Behaviour of nonylphenol ethoxylates in sewage treatment plants in Japan – biotransformation and ecotoxicity

2000 ◽  
Vol 42 (7-8) ◽  
pp. 23-30 ◽  
Author(s):  
M. Fujita ◽  
M. Ike ◽  
K. Mori ◽  
H. Kaku ◽  
Y. Sakaguchi ◽  
...  
Keyword(s):  
Biological Treatment ◽  
Estrogenic Activity ◽  
Sewage Treatment ◽  
Secondary Effluent ◽  
Nonylphenol Ethoxylates ◽  
Sewage Treatment Plants ◽  
Metabolic Intermediates ◽  
Average Value ◽  
Final Effluent ◽  
By Products

Behavior of nonylphenol polyethoxylates (NPnEOs, n; number of ethoxy units) in 40 full-scale sewage treatment plants (STPs) in Japan was studied. Primary effluent (PE), secondary effluent (SE) and final effluent (FE) samples were collected from the STPs, and NPnEOs, their metabolic intermediates and related halogenated derivatives were quantitatively analyzed. Parent NPnEOs (n=4–18) were detected at concentrations between 5.1 and 1035 μg/l with the average value of 296 μg/l in the PEs from all the STPs, indicating widespread pollution of NPnEOs in Japan. The analyses of SEs revealed that normal biological treatment can relatively efficiently remove NPnEOs, however, the biotransformation led to the formation of biologically-refractory metabolites like nonylphenol (NP), NPnEOs with shorter ethoxy chains (n=1–3; NP1-3EO) and nonylphenol carboxylic acids (NP1-3EC). Halogenated (chlorinated or brominated) NPnEOs and/or NPnECs (n=1–2), which are considered to be produced as by-products during the disinfection processes using chlorination, were also found in SEs and/or FEs from 25 STPs. The ecotoxicity assays showed that the metabolic intermediates of NPnEOs possess higher acute toxicity against Daphnia magna and estrogenic activity than the parent surfactant NPnEOs.

Removal of endocrine-disrupting chemicals by ozonation in sewage treatment

2006 ◽  
Vol 54 (10) ◽  
pp. 123-132 ◽  
Author(s):  
Heqing Zhang ◽  
Harumi Yamada ◽  
Sung-Eun Kim ◽  
Hyo-sang Kim ◽  
Hiroshi Tsuno
Keyword(s):  
Endocrine Disrupting Chemicals ◽  
Sewage Treatment ◽  
Secondary Effluent ◽  
Batch Reactors ◽  
Efficient Removal ◽  
Batch Mode ◽  
Endocrine Disrupting Chemical ◽  
Sewage Treatment Plants ◽  
Endocrine Disrupting ◽  
By Products

Treatment experiments by two laboratory scale semi-batch reactors and a demonstration scale process were both carried out to evaluate endocrine disrupting chemical removal characteristics by ozonation in sewage treatment. In the semi-batch mode experiments, secondary effluent and primary effluent of sewage treatment plants were ozonated respectively. Behaviour of brominated by-products was also evaluated. The results based on these studies indicated that estrogenicity in wastewater can be removed by ozonation effectively. The condition of ozonation until dissolved ozone concentration increased to 0.1 mg/L, which corresponded to 1 mgO3/mgC and 0.4 mgO3/mgC of ozone consumption per initial DOC for secondary effluent and primary effluent, respectively, is proposed as an appropriate operational condition for efficient removal of EDCs as well as UV254 and SUVA without production of brominated by-products.

