Fabrication of Dye Sensitized Solar Cell Based on TiO2 Nanoparticles and Chlorophyll from Pandan Leaf as Active Layer

2012 ◽  
Vol 545 ◽  
pp. 405-409 ◽  
Author(s):  
Nurul Huda Yusoff ◽  
Mohamad Firdaus Rosle ◽  
Surani Buniran
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Active Layer ◽  
Low Cost ◽  
Sol Gel ◽  
Dye Sensitized Solar Cells ◽  
Electrical Current ◽  
Dip Coating ◽  
Dye Sensitized Solar Cell ◽  
Dye Sensitized

Dye sensitized solar cell (DSSC) is a new class of low-cost solar cell, that belongs to third generation solar cells in thin film based. It is based on a semiconductor formed between a photo-sensitized anode and an electrolyte, known as photoelectrochemical system. A lot of research has been conducted due to their interesting potential for low-cost, lightweight, disposable and having cell efficiency up to 10%. This paper reports the fabrication of dye sensitized solar cells using TiO2 nanoparticles and chlorophyll as active layer. TiO2 nanoparticles were prepared by sol-gel method while the chlorophyll was extracted from Pandanus amaryllifolius (Pandan leaf). TiO2 film was prepared on ITO coated glass using dip coating technique and then immersed overnight in the chlorophyll solution. An electrolyte solution composed of PC-LiClO4 was injected into the cell before sealed using glass that was coated with Pt as top electrode. An active area of 4.48 cm2 was fabricated by black masking the front side. The performance of the device was studied by observing the current-voltage characteristics of the device in dark at ambient temperature and under illumination of 100 mW/cm2 light. It was found that the device showed rectifier property in the dark and able to generate electrical current under light.

scholarly journals Sol Gel Synthesized Nanosilica as Photoanode Material for Dye Sensitized Solar Cells (DSSCs) System

2014 ◽  
Vol 625 ◽  
pp. 110-113
Author(s):  
Stephanie Lau Chai Tying ◽  
Coswald Stephen Sipaut ◽  
Jedol Dayou ◽  
Rachel Fran Mansa
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Band Gap ◽  
Surface Area ◽  
High Surface ◽  
Sol Gel ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized Solar Cell ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Dye-sensitized solar cells (DSSCs) have been extensively studied due to their promising potential for high efficiency, low production cost and eco-friendly production. The photoanode of DSSCs is traditionally composed of randomly packed TiO2 nanoparticles which have large specific surface area and suitable band gap (3.2 eV) for the effective injection of electrons from the dye molecules to the semiconductor. However, its high surface charge recombination rate accounts for its low efficiency. Alternatively, silica which is chemically inert, thermally stable, high surface area, and inexpensive can be used to substitute TiO2 as photoanode material. However, bulk silica has a wide band gap of 8.9 eV and its band gap need to be narrowed in order to use it as photoanode materials. Thus, in this study, the effect of nanosilica photoanode and its particle size on the performance of dye sensitized solar cell are investigated and characterized. The result is then compared with the fumed silica and conventional TiO2 DSSCs. Although the results shows that photon-electron conversion is inferior compared to TiO2 photoanode, it has a great potential as the fabrication cost is low and more environmental friendly.Keywords : Dye Sensitized Solar Cell, Photoanode material, Nanosilica, Sol gel synthesis

Synthesis of TiO2-rGO Nanocomposite and its Application as Photoanode of Dye-Sensitized Solar Cell (DSSC)

2021 ◽  
Vol 1028 ◽  
pp. 151-156
Author(s):  
Ayunita Chintia Celline ◽  
Astria Yuliani Subagja ◽  
Sri Suryaningsih ◽  
Annisa Aprilia ◽  
Lusi Safriani
Keyword(s):  
Graphene Oxide ◽  
Solar Cells ◽  
Solar Cell ◽  
Low Cost ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized Solar Cell ◽  
Dye Sensitized ◽  
Reduced Graphene ◽  
Ft Ir ◽  
Sensitized Solar Cells

Dye-sensitized solar cells (DSSC) are solar cells that has a great potential to be applied as renewable energy conversion. The major advantages of DSSC are the ease of fabrication process and low cost of production. Despite of these advantages, the efficiency of DSSC for converting light into electricity is still low. It is due to charge recombination in DSSC which limits the photoanode performance. Numerous efforts has been carried out to increase the efficiency of DSSC, one of which is by adding reduced graphene oxide (rGO) to titanium oxide (TiO2) to obtain TiO2-rGO nanocomposite. In this study, the synthesis of TiO2-rGO nanocomposites was carried out with concentration of rGO are 0.6, 0.8, and 1.0 wt% to amount of TiO2. We have done some characterizations to confirm the result of synthesized TiO2-rGO. UV-Vis measurement shows the addition of rGO has widened the absorption up to 400 nm. The FT-IR spectrum confirms that the rGO peaks appears at wavelength of 1400, 1600, dan 1700 cm-1 which exhibited the vibration C-O, C=C, and C=O stretching from COOH groups, respectively. The highest efficiency of DSSC with photoanode TiO2-rGO nanocomposite is 0.09% which was obtained from 0.8 wt% of rGO.

