scholarly journals Applications of chemostratigraphy in Middle Jurassic unconventional reservoirs in eastern Saudi Arabia

GeoArabia ◽  
2015 ◽  
Vol 20 (2) ◽  
pp. 79-110
Author(s):  
Neil W. Craigie

ABSTRACT The following study was undertaken on inorganic geochemical data acquired for 1,032 core and cuttings samples taken from Middle Jurassic and Upper Jurassic sediments encountered in five wells in eastern Saudi Arabia. The study sections extend from the upper part of the Middle Jurassic Dhruma Formation to the base of the Upper Jurassic Arab Formation, though the principal focus was on the intervening Hanifa and Tuwaiq Mountain formations where potential unconventional hydrocarbon reservoirs have been encountered. The principal objective of the study was to produce a chemostratigraphic framework for these wells. A secondary aim was to utilize the geochemical data to recognize organic-rich zones and seals. The study sections mainly comprise limestones, argillaceous limestones and calcareous mudrocks, with the latter lithologies being more abundant in the Tuwaiq Mountain and Hanifa formations. Although ICP-OES (Inductively Coupled Plasma–Optical Emission Spectrometry) and ICP-MS (Inductively Coupled Plasma–Mass Spectrometry) were used to acquire data for 50 elements, the chemostratigraphic framework is based on changes in the following ‘key’ elements and ratios: Nb/Cr, Zr/Nb, Zr/Cr, Cr/Th, Cr/Ta, La/Lu, Zr/Yb, Nb/Ti and Ti/U. Variations in these parameters are dependent on changes in source/provenance, reflecting increases or decreases in the abundances of particular detrital heavy minerals. The framework comprises a hierarchical order of 5 zones, 10 subzones and 8 divisions. The zones are labeled C0, C1, C2, C3 and C4 in ascending stratigraphic order, with C2, C3 and C4 being divided into subzones. Further divisions are also recognized in some subzones. Zones C1, C2, C3 and C4 are correlative between all five wells, with the absence of C0 in three of the wells, probably explained by the existence of this zone below the present sampling intervals of these wells. Unlike most zones, some of the subzones/divisions are not identified in all wells. This is mostly explained by local variations in provenance being responsible for the presence of some subzones/divisions in certain wells but not others. In other instances the absence of particular subzones and divisions may have resulted from localized erosion/non-deposition. Lithostratigraphic boundaries are relatively easy to place in wells 1, 2 and 3 where there are similar changes in e-log response in all three study sections. However, this does not hold true for wells 4 and 5 where e-log trends are more or less obvious. In these wells it has been necessary to utilize chemostratigraphy in combination with much more subtle increases/decreases in e-log trends to identify these boundaries. In addition to enabling the placement of lithostratigraphic boundaries in wells 4 and 5, it is possible to use chemostratigraphy to produce a correlation scheme of much higher resolution than was possible by employing lithostratigraphy. For example, The Dhruma Formation was previously defined as a single lithostratigraphic unit but a fourfold chemostratigraphic zonation of this formation is now proposed for wells 1 and 2 (i.e. zones C0, C1, subzone C2-1, division C2-2a which occur in ascending order). By comparing profiles plotted for U, Mo and TOC it is possible to identify units in which there is a relatively high proportion of organic matter. Sediments producing high values of these parameters may be considered potential unconventional reservoirs, with the most organic-rich zones present in wells 1 and 2. Potential seals have been identified above the ‘reservoir’ sections of these two wells. These produce elevated values of Al and K, inferring an abundance of clay minerals which may prevent or reduce the propagation of induced fractures during future ‘fracking’ operations conducted in the vicinity of these wells.