Presence of Phenolic Compounds in Sewage, Effluent and Sludge from Municipal Sewage Treatment Plants

1982 ◽  
Vol 14 (4-5) ◽  
pp. 143-150 ◽  
Author(s):  
F B DeWalle ◽  
D A Kalman ◽  
R Dills ◽  
D Norman ◽  
E S K Chian ◽  
...  
Keyword(s):  
Sewage Treatment ◽  
Municipal Sewage ◽  
Sewage Effluent ◽  
Capillary Gc ◽  
Digested Sludge ◽  
Calculated Concentration ◽  
Sewage Treatment Plants ◽  
Anaerobically Digested Sludge ◽  
Final Effluent ◽  
Dimethyl Phenol

A total of 25 municipal sewage treatment plants were sampled, 10 of which were resampled, to determine the quantity of phenolics in the sewage, final effluent and the anaerobically digested sludge using capillary GC/MS/DS/techniques. The study noted in decreasing order of frequency in raw sewage: phenol, pentachloro-phenol, dimethyl phenol, 3-methyl, 4-chlorophenol, 2,4,6-trichloro-phenol, 2,4-dichlorophenol, 2-nitrophenol, 2-chlorophenol, 2,4-dinitro-6-methylphenol and 2,4-dinitrophenol. The maximum concentration of phenol in sewage and sludge was 2800 ppb and 4460 respectively, while similar values for pentachlorophenol were 58 and 1200 ppb. Statistically calculated concentration reductions for phenol and dimethyl phenol were generally greater than noted for tri- and pentachlorophenol. Low decreases or increases were noted for monochlorophenol and especially for dichlorophenol as a result of the chloronation of the final effluent.

scholarly journals Distribution and Removal of Pharmaceuticals in Liquid and Solid Phases in the Unit Processes of Sewage Treatment Plants

2020 ◽  
Vol 17 (3) ◽  
pp. 687 ◽  
Author(s):  
Junwon Park ◽  
Changsoo Kim ◽  
Youngmin Hong ◽  
Wonseok Lee ◽  
Hyenmi Chung ◽  
...  
Keyword(s):  
Removal Efficiency ◽  
Biological Treatment ◽  
Sewage Treatment ◽  
Biofilm Reactor ◽  
Relative Distribution ◽  
Biological Processes ◽  
Sewage Treatment Plants ◽  
Treatment Processes ◽  
Mass Load ◽  
Removal Efficiencies

In this study, we analyzed 27 pharmaceuticals in liquid and solid phase samples collected from the unit processes of four different sewage treatment plants (STPs) to evaluate their distribution and behavior of the pharmaceuticals. The examination of the relative distributions of various categories of pharmaceuticals in the influent showed that non-steroidal anti-inflammatory drugs (NSAIDs) were the most dominant. While the relative distribution of antibiotics in the influent was not high (i.e., 3%–5%), it increased to 14%–30% in the effluent. In the four STPs, the mass load of the target pharmaceuticals was reduced by 88%–95% mainly in the biological treatment process, whereas the ratio of pharmaceuticals in waste sludge to those in the influent (w/w) was only 2%. In all the STPs, the removal efficiencies for the stimulant caffeine, NSAIDs (acetaminophen, naproxen, and acetylsalicylic acid), and the antibiotic cefradine were high; they were removed mainly by biological processes. Certain compounds, such as the NSAID ketoprofen, contrast agent iopromide, lipid regulator gemfibrozil, and antibiotic sulfamethoxazole, showed varying removal efficiencies depending on the contribution of biodegradation and sludge sorption. In addition, a quantitative meta-analysis was performed to compare the pharmaceutical removal efficiencies of the biological treatment processes in the four STPs, which were a membrane bioreactor (MBR) process, sequencing batch reactor (SBR) process, anaerobic–anoxic–oxic (A2O) process, and moving-bed biofilm reactor (MBBR) process. Among the biological processes, the removal efficiency was in the order of MBR > SBR > A2O > MBBR. Among the tertiary treatment processes investigated, powdered activated carbon showed the highest removal efficiency of 18%–63% for gemfibrozil, ibuprofen, ketoprofen, atenolol, cimetidine, and trimethoprim.

