scholarly journals Continuous hydrogen and methane production from the treatment of herbal medicines wastewater in the two-phase ‘UASBH-ICM’ system

2019 ◽  
Vol 80 (6) ◽  
pp. 1134-1144 ◽  
Author(s):  
Caiyu Sun ◽  
Fang Liu ◽  
Zhiwei Song ◽  
Lixin Li ◽  
Yu Pan ◽  
...  
Keyword(s):  
Production Rate ◽  
Methane Production ◽  
Herbal Medicines ◽  
Oxygen Demand ◽  
Energy Conversion Efficiency ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Two Phase ◽  
High Level ◽  
Residual Organic Matter

Abstract A two-phase anaerobic system comprised of upflow anaerobic sludge bed (UASB) reactor for hydrogen production and internal circulation reactor (IC) for methane production was proposed and investigated at laboratory scale and mesophilic temperature (35 °C). Hydrogen was efficiently produced from the UASB with the highest production rate of 3.00 ± 0.04 L · L−1reactor · d−1 at optimum hydraulic retention time (HRT) of 6 h and in the IC, methane was also produced from residual organic matter and soluble metabolite products (SMP) with a production rate of 2.54 ± 0.04 L · L−1reactor · d−1 at optimum HRT of 15 h. Finally, system HRT of 21 h was determined to be the optimum HRT at which energy conversion efficiency increased from 9.6 ± 0.1% (hydrogen only production) to 72.4 ± 2.5% (hydrogen and methane coproduction) and system chemical oxygen demand (COD) removal reached up to the high level of 90.1 ± 2.1%.

Sugarcane molasses-based bio-ethanol wastewater treatment by two-phase multi-staged up-flow anaerobic sludge blanket (UASB) combination with up-flow UASB and down-flow hanging sponge

2013 ◽  
Vol 69 (6) ◽  
pp. 1174-1180 ◽  
Author(s):  
P. Choeisai ◽  
N. Jitkam ◽  
K. Silapanoraset ◽  
C. Yubolsai ◽  
W. Yoochatchaval ◽  
...  
Keyword(s):  
Oxygen Demand ◽  
High Strength ◽  
Treatment System ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Phase System ◽  
Sugarcane Molasses ◽  
Two Phase ◽  
Treatment Unit ◽  
Anaerobic Sludge Blanket

This study was designed to evaluate a treatment system for high strength wastewater (vinasse) from a sugarcane molasses-based bio-ethanol plant in Thailand. A laboratory-scale two-phase treatment system composed of a sulfate reducing (SR) tank and multi-staged up-flow anaerobic sludge blanket (MS-UASB) reactor was used as the pre-treatment unit. Conventional UASB and down-flow hanging sponge (DHS) reactors were used as the post-treatment unit. The treatment system was operated for 300 days under ambient temperature conditions (24.6–29.6 °C). The hydraulic retention time (HRT) in each unit was kept at 25 h for the two-phase system and 23 h for the UASB&DHS. The influent concentration was allowed to reach up to 15,000 mg chemical oxygen demand (COD)/L. COD removal efficiency (based on influent COD) of the two-phase MS-UASB and the UASB&DHS was 54.9 and 18.7%, respectively. Due to the effective removal of sulfide in the SR tank, the MS-UASB achieved a high methane conversion ratio of up to 97%. In DHS, nitrification occurred at the outside portion of the sponge media while denitrification occurred at the inside. Consequently, 27% of the total nitrogen (TN) was removed. An amount of 32% of residual nitrogen (28 mgN/L) was in the form of nitrate, a better nitrogen state for fertilizer.

scholarly journals Influence of Pre-Hydrolysis on Sewage Treatment in an Up-Flow Anaerobic Sludge BLANKET (UASB) Reactor: A Review

Water ◽  
2019 ◽  
Vol 11 (2) ◽  
pp. 372 ◽  
Author(s):  
Rajinikanth Rajagopal ◽  
Mahbuboor Choudhury ◽  
Nawrin Anwar ◽  
Bernard Goyette ◽  
Md. Rahaman
Keyword(s):  
Suspended Solids ◽  
Biogas Production ◽  
Sewage Treatment ◽  
Oxygen Demand ◽  
High Rate ◽  
Uasb Reactor ◽  
Organic Loading Rate ◽  
Anaerobic Sludge ◽  
Two Phase ◽  
Anaerobic Sludge Blanket

