scholarly journals Potential of Betanin Natural Dye for Solar Cells Application

2020 ◽  
Author(s):  
Naoufel Ben Hamadi

Abstract Background: A photovoltaic cell, or solar cell, is an electronic component which, exposed to light, produces electricity thanks to the photovoltaic effect. Organic photovoltaic cells are photovoltaic cells of which at least the active layer consists of organic molecules. It has a yield of at least 15%. The future prospects of the research for solar cells application has required for the development in the field.Main body: Dye-sensitized solar cells are considered to be promising candidates for low-cost solar energy harvesting using sustainable and environmentally friendly materials. In general, solar cells sensitized to dyes consist of three parts: TiO2 sensitized to the photoanode dye with porous film on a transparent conductive glass, an electrolyte solution penetrating through the TiO2 anode film, and the conductive oxide transparent platinum glass as counter electrode.Conclusion: In this work, betanin dye was extracted from mature red fruits of Opuntia ficus indica and purified with fractional crystallization protocol using an 8:2 (v/v) ratio of ethyl acetate/ethanol. TiO2_films with different thickness values have been prepared CV and US sensitization of TiO2_films using betanin dye prove an enhancement on the uniformity distribution of the dye on the film in case of US method. Emission spectra of Dye_TiO2 films have been measured and show a hyperchromic shift of the emission intensity with the increase of the thickness due to the augmentation of betanin content. A comparison between the photovoltaic properties of prepared betanin_DSSC and N719 dye_DSSC reveals that betanin dye could be successfully proposed as a sensitizing dye in solar cell applications.

2020 ◽  
Vol 10 ◽  
Author(s):  
Naoufel Ben Hamadi

Background: A photovoltaic cell, or solar cell, is an electronic component which, exposed to light, produces electricity thanks to the photovoltaic effect. Organic photovoltaic cells are photovoltaic cells of which at least the active layer consists of organic molecules. It has a yield of at least 15%. The future prospects of the research for solar cells application has required for the development in the field. Objectives: In this work, we propose in this paper to study the potential of purified betanin dye on the DSSC applications. Methods: Extraction was elaborated under sonication conditions (25 kHz, 100 W) for 15 minutes. Various films of TiO2 with different thickness were prepared referring to doctor blade method on a FTO glass substrate. Results: The increase of the thickness value of dye_TiO2 films induces a hyperchromic shift of the emission intensity. Conclusion: In this work, betanin dye was extracted from mature red fruits of Opuntia ficus indica and purified with fractional crystallization protocol using an 8:2 (v/v) ratio of ethyl acetate/ethanol. TiO2_films with different thickness values have been prepared CV and US sensitization of TiO2_films using betanin dye prove an enhancement on the uniformity distribution of the dye on the film in case of US method. Emission spectra of Dye_TiO2 films have been measured and show a hyperchromic shift of the emission intensity with the increase of the thickness due to the augmentation of betanin content. A comparison between the photovoltaic properties of prepared betanin_DSSC and N719 dye_DSSC reveals that betanin dye could be successfully proposed as a sensitizing dye in solar cell applications.


2014 ◽  
pp. 319-346
Author(s):  
Salahuddin Qazi ◽  
Farhan A. Qazi

Solar radiation is plentiful and a clean source of power. However, despite the first practical use of silicon based solar cell more than 50 years ago, it has not been exploited to its full potential due to the high cost of electrical conversion on a per Watt basis. Many new kinds of photovoltaic cells such as multi-junction solar cells dye –sensitized solar cells and organic solar cell incorporating element of nanotechnology have been proposed to increase the efficiency and reduce the cost. Nanotechnology, in the form of quantum dots, nanorods, nanotubes, and grapheme, has been shown to enhance absorption of sunlight, makes low cost flexible solar panels and increases the efficiency of photovoltaic cells. The chapter reviews the state of current photovoltaic cells and challenges it presents. It also discusses the use of nanotechnology in the application of photovoltaic cells and future research directions to improve the efficiency of solar cells and reduce the cost.


