Evaluation of Metal Removal and Toxicity Reduction in a Low Sulfate Mine Drainage by Constructed Wetlands

1995 ◽  
Vol 1995 (1) ◽  
pp. 78-92 ◽  
Author(s):  
G. H. Farmer ◽  
D. M. Updegraff ◽  
J. M. Lazorchak ◽  
E. R. Bates
Keyword(s):  
Constructed Wetlands ◽  
Mine Drainage ◽  
Metal Removal ◽  
Toxicity Reduction

scholarly journals Effects of Cattails and Hydraulic Loading on Heavy Metal Removal from Closed Mine Drainage by Pilot-Scale Constructed Wetlands

Water ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 1937
Author(s):  
Thuong Thi Nguyen ◽  
Satoshi Soda ◽  
Akihiro Kanayama ◽  
Takaya Hamai
Keyword(s):  
Heavy Metal ◽  
Constructed Wetlands ◽  
Mine Drainage ◽  
Metal Removal ◽  
Heavy Metal Removal ◽  
Pilot Scale ◽  
Sulfate Reducing ◽  
A Minor ◽  
Reducing Bacteria ◽  
Translocation Factors

This study demonstrated heavy metal removal from neutral mine drainage of a closed mine in Kyoto prefecture in pilot-scale constructed wetlands (CWs). The CWs filled with loamy soil and limestone were unplanted or planted with cattails. The hydraulic retention time (HRT) in the CWs was shortened gradually from 3.8 days to 1.2 days during 3.5 months of operation. A short HRT of 1.2 days in the CWs was sufficient to achieve the effluent standard for Cd (0.03 mg/L). The unplanted and the cattail-planted CWs reduced the average concentrations of Cd from 0.031 to 0.01 and 0.005 mg/L, Zn from 0.52 to 0.14 and 0.08 mg/L, Cu from 0.07 to 0.04 and 0.03 mg/L, and As from 0.011 to 0.006 and 0.006 mg/L, respectively. Heavy metals were removed mainly by adsorption to the soil in both CWs. The biological concentration factors in cattails were over 2 for Cd, Zn, and Cu. The translocation factors of cattails for all metals were 0.5–0.81. Sulfate-reducing bacteria (SRB) belonging to Deltaproteobacteria were detected only from soil in the planted CW. Although cattails were a minor sink, the plants contributed to metal removal by rhizofiltration and incubation of SRB, possibly producing sulfide precipitates in the rhizosphere.

scholarly journals Review of Constructed Wetlands for Acid Mine Drainage Treatment

Water ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1685 ◽  
Author(s):  
Aurora Pat-Espadas ◽  
Rene Loredo Portales ◽  
Leonel Amabilis-Sosa ◽  
Gloria Gómez ◽  
Gladys Vidal
Keyword(s):  
Heavy Metal ◽  
Acid Mine Drainage ◽  
Constructed Wetlands ◽  
Mine Drainage ◽  
Metal Removal ◽  
Water Solution ◽  
Heavy Metal Removal ◽  
Systems Design ◽  
Economic Point ◽  
Acid Mine

The mining industry is the major producer of acid mine drainage (AMD). The problem of AMD concerns at active and abandoned mine sites. Acid mine drainage needs to be treated since it can contaminate surface water. Constructed wetlands (CW), a passive treatment technology, combines naturally-occurring biogeochemical, geochemical, and physical processes. This technology can be used for the long-term remediation of AMD. The challenge is to overcome some factors, for instance, chemical characteristics of AMD such a high acidity and toxic metals concentrations, to achieve efficient CW systems. Design criteria, conformational arrangements, and careful selection of each component must be considered to achieve the treatment. The main objective of this review is to summarize the current advances, applications, and the prevalent difficulties and opportunities to apply the CW technology for AMD treatment. According to the cited literature, sub-surface CW (SS-CW) systems are suggested for an efficient AMD treatment. The synergistic interactions between CW components determine heavy metal removal from water solution. The microorganism-plant interaction is considered the most important since it implies symbiosis mechanisms for heavy metal removal and tolerance. In addition, formation of litter and biofilm layers contributes to heavy metal removal by adsorption mechanisms. The addition of organic amendments to the substrate material and AMD bacterial consortium inoculation are some of the strategies to improve heavy metal removal. Adequate experimental design from laboratory to full scale systems need to be used to optimize equilibria between CW components selection and construction and operational costs. The principal limitations for CW treating AMD is the toxicity effect that heavy metals produce on CW plants and microorganisms. However, these aspects can be solved partially by choosing carefully constructed wetlands components suitable for the AMD characteristics. From the economic point of view, a variety of factors affects the cost of constructed wetlands, such as: detention time, treatment goals, media type, pretreatment type, number of cells, source, and availability of gravel media, and land requirements, among others.

