scholarly journals Potential of Betanin natural dye for solar cells application

2020 ◽  
Vol 10 ◽  
Author(s):  
Naoufel Ben Hamadi

Background: A photovoltaic cell, or solar cell, is an electronic component which, exposed to light, produces electricity thanks to the photovoltaic effect. Organic photovoltaic cells are photovoltaic cells of which at least the active layer consists of organic molecules. It has a yield of at least 15%. The future prospects of the research for solar cells application has required for the development in the field. Objectives: In this work, we propose in this paper to study the potential of purified betanin dye on the DSSC applications. Methods: Extraction was elaborated under sonication conditions (25 kHz, 100 W) for 15 minutes. Various films of TiO2 with different thickness were prepared referring to doctor blade method on a FTO glass substrate. Results: The increase of the thickness value of dye_TiO2 films induces a hyperchromic shift of the emission intensity. Conclusion: In this work, betanin dye was extracted from mature red fruits of Opuntia ficus indica and purified with fractional crystallization protocol using an 8:2 (v/v) ratio of ethyl acetate/ethanol. TiO2_films with different thickness values have been prepared CV and US sensitization of TiO2_films using betanin dye prove an enhancement on the uniformity distribution of the dye on the film in case of US method. Emission spectra of Dye_TiO2 films have been measured and show a hyperchromic shift of the emission intensity with the increase of the thickness due to the augmentation of betanin content. A comparison between the photovoltaic properties of prepared betanin_DSSC and N719 dye_DSSC reveals that betanin dye could be successfully proposed as a sensitizing dye in solar cell applications.

2020 ◽  
Author(s):  
Naoufel Ben Hamadi

Abstract Background: A photovoltaic cell, or solar cell, is an electronic component which, exposed to light, produces electricity thanks to the photovoltaic effect. Organic photovoltaic cells are photovoltaic cells of which at least the active layer consists of organic molecules. It has a yield of at least 15%. The future prospects of the research for solar cells application has required for the development in the field.Main body: Dye-sensitized solar cells are considered to be promising candidates for low-cost solar energy harvesting using sustainable and environmentally friendly materials. In general, solar cells sensitized to dyes consist of three parts: TiO2 sensitized to the photoanode dye with porous film on a transparent conductive glass, an electrolyte solution penetrating through the TiO2 anode film, and the conductive oxide transparent platinum glass as counter electrode.Conclusion: In this work, betanin dye was extracted from mature red fruits of Opuntia ficus indica and purified with fractional crystallization protocol using an 8:2 (v/v) ratio of ethyl acetate/ethanol. TiO2_films with different thickness values have been prepared CV and US sensitization of TiO2_films using betanin dye prove an enhancement on the uniformity distribution of the dye on the film in case of US method. Emission spectra of Dye_TiO2 films have been measured and show a hyperchromic shift of the emission intensity with the increase of the thickness due to the augmentation of betanin content. A comparison between the photovoltaic properties of prepared betanin_DSSC and N719 dye_DSSC reveals that betanin dye could be successfully proposed as a sensitizing dye in solar cell applications.


Modeling and simulation of photovoltaic cells or PV cell is becoming important as it provides an easy platform to perform studies on photovoltaic cells and the design and analysis of the system based on photovoltaic cells. In this paper, we present our study of the ordinary photovoltaic module on the basis of one diode and two diode models. Studies are extended to solar cells as solar cells are similar to photodiodes. Performance of the solar cells may be described in terms of ideality factor (α), which decreases with temperature and is observed to affect the performance of the PV cell. PV systems exhibit better performance with diodes having higher values for α. In this paper, our efforts are to study the effects of α on Current and Power versus Voltage characteristics of the solar cells. MATLAB simulation of solar cell systems is a simple and elegant mechanism useful for designing and modeling the framework of the solar power plant


RSC Advances ◽  
2015 ◽  
Vol 5 (130) ◽  
pp. 107566-107574 ◽  
Author(s):  
Xin Liu ◽  
Yuan Xie ◽  
Xinyi Cai ◽  
Yunchuan Li ◽  
Hongbin Wu ◽  
...  

