scholarly journals Preparation and Characterization of Electrochemically Deposited Silicon Films in Ionic Liquid from Polysilicon Byproduct SiCl4

Author(s):  
Zhanxia Zhao ◽  
2018 ◽  
Vol 21 (7) ◽  
pp. 526-532 ◽  
Author(s):  
Zahra Abdi Piralghar ◽  
Mohammad Mahmoodi Hashemi ◽  
Ali Ezabadi

Aim and Objective: In this work, we synthesized and characterized a novel Brönsted acidic ionic liquid from the reaction of N, N, N’, N’-tetramethylethylenediamine with chlorosulfonic acid and explored its catalytic activity in 1, 8-dioxo-octahydroxanthenes synthesis. Materials and Methods: Dimedone, aryl aldehydes, and the ionic liquid as the catalyst were reacted under solvent-free conditions. The progressive of the reaction was monitored by a thin layer of chromatography (ethyl acetate/n-hexane = 1/5). All products were characterized as the basis of their spectra data and melting point by comparison with those reported in the literature. Results: The prepared ionic liquid was successfully applied in the synthesis of 1, 8-dioxooctahydroxanthenes in good to high yields on the reaction of aryl aldehyde and dimedone at 120oC under solvent-free conditions. Conclusion: This research demonstrates that the catalyst is impressive for 1, 8-dioxo-octahydroxanthenes synthesis under solvent-free conditions.


2019 ◽  
Vol 19 (15) ◽  
pp. 6076-6084 ◽  
Author(s):  
Md. Omar Faruk Emon ◽  
Jeongwoo Lee ◽  
U Hyeok Choi ◽  
Da-Hye Kim ◽  
Kyung-Chang Lee ◽  
...  

2008 ◽  
Vol 354 (19-25) ◽  
pp. 2227-2230 ◽  
Author(s):  
J. Kočka ◽  
T. Mates ◽  
M. Ledinský ◽  
H. Stuchlíková ◽  
J. Stuchlík ◽  
...  

ACS Omega ◽  
2017 ◽  
Vol 2 (2) ◽  
pp. 478-486 ◽  
Author(s):  
Merve T. Camci ◽  
Burak Ulgut ◽  
Coskun Kocabas ◽  
Sefik Suzer

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