Using Decomposition Kinetics to Model the Removal of Mine Water Pollutants in Constructed Wetlands

1994 ◽  
Vol 29 (4) ◽  
pp. 219-226 ◽  
Author(s):  
William J. Tarutis ◽  
Richard F. Unz
Keyword(s):  
Organic Matter ◽  
Constructed Wetlands ◽  
Mine Drainage ◽  
Term Treatment ◽  
Decomposition Kinetics ◽  
Dry Density ◽  
Organic Matter Concentration ◽  
Long Term Treatment ◽  
Input Variables ◽  
Reaction Stoichiometry

Although numerous mathematical models have been used to describe decomposition, few, if any, have been used to model the removal of pollutants in constructed wetlands. A steady-state model based on decomposition kinetics and reaction stoichiometry has been developed which simulates the removal of ferrous iron entering wetlands constructed for mine drainage treatment. Input variables for the model include organic matter concentration, reaction rate coefficient, porosity and dry density, and hydraulic detention time. Application of the model assumes complete anaerobic conditions within the entire substrate profile, constant temperature, no additional organic matter input, and subsurface flow only. For these ideal conditions, model simulations indicate that wetlands constructed with readily decomposable substrates rich in organic carbon are initially capable of removing far greater amounts of iron than wetlands built with less biodegradable substrates. However, after three to five years of operation this difference becomes negligible. For acceptable long-term treatment performance, therefore, periodic additions of decomposable organic matter will be required.

scholarly journals Metal Removal from Acid Waters by an Endemic Microalga from the Atacama Desert for Water Recovery

Minerals ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 378 ◽  
Author(s):  
Marcela Martínez ◽  
Yanett Leyton ◽  
Luis Cisternas ◽  
Carlos Riquelme
Keyword(s):  
Mine Drainage ◽  
Metal Removal ◽  
Atacama Desert ◽  
Mining Industry ◽  
Mining Activity ◽  
Water Recovery ◽  
Metallic Ions ◽  
Mineral Extraction ◽  
High Concentrations ◽  
Acid Waters

The environmental problems generated by waste from the mining industry in the mineral extraction for business purposes are known worldwide. The aim of this work is to evaluate the microalga Muriellopsis sp. as a potential remover of metallic ions such as copper (Cu2+), zinc (Zn2+) and iron (Fe2+), pollutants of acid mine drainage (AMD) type waters. For this, the removal of these ions was verified in artificial acid waters with high concentrations of the ions under examination. Furthermore, the removal was evaluated in waters obtained from areas contaminated by mining waste. The results showed that Muriellopsis sp. removed metals in waters with high concentrations after 4–12 h and showed tolerance to pH between 3 and 5. These results allow proposing this species as a potential bioremediator for areas contaminated by mining activity. In this work, some potential alternatives for application in damaged areas are proposed as a decontamination plan and future prevention.

scholarly journals Understanding the biogeochemical mechanisms of metal removal from acid mine drainage with a subsurface limestone bed at the Motokura Mine, Japan

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Shigeshi Fuchida ◽  
Kohei Suzuki ◽  
Tatsuya Kato ◽  
Masakazu Kadokura ◽  
Chiharu Tokoro
Keyword(s):  
Acid Mine Drainage ◽  
Mine Drainage ◽  
Metal Removal ◽  
Theoretical Calculations ◽  
Exchange Capacity ◽  
Treatment Technique ◽  
Manganese Compound ◽  
Edge Structure ◽  
Acid Mine ◽  
Copper Zinc

AbstractSubsurface limestone beds (SLBs) are used as a passive treatment technique to remove toxic metals from acid mine drainage (AMD). In this study, we investigated the mechanisms and thermodynamics of metal (manganese, copper, zinc, cadmium, and lead) precipitation in the SLB installed at the Motokura Mine. Field surveys in 2017 and 2018 showed that the pH of the SLB influent (initially 5–6) increased to approximately 8 in the drain between 24 and 45 m from the inlet. This increase was caused by limestone dissolution and resulted in the precipitation of hydroxides and/or carbonates of copper, zinc, and lead, as expected from theoretical calculations. Manganese and cadmium were removed within a pH range of approximately 7–8, which was lower than the pH at which they normally precipitate as hydroxides (pH 9–10). X-ray absorption near-edge structure analysis of the sediment indicated that δ-MnO2, which has a high cation-exchange capacity, was the predominant tetravalent manganese compound in the SLB rather than trivalent compound (MnOOH). Biological analysis indicates that microorganism activity of the manganese-oxidizing bacteria in the SLB provided an opportunity for δ-MnO2 formation, after which cadmium was removed by surface complexation with MnO2 (≡ MnOH0 + Cd2+  ⇄  ≡ MnOCd+  +  H+). These findings show that biological agents contributed to the precipitation of manganese and cadmium in the SLB, and suggest that their utilization could enhance the removal performance of the SLB.