Four solution-processable acceptor–donor–acceptor structured organic molecules with isoindigo as terminal acceptor units and different aromatic rigid planar cores as donor units were designed and synthesized as the acceptor materials in organic solar cells (OSCs).


Coatings ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 329 ◽  
Author(s):  
Dong Shin ◽  
Suk-Ho Choi

It is necessary to develop semitransparent photovoltaic cell for increasing the energy density from sunlight, useful for harvesting solar energy through the windows and roofs of buildings and vehicles. Current semitransparent photovoltaics are mostly based on Si, but it is difficult to adjust the color transmitted through Si cells intrinsically for enhancing the visual comfort for human. Recent intensive studies on translucent polymer- and perovskite-based photovoltaic cells offer considerable opportunities to escape from Si-oriented photovoltaics because their electrical and optical properties can be easily controlled by adjusting the material composition. Here, we review recent progress in materials fabrication, design of cell structure, and device engineering/characterization for high-performance/semitransparent organic and perovskite solar cells, and discuss major problems to overcome for commercialization of these solar cells.


2014 ◽  
pp. 319-346
Author(s):  
Salahuddin Qazi ◽  
Farhan A. Qazi

Solar radiation is plentiful and a clean source of power. However, despite the first practical use of silicon based solar cell more than 50 years ago, it has not been exploited to its full potential due to the high cost of electrical conversion on a per Watt basis. Many new kinds of photovoltaic cells such as multi-junction solar cells dye –sensitized solar cells and organic solar cell incorporating element of nanotechnology have been proposed to increase the efficiency and reduce the cost. Nanotechnology, in the form of quantum dots, nanorods, nanotubes, and grapheme, has been shown to enhance absorption of sunlight, makes low cost flexible solar panels and increases the efficiency of photovoltaic cells. The chapter reviews the state of current photovoltaic cells and challenges it presents. It also discusses the use of nanotechnology in the application of photovoltaic cells and future research directions to improve the efficiency of solar cells and reduce the cost.


Author(s):  
Salahuddin Qazi ◽  
Farhan A. Qazi

Solar radiation is plentiful and a clean source of power. However, despite the first practical use of silicon based solar cell more than 50 years ago, it has not been exploited to its full potential due to the high cost of electrical conversion on a per Watt basis. Many new kinds of photovoltaic cells such as multi-junction solar cells dye –sensitized solar cells and organic solar cell incorporating element of nanotechnology have been proposed to increase the efficiency and reduce the cost. Nanotechnology, in the form of quantum dots, nanorods, nanotubes, and grapheme, has been shown to enhance absorption of sunlight, makes low cost flexible solar panels and increases the efficiency of photovoltaic cells. The chapter reviews the state of current photovoltaic cells and challenges it presents. It also discusses the use of nanotechnology in the application of photovoltaic cells and future research directions to improve the efficiency of solar cells and reduce the cost.


2016 ◽  
Vol 3 ◽  
pp. 64-85
Author(s):  
Liam Caruana ◽  
Thomas Nommensen ◽  
Toan Dinh ◽  
Dennis Tran ◽  
Robert McCormick