ZnO nanocrystalline powder prepared by sol-gel method for photoanode of dye sensitized solar cells application

2018 ◽  
Vol 1 (88) ◽  
pp. 12-17 ◽  
Author(s):  
M. Szindler ◽  
M.M. Szindler ◽  
P. Boryło
Keyword(s):  
Zinc Oxide ◽  
Solar Cells ◽  
Solar Cell ◽  
Sol Gel ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized Solar Cell ◽  
Gel Method ◽  
Sol Gel Method ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Purpose: The article presents the results of research on ZnO nanopowder prepared using sol-gel method that is the easy process enabling us to control shape and size of particles The purpose of this article is to synthesized ZnO nanostructures by sol-gel method and characterized them for use in dye sensitized solar cells. Design/methodology/approach: Zinc oxide nanopowder was synthesized by using zinc acetate dehydrate as a precursor. The prepared nanopowder has been subjected to structural analysis using a transmission electron microscope (TEM). Scanning Electron Microscopic (SEM) images were taken with a Zeiss Supra 35. Qualitative studies of chemical composition were also performed using the Energy Dispersive Spectrometer (EDS). The structure of zinc oxide was investigated by X-ray crystallography The absorbance of zinc oxide layers with and without dye were measured by Thermo Scientific Evolution 220 spectrophotometer equipped with a xenon lamp in the wavelength range from 190 nm to 1100 nm. Findings: Sol-gel method allows the formation of uniform nanoparticles of zinc oxide. The nanoparticles have been successfully used in photoelectrode of dye sensitized solar cell. The light harvesting efficiency of the electrode it remains in a wide spectral range above 85%, which gives better results than in the case of titanium dioxide. Research limitations/implications: The next step in the research will be to investigate the ZnO/NiO composite on the properties of the photoelectrode of dye sensitized solar cell. Practical implications: he unique properties of produced ZnO nanostructural materials have caused their interest in such fields as medicine, transparent electronics and photovoltaics. Originality/value: The ZnO nanoparticles were prepared using sol-gel method and then effectively used in the photoanode of dye sensitized solar cell.

Synthesis of TiO2 Nanopowders and their Applications in Dye-Sensitized Solar Cell

2010 ◽  
Vol 663-665 ◽  
pp. 848-851
Author(s):  
Jian Sun ◽  
Yan Xiang Wang ◽  
Min Xu ◽  
Ting Li Ma ◽  
Xue Yun Fan
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
High Efficiency ◽  
Low Cost ◽  
Short Circuit ◽  
Sol Gel ◽  
Dye Sensitized Solar Cells ◽  
Open Circuit ◽  
Dye Sensitized ◽  
Tio2 Nanopowders

Dye-sensitized solar cells (DSSC) are currently attracting widespread interest for the conversion of sunlight into electricity because of their low cost and high efficiency. In these cells, photo-anode is one of the key components for high power conversion efficiencies. In this paper, TiO2 nanopowders were prepared by the non-hydrolytic sol-gel method using TiCl4 as precursor, absolute ethanol and isopropanol as oxygen donor. Several different TiO2 nanopowders were used to fabricate TiO2 solar cells, and properties of TiO2 solar cells were characterized. The solar cell prepared with grainsize 50~80nm TiO2 nanopowders generated a short-circuit photocurrent of 13.17 mA/cm2, an open-circuit photovoltage of 789 mV, a fill factor of 69.8% and the efficiency of 7.25% under the light intensity of 100 mW/cm2.

scholarly journals Hibiscus Leachate Dye-Based Low-Cost and Flexible Dye-Sensitized Solar Cell Prepared by Screen Printing

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2748
Author(s):  
Congjun Cao ◽  
Tianning Yang ◽  
Guangxue Chen
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Screen Printing ◽  
Low Cost ◽  
Dye Sensitized Solar Cells ◽  
Open Circuit ◽  
Dye Sensitized Solar Cell ◽  
Counter Electrodes ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Although the price of dye-sensitized solar cells is lower than other solar cells, they still contain some high-cost materials, such as transparent conductive substrates, dyes (ruthenium dyes, organic dyes, etc.), and platinum counter electrodes. To solve this problem, a dye-sensitized solar cell based on hibiscus leaching solution and carbon black–silver electrodes was prepared by screen printing. The prepared low-cost dye-sensitized solar cells were flexible. The open-circuit voltage (Voc) of the obtained dye-sensitized solar cell is 0.65 V, the current density (Jsc) is 90 μA/cm², and the fill factor (FF) is 0.241.