2016 ◽  
Vol 8 (1) ◽  
pp. 585-594 ◽  
Author(s):  
David A. Riley ◽  
Tim J. Pearce ◽  
Eliza Mathia ◽  
Ken Ratcliffe ◽  
John Martin

AbstractThe Namurian and Westphalian sequences from the onshore well Scaftworth-B2, located in the Gainsborough Trough, central England, have been analysed for whole-rock inorganic geochemical data via inductively coupled plasma optical emission spectrometry (ICP-OES) and mass spectrometry (MS). The changes within key elements, and elemental ratios, results in a chemostratigraphic zonation scheme consisting of eight chemostratigraphic sequences and 13 chemostratigraphic packages, providing the type zonation for the Bowland Shale and overlying formations. Mineralogical data are provided by whole rock X-ray diffraction (XRD) and are used to calibrate the mineral modelling in order to generate a modelled mineral log for the study well. Furthermore, the modelled mineralogy is then used to calculate a relative brittleness for the samples, which can then be collaborated with traditional rock properties data at a later date. Elemental data can also be used to model the relative abundance of detrital quartz and biogenic silica; while total silicon is detected by ICP, biogenic silica is not detected by XRD owing to its amorphous nature. Enrichment factors calculated from the inorganic elemental data suggest that the sediment was deposited in an unrestricted marine setting, which experienced periods of anoxia.


2019 ◽  
Vol 26 (4) ◽  
pp. 568-588
Author(s):  
Neil W. Craigie

The following chemostratigraphy study was conducted on Paleozoic sediments encountered in 14 wells in eastern Saudi Arabia. A total of 1500 samples were analysed by inductively coupled plasma optical emission spectrometry (ICP-OES) and inductively coupled plasma mass spectrometry (ICP-MS), with data acquired for 48 elements, ranging from Na to U in the periodic table. The aim was to utilize chemostratigraphy, in conjunction with existing biostratigraphic, lithostratigraphic and sedimentological data, to define the Hercynian Unconformity in each well and to recognize stratigraphic boundaries occurring above and below it. This was necessary as the unconformity eroded to different stratigraphic levels in each well, with Devonian, Silurian and Ordovician sediments found immediately below it in adjacent locations. In the absence of chemostratigraphic, biostratigraphic and sedimentological data, it is often very difficult to define this boundary and others using lithostratigraphy alone as many stratigraphic intervals yield similar gamma-ray (GR) log trends. For example, a low ‘blocky’ GR response is typical of both the Carboniferous Ghazal Member and the Ordovician Sarah Formation. Similarly, both the Silurian Sharawra Member and the Silurian–Devonian Tawil Formation produce a ‘ratty’ GR trend. Each stratigraphic member and formation was found to have distinctive chemostratigraphic, biostratigraphic, sedimentological and/or wireline log signatures.


2020 ◽  
Vol 16 ◽  
Author(s):  
Diogo L. R. Novo ◽  
Priscila T. Scaglioni ◽  
Rodrigo M. Pereira ◽  
Filipe S. Rondan ◽  
Gilberto S. Coelho Junior ◽  
...  

Background: Conventional analytical methods for phosphorus and sulfur determination in several matrices present normally analytical challenges regarding inaccuracy, detectability and waste generation. Objective: The main objective is proposing a green and feasible analytical method for phosphorus and sulfur determination in animal feed. Methods: Synergic effect between microwave and ultraviolet radiations during sample preparation was evaluated for the first time for the animal feed digestion associated with further phosphorus and sulfur determination by ion chromatography with conductivity detection. Dissolved carbon and residual acidity in final digests were used for the proposed method assessment. Phosphorus and sulfur values were compared with those obtained using conventional microwave-assisted wet digestion in closed vessels associated with inductively coupled plasma optical emission spectrometry and with those obtained using Association of Official Analytical Chemists International official method. Recovery tests and certified reference material analysis were performed. Animal feeds were analyzed using the proposed method. Results: Sample masses of 500 mg were efficiently digested using only 2 mol L -1 HNO3. The results obtained by the proposed method was not differing significantly (p > 0.05) from those obtained by the conventional and official methods. Suitable recoveries (from 94 to 99%), agreement with certified values (101 and 104%) and relative standard deviations (< 8%) were achieved. Phosphorus and sulfur content in commercial products varied in a wide range (P: 5,873 to 28,387 mg kg-1 and S: 2,165 to 4,501 mg kg-1 ). Conclusion: The proposed method is a green, safe, accurate, precise and sensitive alternative for animal feed quality control.


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