In the 21st century, global energy consumption has increased exponentially and hence, sustainable energy sources are essential to accommodate for this. Advancements within photovoltaics, in regards to light trapping, has demonstrated to be a promising field of dramatically improving the efficiency of solar cells. This improvement is done by using different nanostructures, which enables solar cells to use the light spectrum emitted more efficiently. The purpose of this meta study is to investigate irreversible entropic losses related to light trapping. In this respect, the observation is aimed at how nanostructures on a silicon substrate captures high energy incident photons. Furthermore, different types of nanostructures are then investigated and compared, using the étendue ratio during light trapping. It is predicted that étendue mismatching is a parasitic entropy generation variable, and that the matching has an effect on the open circuit voltage of the solar cell. Although solar cells do have their limiting efficiencies, according to the Shockley-Queisser theory and Yablonovitch limit, with careful engineering and manufacturing practices, these irreversible entropic losses could be minimized. Further research in energy losses, due to entropy generation, may guide nanostructures and photonics in exceeding past these limits.Keywords: Photovoltaic cell; Shockley-Queisser; Solar cell nanostructures; Solar cell intrinsic and extrinsic losses; entropy; étendue; light trapping; Shockley Queisser; Geometry; Meta-study


2015 ◽  
Vol 3 (17) ◽  
pp. 9264-9270 ◽  
Author(s):  
Hyun Bin Kim ◽  
Iseul Im ◽  
Yeomin Yoon ◽  
Sang Do Sung ◽  
Eunji Kim ◽  
...  

In a novel heterojunction solar cell employing CH3NH3PbBr3 (MAPbBr3) as the light absorber, the introduction of a carboxylate monolayer on the mesoporous TiO2 surfaces significantly enhances JSC as well as VOC.


2015 ◽  
Vol 44 (1) ◽  
pp. 26-32 ◽  
Author(s):  
F. Aziz ◽  
Z. Ahmad ◽  
S.M. Abdullah ◽  
K. Sulaiman ◽  
M.H. Sayyad

Purpose – The purpose of this paper is to study the optical and electrical characteristics of a single-junction solar cell based on a green-colour dye vanadyl 2,9,16, 23-tetraphenoxy-29H, 31H-phthalocyanine (VOPcPhO). The use of soluble vanadyl phthalocyanine derivative makes it very attractive for photovoltaic applications due to its tunable properties and high solubility. Design/methodology/approach – A photoactive layer of VOPcPhO has been sandwiched between indium tin oxide (ITO) and aluminium (Al) electrodes to produce a ITO/PEDOT:PSS/VOPcPhO/Al photovoltaic device. The VOPcPhO thin film is deposited by a simple spin coating technique. To obtain the optimal thickness for the solar cell device, different thicknesses of the photoactive layer, achieved by manipulating the spin rate, have been investigated. Findings – The device exhibited photovoltaic effect with the values of Jsc, Voc and FF equal to 5.26 × 10-6 A/cm2, 0.621 V and 0.33, respectively. The electronic parameters of the cell have been obtained from the analysis of current-voltage characteristics measured in dark. The values of ideality factor and barrier height were found to be 2.69 and 0.416 eV, respectively. The optical examination showed that the material is sensitive to light in the UV region between 270 nm and 410 nm, as well as in the visible spectrum within the range of 630 nm and 750 nm. Research limitations/implications – The solar cell based on a single layer of vanadyl phthalocyanine derivative results in low efficiency, which can be enhanced by introducing a variety of donor materials to form bulk heterojunction solar cells. Practical implications – The spin coating technique provides a simple, less expensive and effective approach for preparing thin films. Originality/value – A novel thin-film, single-junction organic solar cell, fabricated by using VOPcPhO, has been investigated for the first time ever. The vanadyl phthalocyanine derivative together with a donor material will have potential application for improved efficiency of the solar cells.


2015 ◽  
Vol 730 ◽  
pp. 173-177
Author(s):  
Yu Wen Tang

Solar energy is an inexhaustible and renewable energy without environmental pollution. Solar energy can be used in three kinds of forms: solar thermal energy, photochemical conversion and photovoltaic power generation. Among these, the final form of photovoltaic power generation is electricity which can be transported, applied and stored conveniently. On the basis of photovoltaic effect, solar cell is developed as a new technology to convert light energy into electrical energy using semiconductor. Up to now the two key problems of the development of solar cells are how to improve the conversion efficiency and reduce cost. Therefore, the material and production technology used for solar cells are discussed based on improving conversion efficiency in this article.


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