scholarly journals Electrochemical Impedance spectroscopy (EIS) and study of iron corrosion inhibition by turmeric roots Extract (TRE) in hydrochloric acid solution

2018 ◽  
Vol 0 (0) ◽  
pp. 0-0
Author(s):  
Kholod ALMZARZIE ◽  
aHmad falah ◽  
ayman masrri ◽  
hassan kellawi
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Hydrochloric Acid ◽  
Impedance Spectroscopy ◽  
Acid Solution ◽  
Corrosion Inhibition ◽  
Hydrochloric Acid Solution ◽  
Electrochemical Impedance ◽  
Iron Corrosion

scholarly journals Electrodeposited Benzothiazole Phthalocyanines for Corrosion Inhibition of Aluminium in Acidic Medium

2020 ◽  
Vol 2020 ◽  
pp. 1-11
Author(s):  
Nnaemeka Nnaji ◽  
Njemuwa Nwaji ◽  
Tebello Nyokong
Keyword(s):  
Hydrochloric Acid ◽  
Acid Solution ◽  
Corrosion Inhibition ◽  
Hydrochloric Acid Solution ◽  
Electrochemical Impedance ◽  
X Ray Diffraction ◽  
Corrosion Attack ◽  
X Ray ◽  
Eis Measurements ◽  
Better Than

Tetrakis[(benzo[d]thiazol-2-yl-thio) phthalocyaninato] gallium(III)chloride (1) and tetrakis[(benzo[d]thiazol-2ylphenoxy) phthalocyaninato] gallium(III)chloride (2) were successfully electrodeposited onto aluminium for corrosion retardation in 1.0 M hydrochloric acid solution. The aim of this study was to compare the corrosion resistance of electrodeposited metallated phthalocyanines. Scanning electron microscopy, X-ray diffraction, electrochemical impedance spectroscopy (EIS), and polarization confirmed the aluminium corrosion inhibition potentials of complexes 1 and 2. EIS and polarization techniques showed that complex 2 performed better than complex 1, with values from EIS measurements of 82% for 1 and 86% for 2 in 1.0 M hydrochloric acid solution. The importance of electrodeposition in industries and a dearth of research on the use of electrodeposited metallated phthalocyanines necessitated this study, and results show that coatings formed by electrodeposition of 1 and 2 onto aluminium reduced its susceptibility to corrosion attack.

scholarly journals New triazepine carboxylate derivatives: correlation between corrosion inhibition property and chemical structure

2020 ◽  
Vol 11 (1) ◽  
pp. 23-42 ◽  
Author(s):  
K. Alaoui ◽  
Y. El Kacimi ◽  
M. Galai ◽  
H. Serrar ◽  
R. Touir ◽  
...  
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Hydrochloric Acid ◽  
Impedance Spectroscopy ◽  
Mild Steel ◽  
Acid Medium ◽  
Corrosion Inhibition ◽  
Electrochemical Impedance ◽  
Protective Film ◽  
Hydrochloric Acid Medium ◽  
Inhibition Property

AbstractIn this investigation, attempts have been made to study the corrosion inhibition properties of three new triazepine carboxylate compounds for mild steel in 1.0 M hydrochloric acid medium. The evaluation was carried out using mass loss, electrochemical impedance spectroscopy and polarization curves measurement. Impedance diagrams and Bode plots for uninhibited and inhibited systems were analyzed using Zview program. The fitted data observed trails in nearly the same pattern as the experimental results. It is showed that triazepine carboxylate compounds are very good inhibitors for mild steel corrosion in 1.0 M hydrochloric acid medium which act as mixed-type inhibitors. So, the inhibition efficiency was increased with inhibitor concentration in the order Cl–Me–CN > Me–CN > Cl–Me–CO2Et which depended on their molecular structures. Electrochemical impedance spectroscopy showed that all compounds act by the formation of a protective film at the metal surface. Surface analyses via SEM and Optical 3D profilometry were used to investigate the morphology of the steels before and after immersion in 1.0 M HCl solution containing inhibitors. The correspondence between inhibition property and molecular structure of the triazepine carboxylate compounds was investigated, using density functional theory (DFT). Experimental and DFT study was further supported by molecular dynamic simulations study.

scholarly journals Corrosion of the stainless steel 316Ti in 10% hydrochloric and sulfuric acid

2020 ◽  
Vol 61 (4) ◽  
pp. 339-345
Author(s):  
Branimir Grgur
Keyword(s):  
Weight Loss ◽  
Stainless Steel ◽  
Sulfuric Acid ◽  
Electrochemical Impedance Spectroscopy ◽  
Austenitic Stainless Steel ◽  
Hydrochloric Acid ◽  
Impedance Spectroscopy ◽  
Acid Solution ◽  
Linear Polarization ◽  
Electrochemical Impedance

The corrosion of the austenitic stainless steel 316Ti is investigated in 10% hydrochloric and 10% sulfuric acid, by the means of linear polarization, electrochemical impedance spectroscopy, polarization, and weight loss measurements. It is concluded that 316Ti is unstable in 10% hydrochloric acid and passive in 10% sulfuric acid solution.