Author(s):  
Salahuddin Qazi ◽  
Farhan A. Qazi

Solar radiation is plentiful and a clean source of power. However, despite the first practical use of silicon based solar cell more than 50 years ago, it has not been exploited to its full potential due to the high cost of electrical conversion on a per Watt basis. Many new kinds of photovoltaic cells such as multi-junction solar cells dye –sensitized solar cells and organic solar cell incorporating element of nanotechnology have been proposed to increase the efficiency and reduce the cost. Nanotechnology, in the form of quantum dots, nanorods, nanotubes, and grapheme, has been shown to enhance absorption of sunlight, makes low cost flexible solar panels and increases the efficiency of photovoltaic cells. The chapter reviews the state of current photovoltaic cells and challenges it presents. It also discusses the use of nanotechnology in the application of photovoltaic cells and future research directions to improve the efficiency of solar cells and reduce the cost.


2014 ◽  
Vol 16 (44) ◽  
pp. 24173-24177 ◽  
Author(s):  
J. Park ◽  
N. Barbero ◽  
J. Yoon ◽  
E. Dell'Orto ◽  
S. Galliano ◽  
...  

A new series of low cost dibranched symmetrical blue-greenish squaraines showing interesting photovoltaic properties and photostabilities is reported.


2021 ◽  
Vol 5 (11) ◽  
pp. 288
Author(s):  
José A. Castillo-Robles ◽  
Enrique Rocha-Rangel ◽  
José A. Ramírez-de-León ◽  
Frida C. Caballero-Rico ◽  
Eddie N. Armendáriz-Mireles

Human beings are attempting to take advantage of renewable natural resources by using solar cells. These devices take the sun’s radiation and convert it into electrical energy. The issue with traditional silicon-based solar cells is their manufacturing costs and environmental problems. For this reason, alternatives have been developed within the solar cell field. One of these alternatives is the dye-sensitized solar cell (DSSC), also known as Grätzel solar cells. DSSCs are a type of solar cell that mimics photosynthesis. They have a photoanode, which is formed by a semiconductor film sensitized with a dye. Some of their advantages include low-cost manufacturing, eco-friendly materials use, and suitability for most environments. This review discusses four important aspects, with two related to the dye, which can be natural or synthetic. Herein, only natural dyes and their extraction methods were selected. On the other hand, this paper discusses the nanostructures used for DSSCs, the TiO2 nanostructure being the most reported; it recently reached an efficiency level of 10.3%. Finally, a review on the novelties in DSSCs technology is presented, where it is observed that the use of Catrin protein (cow brain) shows 1.45% of efficiency, which is significantly lower if compared to Ag nanoparticles doped with graphene that report 9.9% efficiency.


2021 ◽  
Vol 1028 ◽  
pp. 151-156
Author(s):  
Ayunita Chintia Celline ◽  
Astria Yuliani Subagja ◽  
Sri Suryaningsih ◽  
Annisa Aprilia ◽  
Lusi Safriani

Dye-sensitized solar cells (DSSC) are solar cells that has a great potential to be applied as renewable energy conversion. The major advantages of DSSC are the ease of fabrication process and low cost of production. Despite of these advantages, the efficiency of DSSC for converting light into electricity is still low. It is due to charge recombination in DSSC which limits the photoanode performance. Numerous efforts has been carried out to increase the efficiency of DSSC, one of which is by adding reduced graphene oxide (rGO) to titanium oxide (TiO2) to obtain TiO2-rGO nanocomposite. In this study, the synthesis of TiO2-rGO nanocomposites was carried out with concentration of rGO are 0.6, 0.8, and 1.0 wt% to amount of TiO2. We have done some characterizations to confirm the result of synthesized TiO2-rGO. UV-Vis measurement shows the addition of rGO has widened the absorption up to 400 nm. The FT-IR spectrum confirms that the rGO peaks appears at wavelength of 1400, 1600, dan 1700 cm-1 which exhibited the vibration C-O, C=C, and C=O stretching from COOH groups, respectively. The highest efficiency of DSSC with photoanode TiO2-rGO nanocomposite is 0.09% which was obtained from 0.8 wt% of rGO.


