Extraordinary Spin-Wave Thermal Conductivity in Low-Dimensional Copper Oxides

2015 ◽  
Author(s):  
David Cahill
2000 ◽  
Vol 626 ◽  
Author(s):  
Harald Beyer ◽  
Joachim Nurnus ◽  
Harald Böttner ◽  
Armin Lambrecht ◽  
Lothar Schmitt ◽  
...  

ABSTRACTThermoelectric properties of low dimensional structures based on PbTe/PbSrTe-multiple quantum-well (MQW)-structures with regard to the structural dimensions, doping profiles and levels are presented. Interband transition energies and barrier band-gap are determined from IR-transmission spectra and compared with Kronig-Penney calculations. The influence of the data evaluation method to obtain the 2D power factor will be discussed. The thermoelectrical data of our layers show a more modest enhancement in the power factor σS2 compared with former publications and are in good agreement with calculated data from Broido et al. [5]. The maximum allowed doping level for modulation doped MQW structures is determined. Thermal conductivity measurements show that a ZT enhancement can be achieved by reducing the thermal conductivity due to interface scattering. Additionally promising lead chalcogenide based superlattices for an increased 3D figure of merit are presented.


Nanoscale ◽  
2021 ◽  
Author(s):  
Hongying Wang ◽  
Yajuan Cheng ◽  
Zheyong Fan ◽  
Yangyu Guo ◽  
Zhongwei Zhang ◽  
...  

Nanophononic metamaterials have broad applications in fields such as heat management, thermoelectric energy conversion, and nanoelectronics. Phonon resonance in pillared low-dimensional structures has been suggested to be a feasible approach...


1998 ◽  
Vol 545 ◽  
Author(s):  
G. Chen ◽  
S. G. Volz ◽  
T. Borca-Tasciuc ◽  
T. Zeng ◽  
D. Song ◽  
...  

AbstractUnderstanding phonon heat conduction mechanisms in low-dimensional structures is of critical importance for low-dimensional thermoelectricity. In this paper, we discuss heat conduction mechanisms in two-dimensional (2D) and one-dimensional (1D) structures. Models based on both the phonon wave picture and particle picture are developed for heat conduction in 2D superlattices. The phonon wave model, based on the acoustic wave equations, includes the effects of phonon interference and tunneling, while the particle model, based on the Boltzmann transport equation, treats the internal as well interface scattering of phonons. For 1D systems, both the Boltzmann transport equation and molecular dynamics simulation approaches are employed. Comparing the modeling results with experimental data suggest that the interface scattering of phonons plays a crucial role in the thermal conductivity of low-dimensional structures. We also discuss the minimum thermal conductivity of low-dimensional structures based on a generalized thermal conductivity integral, and suggest that the minimum thermal conductivities of low-dimensional systems may differ from those of their corresponding bulk materials. The discussion leads to alternative ways to reduce thermal conductivity based on the propagating phonon modes.


1964 ◽  
Vol 136 (2A) ◽  
pp. A426-A428 ◽  
Author(s):  
D. C. McCollum ◽  
R. L. Wild ◽  
J. Callaway

2001 ◽  
Vol 691 ◽  
Author(s):  
Terry M. Tritt

ABSTRACTRecently, there has been a renewed interest in thermoelectric material research. There are a number of different systems of potential thermoelectric (TE) materials that are under investigation by various research groups. Some of these research efforts focus on minimizing lattice thermal conductivity while other efforts focus on materials that exhibit large power factors. An overview of some of the requirements and strategies for the investigation and optimization of a new system of materials for potential thermoelectric applications will be discussed. Some of the newer concepts such as low-dimensional systems and Slack's phononglass, electron-crystal concept will be discussed. Current strategies for minimizing lattice thermal conductivity and also minimum requirements for thermopower will be presented. The emphasis of this paper will be to identify some of the more recent promising bulk materials and discuss the challenges and issues related to each. This paper is targeted more at “newcomers” to the field and does not discuss some of the very interesting results that are being reported in the thin film and superlattice materials. Some of the bulk materials which will be discussed include complex chalcogenides (e.g.CsBi4Te6 and pentatellurides such as the Zr1−XHfXTe5 system), half-Heusler alloys (e.g. TiNiSn1−XSbX), ceramic oxides (NaCo4O2), skutterudites (e.g. YbXCo4−XSb12 or EuXCo4−XSb12) and clathrates (e.g. Sr8Ga16Ge30). Each of these systems is distinctly different yet each exhibits some prospect as a potential thermoelectric material. Results will be presented and discussed on each system of materials.