scholarly journals Corrosion Inhibition Effect of 4-Hydroxy-N′-[(E)-(1H-indole-2-ylmethylidene)] Benzohydrazide on Mild Steel in Hydrochloric Acid Solution

2014 ◽  
Vol 2014 ◽  
pp. 1-11 ◽  
Author(s):  
Preethi Kumari ◽  
Prakash Shetty ◽  
Suma A. Rao
Keyword(s):  
Hydrochloric Acid ◽  
Acid Solution ◽  
Mild Steel ◽  
Corrosion Inhibition ◽  
Hydrochloric Acid Solution ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Langmuir Adsorption ◽  
Solution Interface ◽  
Inhibition Performance

The inhibition performance and adsorption behaviour of 4-hydroxy-N′-[(E)-(1H-indole-2-ylmethylidene)] benzohydrazide (HIBH) on mild steel in 1 M HCl solution were tested by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The inhibition efficiency of HIBH increases with increase in inhibitor concentration in the temperature range 30–60°C. Polarisation curves indicate that HIBH is a mixed inhibitor, affecting both cathodic and anodic corrosion currents. The adsorption process of HIBH at the mild steel/hydrochloric acid solution interface obeyed Langmuir adsorption isotherm model and inhibition takes place by mixed adsorption, predominantly chemisorption. The activation and thermodynamic parameters for the corrosion inhibition process were calculated to elaborate the mechanism of corrosion inhibition.

scholarly journals Novel pyrimidine-bichalcophene derivatives as corrosion inhibitors for copper in 1 M nitric acid solution

RSC Advances ◽  
2021 ◽  
Vol 11 (41) ◽  
pp. 25314-25333
Author(s):  
Mai A. Khaled ◽  
Mohamed A. Ismail ◽  
Ahmed. A. El-Hossiany ◽  
Abd El-Aziz S. Fouda
Keyword(s):  
Weight Loss ◽  
Electrochemical Impedance Spectroscopy ◽  
Nitric Acid ◽  
Impedance Spectroscopy ◽  
Acid Solution ◽  
Nitric Acid Solution ◽  
Potentiodynamic Polarization ◽  
Corrosion Inhibitors ◽  
Electrochemical Impedance ◽  
Pyrimidine Derivatives

This study targets the investigation of three pyrimidine derivatives (MA-1230, MA-1231, MA-1232) for the prevention of corrosion on copper in 1 M HNO3via weight loss (WL), potentiodynamic polarization (PDP), and electrochemical impedance spectroscopy (EIS) techniques.

scholarly journals Investigation of the corrosion inhibition of carbon steel in hydrochloric acid solution by using ginger roots extract

RSC Advances ◽  
2017 ◽  
Vol 7 (40) ◽  
pp. 24576-24588 ◽  
Author(s):  
H. S. Gadow ◽  
M. M. Motawea
Keyword(s):  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Acid Solution ◽  
Corrosion Inhibition ◽  
Hydrochloric Acid Solution ◽  
Adsorption Behavior ◽  
Different Temperatures ◽  
Hcl Solution

The inhibitive effect and adsorption behavior of ginger roots extract (GRE) on the corrosion of carbon steel in 1.0 M HCl solution at different temperatures were investigated.

scholarly journals Electrochemical and Surface Morphological Studies of Carbon Steel Corrosion by a Novel Polynuclear Schiff Base in HCl Solution

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
K. S. Shaju ◽  
K. Joby Thomas ◽  
Vinod P. Raphael ◽  
Aby Paul
Keyword(s):  
Weight Loss ◽  
Schiff Base ◽  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Adsorption Isotherm ◽  
Acid Solution ◽  
Corrosion Inhibition ◽  
Hydrochloric Acid Solution ◽  
Inhibition Efficiency ◽  
Morphological Studies

The corrosion inhibition efficiency of a potential polynuclear Schiff base, (s)-2-(anthracene-9 (10H)-ylidene amino)-5-guanidinopentanoic acid (A9Y5GPA), on carbon steel (CS) in 1 M hydrochloric acid solution has been investigated using weight loss measurements, electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization studies. The corrosion inhibition efficiencies of parent amine [(s)-2-amino-5-guanidinopentanoic acid] and parent ketone (anthracene-9 (10H)-one) on carbon steel in 1.0 M hydrochloric acid solution have also been investigated using weight loss studies. The electrochemical and weight loss data established that the inhibition efficiency on CS increases with the increase in the concentration of inhibitor, A9Y5GPA. The adsorption of A9Y5GPA obeys the Langmuir adsorption isotherm. Thermodynamic parameters (Kads, ΔGads0) were calculated using the adsorption isotherm. Activation parameters of the corrosion process (Ea, ΔH* and ΔS*) were also calculated from the corrosion rates obtained from temperature studies. Tafel plot analysis revealed that A9Y5GPA acts as a mixed-type inhibitor. A probable inhibition mechanism was also proposed. Surface morphology of the carbon steel specimens in the presence and absence of the inhibitor was evaluated by SEM analysis.

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