Kinetics for ammonium ion removal using a three-dimensional electrode system

2013 ◽  
Vol 67 (1) ◽  
pp. 168-173 ◽  
Author(s):  
Qicheng Qiao ◽  
Yuemin Zhao ◽  
Lizhang Wang
Keyword(s):  
Rate Constant ◽  
Current Density ◽  
Three Dimensional ◽  
Electrode System ◽  
Experimental Results ◽  
Ammonium Ion ◽  
Ion Removal ◽  
First Order Kinetics ◽  
Accurate Design ◽  
Chlorine Ions

Electrochemical oxidation of ammonium ions (NH4+) by using a three-dimensional electrode (TDE) composed of IrO2–Ta2O5/Ti anode and bamboo carbon was carried out in this paper. Experimental results reveal that the NH4+ oxidation follows first-order kinetics at lower NH4+ concentration and the rate constant is highly dependent on the applied current density, dosage of chlorine ions and initial NH4+ concentration. In addition, increasing current density, more Cl− dosage and higher initial NH4+ concentration are beneficial for NH4+ removal. By inspecting the relation between rate constant and those operating factors, an overall empirical equation for estimation of the rate constant of NH4+ oxidation is presented. The estimated model is in good agreement with the experimental results and it could also be used for accurate design of the TDE system.

Electrochemical treatment of residual ammonia nitrogen in biologically pretreated coking wastewater with three-dimensional electrodes

2011 ◽  
Vol 63 (11) ◽  
pp. 2732-2736 ◽  
Author(s):  
Xu-wen He ◽  
Li-yuan Liu ◽  
Hao Wang ◽  
Gong Zhang ◽  
Jing-wen Gong ◽  
...  
Keyword(s):  
Current Density ◽  
Three Dimensional ◽  
Surface Characteristics ◽  
Electrochemical Treatment ◽  
Ammonia Nitrogen ◽  
Electrode System ◽  
Coking Wastewater ◽  
Two Dimensional ◽  
Electrode Distance ◽  
Good Surface

The electrochemical oxidation of the residual ammonia nitrogen contained in biologically pretreated coking wastewater using three-dimensional electrode system was studied. The results show the Ti/RuO2/IrO2 anode plates and the coke have good surface characteristics for the purpose of this study. In addition, studies also show that the three-dimensional electrode system should be able to give a satisfied solution to the residual bio-refractory ammonia nitrogen in biologically pretreated coking wastewater in comparison to conventional two-dimensional electrodes. At coke size of 10–20 mesh, electrode distance of 1.0 cm and current density of 4.5 mA/cm2, the residual ammonia nitrogen in the three-dimensional electrode system was almost completely removed in 60 min.

Tertiary Treatment of Paper Industries Effluent with Advanced Electrochemical Oxidation Process in the Presence of Modified Bentonite Powdery Electrodes

2013 ◽  
Vol 690-693 ◽  
pp. 1065-1068 ◽  
Author(s):  
Zhen Wang ◽  
Ze Sheng Cheng ◽  
Yu Liu ◽  
Na Na Bo ◽  
Ying Liu
Keyword(s):  
Removal Efficiency ◽  
Current Density ◽  
Paper Industry ◽  
Three Dimensional ◽  
Electrode System ◽  
Pulp And Paper ◽  
Tertiary Treatment ◽  
Modified Bentonite ◽  
Cost Treatment ◽  
Pulp And Paper Effluent

Tertiary treatment wascarried out to treat pulp and paper effluent from secondary treatment processby a three-dimensional electrode system equipped with modifiedbentonites as powdery electrode. The cetyl trimethylammonium bromide modified bentonite (CTAB-bent) and hydroxy-aluminum pillaredorganic bentonite (OH-Al-CTAB-bent) were synthesized and characterized by XRDand FTIR spectroscopy analysis.The impacts such as the dosage of particle electrode, electrolysis times,current density were on the COD removal efficiency and decolorization effect ofeffluent were also investigated. The results showed that the experimentscarried out by three-dimensional electrode system with OH-Al-CTAB-bent weresufficient for the COD and color removal efficiency. A current density of 30mA/cm2, electrolysis time of 40min, and the particle electrodedosage of 1.6g/L were selected as an optimum conditions that allows fast andlow cost treatment. The effluent can achieve the discharge standard of waterpollutants for pulp and paper industry (GB3544-2008) after electrolysis.