2009 ◽  
Vol 1166 ◽  
Author(s):  
Sabah Bux ◽  
Jean-Pierre Fleurial ◽  
Richard G. Blair ◽  
Pawan K. Gogna ◽  
Thierry Caillat ◽  
...  

AbstractPoint defect scattering via the formation of solid solutions to reduce the lattice thermal conductivity has been an effective method for increasing ZT in state-of-the-art thermoelectric materials such as Si-Ge, Bi2Te3-Sb2Te3 and PbTe-SnTe. However, increases in ZT are limited by a concurrent decrease in charge carrier mobility values. The search for effective methods for decoupling electronic and thermal transport led to the study of low dimensional thin film and wire structures, in particular because scattering rates for phonons and electrons can be better independently controlled. While promising results have been achieved on several material systems, integration of low dimensional structures into practical power generation devices that need to operate across large temperature differential is extremely challenging. We present achieving similar effects on the bulk scale via high pressure sintering of doped and undoped Si and Si-Ge nanoparticles. The nanoparticles are prepared via techniques that include high energy ball milling of the pure elements. The nanostructure of the materials is confirmed by powder X-ray diffraction, transmission electron microscopy, scanning electron microscopy, and dynamic light scattering. Thermal conductivity measurements on the densified pellets show a drastic 90% reduction in the lattice contribution at room temperature when compared to doped single crystal Si. Additionally, Hall effect measurements show a much more limited degradation in the carrier mobility. The combination of low thermal conductivity and high power factor in heavily doped n-type nanostructured bulk Si leads to an unprecedented increase in ZT at 1275 K by a factor of 3.5 over that of single crystalline samples. Experimental results on both n-type and p-type Si are discussed in terms of the impact of the size distribution of the nanoparticles, doping impurities and nanoparticle synthesis processes.


2005 ◽  
Vol 127 (1) ◽  
pp. 108-114 ◽  
Author(s):  
Deyu Li ◽  
Scott T. Huxtable ◽  
Alexis R. Abramson ◽  
Arun Majumdar

Low-dimensional nanostructured materials are promising candidates for high efficiency solid-state cooling devices based on the Peltier effect. Thermal transport in these low-dimensional materials is a key factor for device performance since the thermoelectric figure of merit is inversely proportional to thermal conductivity. Therefore, understanding thermal transport in nanostructured materials is crucial for engineering high performance devices. Thermal transport in semiconductors is dominated by lattice vibrations called phonons, and phonon transport is often markedly different in nanostructures than it is in bulk materials for a number of reasons. First, as the size of a structure decreases, its surface area to volume ratio increases, thereby increasing the importance of boundaries and interfaces. Additionally, at the nanoscale the characteristic length of the structure approaches the phonon wavelength, and other interesting phenomena such as dispersion relation modification and quantum confinement may arise and further alter the thermal transport. In this paper we discuss phonon transport in semiconductor superlattices and nanowires with regards to applications in solid-state cooling devices. Systematic studies on periodic multilayers called superlattices disclose the relative importance of acoustic impedance mismatch, alloy scattering, and crystalline imperfections at the interfaces. Thermal conductivity measurements of mono-crystalline silicon nanowires of different diameters reveal the strong effects of phonon-boundary scattering. Experimental results for Si/SiGe superlattice nanowires indicate that different phonon scattering mechanisms may disrupt phonon transport at different frequencies. These experimental studies provide insight regarding the dominant mechanisms for phonon transport in nanostructures. Finally, we also briefly discuss Peltier coolers made from nanostructured materials that have shown promising cooling performance.


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