scholarly journals Influence of Monovalent Cations on the Efficiency of Ferrous Ion Oxidation, Total Iron Precipitation, and Adsorptive Removal of Cr(VI) and As(III) in Simulated Acid Mine Drainage with Inoculation of Acidithiobacillus ferrooxidans

Metals ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 596 ◽  
Author(s):  
Yongwei Song ◽  
Heru Wang ◽  
Jun Yang ◽  
Yanxiao Cao
Keyword(s):  
Heavy Metal ◽  
Acid Mine Drainage ◽  
Acidithiobacillus Ferrooxidans ◽  
Mine Drainage ◽  
Metal Removal ◽  
Heavy Metal Removal ◽  
Monovalent Cations ◽  
Iron Minerals ◽  
Acid Mine ◽  
Removal Efficiencies

Acid mine drainage is highly acidic and contains large quantities of Fe and heavy metal elements. Thus, it is important to promote the transformation of Fe into secondary iron minerals that exhibit strong heavy-metal removal abilities. Using simulated acid mine drainage, this work analyzes the influence of monovalent cations (K+, NH4+, and Na+) on the Fe2+ oxidation and total Fe deposition efficiencies, as well as the phases of secondary iron minerals in an Acidithiobacillus ferrooxidans system. It also compares the Cr(VI) (K2Cr2O7) and As(III) (As2O3) removal efficiencies of different schwertmannites. The results indicated that high concentrations of monovalent cations (NH4+ ≥ 320 mmol/L, and Na+ ≥ 1600 mmol/L) inhibited the biological oxidation of Fe2+. Moreover, the mineralizing abilities of the three cations differed (K+ > NH4+ > Na+), with cumulative Fe deposition efficiencies of 58.7%, 28.1%, and 18.6%, respectively [n(M) = 53.3 mmol/L, cultivation time = 96 h]. Additionally, at initial Cr(VI) and As(III) concentrations of 10 and 1 mg/L, respectively, the Cr(VI) and As(III) removal efficiencies exhibited by schwertmannites acquired by the three mineralization systems differed [n(Na) = 53.3 > n(NH4) = 53.3 > n(K) = 0.8 mmol/L]. Overall, the analytical results suggested that the removal efficiency of toxic elements was mainly influenced by the apparent structure, particle size, and specific surface area of schwertmannite.

scholarly journals Novel hybrid metal loaded chelating resins for removal of toxic metals from acid mine drainage

2020 ◽  
Vol 81 (12) ◽  
pp. 2568-2584
Author(s):  
Caroline Lomalungelo Dlamini ◽  
Lueta-Ann De Kock ◽  
Kebede Keterew Kefeni ◽  
Bhekie Brilliance Mamba ◽  
Titus Alfred Makudali Msagati
Keyword(s):  
Acid Mine Drainage ◽  
Inductively Coupled Plasma ◽  
Mine Drainage ◽  
Metal Removal ◽  
Chelating Resin ◽  
Precipitation Method ◽  
Emission Spectrometry ◽  
Hybrid Resin ◽  
Acid Mine ◽  
Metal Levels

Abstract Iron (Fe), zirconium (Zr) and titanium (Ti) oxides nanoparticles were each embedded onto a weak acid chelating resin for support using the precipitation method to generate three hybrid adsorbents of hydrated Fe oxide (HFO-P), hydrated Zr oxide (HZO-P) and hydrated Ti oxide (HTO-P). This paper reports on the characterization, performance and potential of these generated nanoadsorbents in the removal of toxic metal ions from acid mine drainage (AMD). The optimum contact time, adsorbent dose and pH for aluminium (Al) (III) adsorption were established using the batch equilibrium technique. The metal levels were measured using inductively coupled plasma-optical emission spectrometry. The scanning electron microscopy–energy dispersive X-ray spectroscopy results confirmed the presence of the metal oxides within the hybrid resin beads. HFO-P, HZO-P and HTO-P adsorbed Al(III) rapidly from synthetic water with maximum adsorption capacities of 54.04, 58.36 and 40.10 mg/g, respectively, at initial pH 1.80 ± 0.02. The adsorption of Al(III) is of the second-order in nature (R2 > 0.98). The nanosorbents removed ten selected metals from environmental AMD and the metal removal efficiency was in the order HTO-P > HZO-P > HFO-P. All three hybrid nanosorbents can be used to remove metals from AMD; the choice would be dependent on the pH of the water to be treated.

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