Analysis and occurrence of typical endocrine-disrupting chemicals in three sewage treatment plants

2010 ◽  
Vol 62 (11) ◽  
pp. 2501-2509 ◽  
Author(s):  
L. Y. Wang ◽  
X. H. Zhang ◽  
N. F. Y. Tam
Keyword(s):  
Biological Treatment ◽  
Endocrine Disrupting Chemicals ◽  
Sewage Treatment ◽  
Average Concentration ◽  
Gas Chromatography Mass Spectrometry ◽  
Wet Season ◽  
Physical Treatment ◽  
Sewage Treatment Plants ◽  
Treatment Processes ◽  
Endocrine Disrupting

Seven typical endocrine-disrupting chemicals (EDCs), including bisphenol A (BPA), 4-tert-octylphenol (OP), estrone (E1), estradiol (E2), 17α-estradiol (17α-E2), estriol (E3) and 17α-ethinylestradiol (EE2) in wastewater, were simultaneously determined with gas chromatography–mass spectrometry (GC–MS). Samples, including influents, effluents and wastewater of different unit processes, were taken seasonally from three different sewage treatment plants. The result showed that BPA and EE2 were the two main types of EDCs in all the samples. The average concentration of BPA were in the range of 268.1–2,588.5 ng l−1 in influents and 34.0–3,099.6 ng l−1 in effluents, while EE2 ranging from 133.1 to 403.2 ng l−1 and from 35.3 to 269.1 ng l−1, respectively. Seasonal change of EDCs levels in effluents was obvious between wet season and dry season. Besides, BPA and E3 could be effectively removed by the biological treatment processes (oxidation ditch and A2/O) with the unit removal of 64–91% and 63–100% for each compound, while other five EDCs had moderate or low removal rates. The study also proved that physical treatment processes, including screening, primary sedimentation and pure aeration, had no or little effect on EDCs removal.

Occurrence and Elimination of Nonylphenol Ethoxylates and Metabolites in Municipal Wastewater and Effluents

1998 ◽  
Vol 33 (3) ◽  
pp. 389-402-402 ◽  
Author(s):  
Hing-Biu Lee ◽  
Thomas E. Peart
Keyword(s):  
Carboxylic Acids ◽  
Municipal Wastewater ◽  
Sewage Treatment ◽  
Elimination Rate ◽  
Sewage Treatment Plant ◽  
Treatment Plant ◽  
Nonylphenol Ethoxylates ◽  
Wastewater Samples ◽  
One Year ◽  
Final Effluent

Abstract A survey of the concentrations of nonylphenol ethoxylates (NPnEO) and their metabolites in wastewater samples collected from a Canadian sewage treatment plant using primary and secondary treatment is presented. Twenty-four-hour composite raw sewage, primary effluent and final effluent samples were collected monthly over a one-year period. Levels of NPnEO (n = 1 to 17) and their metabolites, nonylphenol (NP) and nonylphenoxy carboxylic acids (NPnEC), in these samples were determined by HPLC and GC/MS methods. While ca. 85% of the total alkylphenolics in raw sewage are ethoxylates, the major component (nearly 80%) in the final effluent was in the form of carboxylic acids. During this study period, the median total alkylphenolic concentrations in raw sewage and final effluent were 526 and 248 nmol/L, respectively, representing an overall elimination rate of 53%. The estimated daily discharge of the nonylpheno-lics to the aquatic environment varied from 15 to 44 moles, with a median value of 20 moles. These data suggested that conventional sewage treatments are ineffective in the removal of the surfactant-derived metabolites.

Biological Waste Water Rehabilitation of Sugar Factories by Algocoenosis Correction

2017 ◽  
Vol 21 (3) ◽  
pp. 16-20 ◽  
Author(s):  
V.V. Kul’nev ◽  
V.I. Stupin ◽  
A.A. Borzenkov
Keyword(s):  
Waste Water ◽  
Biological Treatment ◽  
Sewage Treatment ◽  
Sewage Treatment Plant ◽  
Treatment Plant ◽  
Domestic Sewage ◽  
Total Water ◽  
Sewage Treatment Plants ◽  
Total Water Consumption

The article deals with theoretical and practical aspects of biological waste water rehabilitation of sugar factories by algocoenosis correction. This technology allows you to transfer domestic sewage treatment plant of filtration mode fields in the biological treatment ponds mode, significantly reducing the area of sewage treatment plants, thus improving the quality of treated waste water, which will, in turn, use them repeatedly reducing total water consumption.

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