Morphological and Photodecomposition Rate Constant Study of PVC Films Doped with Sulfadiazine Tin(IV) Complexes

2020 ◽  
Vol 14 (2) ◽  
pp. 88
Author(s):  
Emad Yousif
Keyword(s):  
Radiation Exposure ◽  
Uv Radiation ◽  
Rate Constant ◽  
Experimental Results

This article focus on the calculation of photodecomposition rate constant of PVC films that containing sulfadiazine tin(IV) complexes 1-3 as photostabilzers during UV radiation exposure. This constant calculated as a method for evaluating the efficiency of sulfadiazine tin(IV) complexes 1-3 when used as a PVC photostabilizers after 300 hours of irradiation. The experimental results showed that sulfadiazine tin(IV) complexes 1-3 have reduced the rate of photodecomposition constant value of PVC films significantly with comparison to PVC (blank).

Three-dimensional porous copper-decorated bismuth-based nanofoam for boosting electrochemical reduction of CO2 to formate

2021 ◽  
Author(s):  
Yingchun Zhang ◽  
Changsheng Cao ◽  
Xintao Wu ◽  
Qi-Long Zhu
Keyword(s):  
Current Density ◽  
High Current Density ◽  
Three Dimensional ◽  
Co2 Reduction ◽  
Reduction Reaction ◽  
High Current ◽  
Porous Copper ◽  
Reduction Of Co2 ◽  
Co2 Reduction Reaction ◽  
Wide Potential

Bismuth (Bi)-based nanomaterials are considered as the promising electrocatalysts for electrocatalytic CO2 reduction reaction (CO2RR), but it is challenging to achieve high current density and selectivity in a wide potential...

Conical SNA using fuzzy k-medoids based on user experience

2021 ◽  
pp. 002072092098849
Author(s):  
Poonam Rani ◽  
MPS Bhatia ◽  
Devendra K Tayal
Keyword(s):  
Social Networks ◽  
Social Network ◽  
User Experience ◽  
Three Dimensional ◽  
Experimental Results ◽  
Dynamic Parameters ◽  
Clustering Method ◽  
Cone Model ◽  
Intelligent Approach ◽  
Conical Model

The paper presents an intelligent approach for the comparison of social networks through a cone model by using the fuzzy k-medoids clustering method. It makes use of a geometrical three-dimensional conical model, which astutely represents the user experience views. It uses both the static as well as the dynamic parameters of social networks. In this, we propose an algorithm that investigates which social network is more fruitful. For the experimental results, the proposed work is employed on the data collected from students from different universities through the Google forms, where students are required to rate their experience of using different social networks on different scales.

Research on Transition Zones of Spherical Surface Parts in 3D Rolling Process

2014 ◽  
Vol 687-691 ◽  
pp. 3-6
Author(s):  
Da Ming Wang ◽  
Ming Zhe Li ◽  
Zhong Yi Cai
Keyword(s):  
Sheet Metal ◽  
Spherical Surface ◽  
Three Dimensional ◽  
Rolling Process ◽  
Experimental Results ◽  
Transition Zones ◽  
Spherical Surfaces ◽  
Sheet Width ◽  
Forming Precision ◽  
Roll Gap

3D rolling is a novel technology for three-dimensional surface parts. In this process, by controlling the gap between the upper and lower forming rolls, the sheet metal is non-uniformly thinned in thickness direction, and the longitudinal elongation of the sheet metal is different along the transverse direction, which makes the sheet metal generate three-dimensional deformation. In this paper, the transition zones of spherical surface parts in 3D rolling process are investigated. Spherical surface parts with the same widths but different lengths are simulated in condition of the same roll gap, and their experimental results are presented. The forming precision of forming parts and the causes of transition zones in the head and tail regions are analyzed through simulated results. The simulated and experimental results show that the lengths of transition zones of spherical surfaces in the head and tail regions are fixed values in condition of the same sheet width and roll gap.