The up-flow anaerobic sludge blanket (UASB) process has emerged as a promising high-rate anaerobic digestion technology for the treatment of low- to high-strength soluble and complex wastewaters. Sewage, a complex wastewater, contains 30–70% particulate chemical oxygen demand (CODP). These particulate organics degrade at a slower rate than the soluble organics found in sewage. Accumulation of non-degraded suspended solids can lead to a reduction of active biomass in the reactor and hence a deterioration in its performance in terms of acid accumulation and poor biogas production. Hydrolysis of the CODP in sewage prior to UASB reactor will ensure an increased organic loading rate and better UASB performance. While single-stage UASB reactors have been studied extensively, the two-phase full-scale treatment approach (i.e., a hydrolysis unit followed by an UASB reactor) has still not yet been commercialized worldwide. The concept of treating sewage containing particulate organics via a two-phase approach involves first hydrolyzing and acidifying the volatile suspended solids without losing carbon (as methane) in the first reactor and then treating the soluble sewage in the UASB reactor. This work reviews the available literature to outline critical findings related to the treatment of sewage with and without hydrolysis before the UASB reactor.

Co-production of hydrogen and methane from herbal medicine wastewater by a combined UASB system with immobilized sludge (H2 production) and UASB system with suspended sludge (CH4 production)

2015 ◽  
Vol 73 (1) ◽  
pp. 130-136 ◽  
Author(s):  
Caiyu Sun ◽  
Ping Hao ◽  
Bida Qin ◽  
Bing Wang ◽  
Xueying Di ◽  
...  
Keyword(s):  
Herbal Medicine ◽  
Hydrogen Production ◽  
Production Rate ◽  
Methane Production ◽  
Oxygen Demand ◽  
H2 Production ◽  
Organic Loading Rate ◽  
Anaerobic Sludge ◽  
Organic Loading ◽  
Production Of Hydrogen

An upflow anaerobic sludge bed (UASB) system with sludge immobilized on granular activated carbon was developed for fermentative hydrogen production continuously from herbal medicine wastewater at various organic loading rates (8–40 g chemical oxygen demand (COD) L−1 d−1). The maximum hydrogen production rate reached 10.0 (±0.17) mmol L−1 hr−1 at organic loading rate of 24 g COD L−1 d−1, which was 19.9% higher than that of suspended sludge system. The effluents of hydrogen fermentation were used for continuous methane production in the subsequent UASB system. At hydraulic retention time of 15 h, the maximum methane production rate of 5.49 (±0.03) mmol L−1 hr−1 was obtained. The total energy recovery rate by co-production of hydrogen and methane was evaluated to be 7.26 kJ L−1 hr−1.

APLIKASI PROSES DIGESTASI ANAEROBIK LUMPUR BIOLOGI INSTALASI PENGOLAHAN AIR LIMBAH INDUSTRI KERTAS

2014 ◽  
Vol 4 (02) ◽  
Author(s):  
Rina S. Soetopo ◽  
Sri Purwati ◽  
Henggar Hardiani ◽  
Mukharomah Nur Aini ◽  
Krisna Adhitya Wardhana
Keyword(s):  
Oxygen Demand ◽  
Total Solid ◽  
Pilot Scale ◽  
Organic Content ◽  
Solid Content ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Organic Loading ◽  
Total Solid Content ◽  
Average Value

