◽  
Transition Metal Dichalcogenides ◽  
Polymer Chemistry ◽  
Covalent Functionalization ◽  
Click Reactions ◽  
Mild Conditions ◽  
Metal Dichalcogenides

The physical properties of ultrathin transition metal dichalcogenides (2D-TMDCs) make them promising candidates as active nanomaterials for catalysis, optoelectronics, and biomedical applications. Chemical modification of TMDCs is expected to be key in modifying/adding new functions that will help make such promise a reality. We present a mild method for the modification of the basal planes of 2H-MoS<sub>2</sub> and WS<sub>2</sub>. We exploit the soft nucleophilicity of sulfur to react it with maleimide derivatives, achieving covalent functionalization of 2H-TMDCs under very mild conditions. Extensive characterization proves that the reaction occurs through Michael addition. Our results adapt one of the most popular “click” reactions in polymer chemistry and biochemistry to obtain a powerful tool for the chemical manipulation of TMDCs.

Polyester nitrile N-oxides for click reactions synthesized with nitroalkane precursors as the initiator

2020 ◽  
Vol 11 (18) ◽  
pp. 3115-3119 ◽  
Author(s):  
Toyokazu Tsutsuba ◽  
Hiromitsu Sogawa ◽  
Toshikazu Takata
Keyword(s):  
Click Reaction ◽  
Polymer Synthesis ◽  
Star Polymer ◽  
Click Reactions ◽  
Catalyst Free

Polyesters that have a nitrile N-oxide function at the initiation end were prepared and applied to a catalyst-free click reaction for star polymer synthesis.

scholarly journals Superhydrophobic Melamine Sponge Coated with Striped Polydimethylsiloxane by Thiol–Ene Click Reaction for Efficient Oil/Water Separation

ACS Omega ◽  
2018 ◽  
Vol 3 (5) ◽  
pp. 5222-5228 ◽  
Author(s):  
Jinwen Peng ◽  
Junjie Deng ◽  
Yiteng Quan ◽  
Chuanbai Yu ◽  
Hai Wang ◽  
...  
Keyword(s):  
Click Reaction ◽  
Water Separation ◽  
Oil Water Separation ◽  
Oil Water
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