Preparation, Solubility, Infrared Spectra and Radiolysis of Tetramethylammonium Hydrogenselenate Monohydrate and Lithium Tetramethylammonium Selenate Tetrahydrate

2006 ◽  
Vol 71 (3) ◽  
pp. 411-422 ◽  
Author(s):  
David Havlíček ◽  
Libor Turek ◽  
Jiří Plocek ◽  
Zdeněk Mička
Keyword(s):  
Chemical Analysis ◽  
Rate Constant ◽  
Infrared Spectra ◽  
Molecular Spectroscopy ◽  
Anhydrous Salt ◽  
First Order ◽  
First Order Kinetics ◽  
New Compounds

Solubility in the (Me4N)2SeO4-H2SeO4-H2O and (Me4N)2SeO4-Li2SeO4-H2O systems were studied. The new compounds, tetramethylammonium hydrogenselenate monohydrate ((Me4N)HSeO4·H2O) and lithium tetramethylammonium selenate tetrahydrate (Li(Me4N)SeO4·4H2O), have been found in these systems. Both substances were characterised by chemical analysis and IR molecular spectroscopy. Both of the title substances decompose under the influence of X-radiation and, thus, their structures cannot be determined. The radiolysis of both substances was studied in greater detail. Tetramethylammonium hydrogenselenate monohydrate is dehydrated by X-radiation to form the anhydrous salt. The reaction is controlled by first-order kinetics with a rate constant of 1.30(3) × 10-3 s-1.

Segmentation of Kidneys from Computed Tomography Using 3D Fast GrowCut Algorithm

2013 ◽  
Vol 333-335 ◽  
pp. 1145-1150 ◽  
Author(s):  
Gao Yuan Dai ◽  
Zhi Cheng Li ◽  
Jia Gu ◽  
Lei Wang ◽  
Xing Min Li ◽  
...  
Keyword(s):  
Computed Tomography ◽  
Three Dimensional ◽  
Experimental Results ◽  
Volume Data ◽  
Great Role ◽  
Color Features ◽  
Monotonically Decreasing Function ◽  
Kidney Segmentation ◽  
Ct Volume

This paper proposes a fast GrowCut (FGC) algorithm and applies the new algorithm in three-dimensional (3D)kidney segmentation from computed tomography (CT) volume data. Users could mark the object of interest with different labels in CT slices.FGC propagates the labels using monotonically decreasing function and color features to derive an optimal cut for a given data in space. The color features play a great role in comparing with neighborhood cells. The experimental results clearly demonstrate the superiority of FGC in accuracy and speed.

Finite Element Study of the Cutting Mechanics of the Three Dimensional Rock Turning Process

2015 ◽  
Author(s):  
Demeng Che ◽  
Jacob Smith ◽  
Kornel F. Ehmann
Keyword(s):  
Finite Element ◽  
Oil And Gas ◽  
Three Dimensional ◽  
Polycrystalline Diamond ◽  
Close Correlation ◽  
Experimental Results ◽  
Failure Behavior ◽  
Fe Model ◽  
Gas Drilling ◽  
Cutting Mechanics

The unceasing improvements of polycrystalline diamond compact (PDC) cutters have pushed the limits of tool life and cutting efficiency in the oil and gas drilling industry. However, the still limited understanding of the cutting mechanics involved in rock cutting/drilling processes leads to unsatisfactory performance in the drilling of hard/abrasive rock formations. The Finite Element Method (FEM) holds the promise to advance the in-depth understanding of the interactions between rock and cutters. This paper presents a finite element (FE) model of three-dimensional face turning of rock representing one of the most frequent testing methods in the PDC cutter industry. The pressure-dependent Drucker-Prager plastic model with a plastic damage law was utilized to describe the elastic-plastic failure behavior of rock. A newly developed face turning testbed was introduced and utilized to provide experimental results for the calibration and validation of the formulated FE model. Force responses were compared between simulations and experiments. The relationship between process parameters and force responses and the mechanics of the process were discussed and a close correlation between numerical and experimental results was shown.

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