Kinetics of dye regeneration in liquid electrolyte unveils efficiency of 10.5% in dye-sensitized solar cells

2018 ◽  
Vol 6 (42) ◽  
pp. 11444-11456 ◽  
Author(s):  
Jonnadula Venkata Suman Krishna ◽  
Narra Vamsi Krishna ◽  
Towhid H. Chowdhury ◽  
Suryaprakash Singh ◽  
Idriss Bedja ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Power Conversion ◽  
Dye Sensitized Solar Cells ◽  
Liquid Electrolyte ◽  
Dye Sensitized Solar Cell ◽  
Dye Sensitized ◽  
Dye Regeneration ◽  
Sensitized Solar Cells ◽  
Kinetics Of

We have designed and synthesised four novel porphyrin sensitizers for dye-sensitized solar cell applications and shown power conversion efficiency of 10.5%.

Correlating cobalt redox couples to photovoltage in the dye-sensitized solar cell

2018 ◽  
Vol 47 (34) ◽  
pp. 11942-11952 ◽  
Author(s):  
Kitty Y. Chen ◽  
Phil A. Schauer ◽  
Brian O. Patrick ◽  
Curtis P. Berlinguette
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Redox Potential ◽  
Linear Correlation ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized Solar Cell ◽  
Redox Mediators ◽  
Dye Sensitized ◽  
Redox Couples ◽  
Sensitized Solar Cells

Two sets of structurally analogous Co(iii/ii)-based redox mediators were incorporated in the dye-sensitized solar cells and a linear correlation was demonstrated between redox potential and photovoltage.

Modelling and Validation of Transmittance from Nanocrystalline Titania film for Photoanodic Action in Dye-Sensitized Solar Cells

2015 ◽  
Vol 4 (1) ◽  
Author(s):  
Divya Jyoti
Keyword(s):  
Solar Cells ◽  
Tin Oxide ◽  
Incident Light ◽  
Sol Gel ◽  
Dye Sensitized Solar Cells ◽  
Dip Coating ◽  
Optical Simulation ◽  
Nanocrystalline Tio2 ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

AbstractA four phase model air/glass/indium doped tin oxide/TiO2 has been studied by modifying Rouard’s model to calculate the final transmittance from TiO2 layer to be used as photoanode in dye-sensitized solar cells. An optical simulation for the reflectance and transmittance has been executed for the constructed nanocrystalline TiO2 films. To validate the theoretical results TiO2 film has been deposited onto indium doped tin oxide (ITO) layer by sol-gel dip coating technique. It has been found that the incident light suffers losses by 5-15% on passage through TiO2 coated ITO layer. Experimentally it has been observed on the basis of efficiency value that meso-nano combination is the best candidate to be used as photoanode in a dye-sensitize solar cell.

Dye-sensitized solar cells containing mesoporous TiO2spheres as photoanodes and methyl sulfate anion based biionic liquid electrolytes

2015 ◽  
Vol 3 (12) ◽  
pp. 6383-6391 ◽  
Author(s):  
Jia-De Peng ◽  
Chuan-Pei Lee ◽  
D. Velayutham ◽  
V. Suryanarayanan ◽  
Kuo-Chuan Ho
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Solid State ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized Solar Cell ◽  
Methyl Sulfate ◽  
Sulfate Anion ◽  
Dye Sensitized ◽  
Liquid Electrolytes ◽  
Sensitized Solar Cells

A quasi-solid state dye-sensitized solar cell with the photoanode film of mesoporous TiO2spheres exhibited an efficiency of 6.18% and unfailing stability for 1200 h at 50 °C.

Ruthenium(ii) complexes incorporating carbazole–diazafluorene based bipolar ligands for dye sensitized solar cell applications

2017 ◽  
Vol 41 (13) ◽  
pp. 5605-5612 ◽  
Author(s):  
Radhakrishnan Sivakumar ◽  
Rodrigo Recabarren ◽  
Sekar Ramkumar ◽  
Arumugam Manivel ◽  
Jans Alzate-Morales ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized Solar Cell ◽  
Ancillary Ligands ◽  
Dye Sensitized ◽  
New Type ◽  
Sensitized Solar Cells

A new type of ruthenium sensitizers, S3 and S4, consisting of carbazole–diazafluorene based bipolar ancillary ligands have been synthesized and characterized for dye sensitized solar cells.

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