2012 ◽  
Vol 545 ◽  
pp. 405-409 ◽  
Author(s):  
Nurul Huda Yusoff ◽  
Mohamad Firdaus Rosle ◽  
Surani Buniran

Dye sensitized solar cell (DSSC) is a new class of low-cost solar cell, that belongs to third generation solar cells in thin film based. It is based on a semiconductor formed between a photo-sensitized anode and an electrolyte, known as photoelectrochemical system. A lot of research has been conducted due to their interesting potential for low-cost, lightweight, disposable and having cell efficiency up to 10%. This paper reports the fabrication of dye sensitized solar cells using TiO2 nanoparticles and chlorophyll as active layer. TiO2 nanoparticles were prepared by sol-gel method while the chlorophyll was extracted from Pandanus amaryllifolius (Pandan leaf). TiO2 film was prepared on ITO coated glass using dip coating technique and then immersed overnight in the chlorophyll solution. An electrolyte solution composed of PC-LiClO4 was injected into the cell before sealed using glass that was coated with Pt as top electrode. An active area of 4.48 cm2 was fabricated by black masking the front side. The performance of the device was studied by observing the current-voltage characteristics of the device in dark at ambient temperature and under illumination of 100 mW/cm2 light. It was found that the device showed rectifier property in the dark and able to generate electrical current under light.


Author(s):  
U. Fegade

Solar energy is an attractive renewable energy source across the globe that can help overcome the energy crises and has the ability to replace conventional resources. Hybrid solar cells have higher conversion efficiency. In the current chapter the research related to the carbon nanotubes, organic and inorganic solar cell, dye-sensitized solar cells and tandem solar cells are reviewed. The organic solar cells are most suitable and economic, but it has low efficiency of up to 15%. The inorganic solar cells are very expensive and have high efficiency of up to 46% and are used in space applications. The hybrid solar cell is the third type and the perovskite tandem has already proven to be quite efficient (17%) and low cost, mostly because of the cheap materials that are being used.


2021 ◽  
Vol 2021 ◽  
pp. 1-12
Author(s):  
Shibu Joseph ◽  
Albin John P. Paul Winston ◽  
S. Muthupandi ◽  
P. Shobha ◽  
S. Mary Margaret ◽  
...  

This paper is aimed at how to select, extract, and characterize natural dyes and to use them as sensitizers in dye-sensitized solar cells (DSSCs). Dyes obtained from fresh sources of annatto fruits, black plums, cactus fruits, turmeric roots, and red spinach leaves were used as sensitizers. The dye pigments were analyzed using UV-Vis spectrophotometer and FT-IR for the characterization of their spectral properties. The combination from Titanium dioxide paste with the powdered nanotubes was used as photoanodes for DSSCs. The photovoltaic properties of the DSSCs such as efficiency, fill factor, open-circuit voltage, and short circuit current were studied using a standard illumination of air-mass 1.5 global (AM 1.5 G) having an irradiance of 100 mW/cm2. The highest power conversion efficiencies (η) of 0.7% was achieved for the DSSCs fabricated using dye extracted from annatto fruits and 0.4% each for dyes extracted from black plum fruits and cactus fruits, respectively. The widespread accessibility of these fruits, roots, and leaves and ease of extraction of dyes from these ordinarily available natural resources render them unique and low-cost candidates for solar cell fabrication.


2012 ◽  
Vol 550-553 ◽  
pp. 2036-2039 ◽  
Author(s):  
Than Than Win ◽  
Yin Maung Maung ◽  
Ko Ko Kyaw Soe

TiO2-ZrO2 fine binary oxide was firstly prepared by mechanochemical milling process to be homogeneous binary oxide powder. TiO2-ZrO2 paste was deposited onto microscopic glass slide by rolling. It was immersed in the Rose solution at different pH levels and annealed at 100°C for 2h. Carbon catalyst obtained from soot and HCl was coated onto another glass slide and it was used as counter electrode. Two glass slides were offset and two binder clips were used to hold the electrodes together. Photovoltaic properties of TiO2-ZrO2 cells were measured at different pH levels and it was expected to utilize the dye sensitized solar cells application. The highest efficiency (0.23%) of the dye sensitize solar cell was found to be rose extract at pH level 4.1. The cell exhibited the potential to be a low-cost photovoltaic option.


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