A continuous pilot scale study has been conducted to investigate the effectiveness of anaerobic digestion of biological sludge. The sludge has a total solid content of 0.53% - 1.1%, pH of 7.20 to 7.32. Its organic content is about 97 %, The research were conducted in two stages, which are acidification (performed in 3 m3 the Continously Stirred Tank Reactor/CSTR at pH of 5.5 to 6.0) and methanation (performed in 5 m3 the Up Flow Anaerobic Sludge Blanket/UASB reactor at pH 6.5 to 7.0). The retention time (RT) was gradually shortened from 6 days to 1 day for acidification and from 8 days to 2 days for methanation. The results showed that operating the CSTR at the RT of 1 day and the organic loading of 8.23 g Volatile Solid (VS)/m3.day could produce Volatile Fatty Acid (VFA) at an average value of 17.3 g/kg VS.day. Operating the UASB reactor at the RT of 2 days and the organic loading (Chemical Oxygen Demand/COD) of 2.4 kg COD/m3.day could produce biogas at an average value of 66.3 L/day, with an average methane content of 69.9%, methane rate of 0.17 L CH4/g COD reduction or 19.06 L CH4/kg VS. Furthermore, methanation could reduce COD at an average value of 51.2 %, resulting in the effluent average value of COD filtrate and COD total of 210.1 mg/L and 375.2 mg /L, respectively.Keywords: acidification, methanation, CSTR, UASB, biogas ABSTRAKPercobaan digestasi anaerobik lumpur IPAL biologi industri kertas secara kontinyu skala pilot telah dilakukan di industri kertas dengan tujuan mengkaji efektivitas proses digestasi anaerobik dalam mengolah lumpur tersebut. Lumpur yang digunakan memiliki total solids sekitar 0,53% – 1,1%, pH netral (7,20 – 7,32) dengan komponen utama senyawa organik sekitar 97%. Percobaan dilakukan dalam dua tahap yaitu asidifikasi dalam reaktor CSTR berkapasitas 3 m3 pada pH 5,5 – 6,0 dan metanasi dalam reaktor UASB berkapasitas 5 m3 pada pH 6,5 – 7,0. Percobaan dilakukan dengan waktu retensi yang dipersingkat secara bertahap dari 6 hari ke 1 hari untuk proses asidifikasi dan dari 8 hari ke 2 hari untuk proses metanasi. Hasil percobaan menunjukkan bahwa pengoperasian reaktor CSTR dengan waktu retensi 1 hari dan beban organik 8,3 g VS/m3.hari dapat menghasilkan VFA rata-rata 17,3 g/kg VS.hari dengan kisaran 8,36 – 30,59 g/kg VS.hari, sedangkan pengoperasian reaktor UASB pada waktu retensi 2 hari dan beban organik 2,4 kg COD/m3.hari dapat menghasilkan biogas rata-rata 66,3 L/hari dengan kadar metana rata-rata 69,9% atau 0,17 L CH4/g COD reduksi atau 19,06 L CH4/kg VS. Selain itu proses metanasi dapat menurunkan COD terlarut rata-rata 51,2%, dengan konsentrasi efluen COD terlarut  rata-rata 210,1 mg/L dan COD total rata-rata 375,2 mg/L.Kata kunci: asidifikasi, metanasi, CSTR, UASB, biogas

scholarly journals The Concept of Wastes to Energy Using Sugary Wastes

2012 ◽  
Vol 9 ◽  
pp. 57-62
Author(s):  
Fiza Sarwar ◽  
Wajeeha Malik ◽  
Muhammad Salman Ahmed ◽  
Harja Shahid
Keyword(s):  
Volatile Fatty Acids ◽  
Loading Rate ◽  
Biogas Production ◽  
Oxygen Demand ◽  
Uasb Reactor ◽  
Organic Loading Rate ◽  
Anaerobic Sludge ◽  
Loading Rates ◽  
Sugar Mills ◽  
Anaerobic Sludge Blanket

Abstract: This study was designed using actual effluent from the sugary mills in an Up-flow Anaerobic Sludge Blanket (UASB) Reactor to evaluate treatability performance. The reactor was started-up in step-wise loading rates beginning from 0.05kg carbon oxygen demand (COD)/m3-day to 3.50kg-COD/m3-day. The hydraulic retention time (HRT) was slowly decreased from 96 hrs to eight hrs. It was observed that the removal efficiency of COD of more than 73% can be easily achieved at an HRT of more than 16 hours corresponding to an average organic loading rate (OLR) of 3.0kg-COD/m3-day, at neutral pH and constant temperature of 29°C. The average VFAs (volatile fatty acids) and biogas production was observed as 560mg/L and 1.6L/g-CODrem-d, respectively. The average methane composition was estimated as 62%. The results of this study suggest that the treatment of sugar mills effluent with the anaerobic technology seems to be more reliable, effective and economical.DOI: http://dx.doi.org/10.3126/hn.v9i0.7075 Hydro Nepal Vol.9 July 2011 57-62

Open trickling filter: an innovative, cheap and simple form of post-treatment of sanitary effluents from anaerobic reactors in small communities

2012 ◽  
Vol 2 (2) ◽  
pp. 59-67 ◽  
Author(s):  
P. C. Vieira ◽  
M. von Sperling
Keyword(s):  
Loading Rate ◽  
Oxygen Demand ◽  
Post Treatment ◽  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Organic Loading Rate ◽  
Anaerobic Sludge ◽  
Trickling Filter ◽  
Small Communities ◽  
Capital Costs

We aimed to evaluate the performance and cost savings of an innovative design of a trickling filter (TF) for small population sizes, developed at the Federal University of Minas Gerais, Brazil referred to as an open trickling filter (OTF). The OTF had no side walls and no perforated bottom slab, and was applied for the post-treatment of sanitary sewage from an upflow anaerobic sludge blanket (UASB) reactor. The OTF had crushed-stone packing (3.5 m high) and was operated with an average surface hydraulic loading rate of 4.1 m3 m−2 d−1 and an average volumetric organic loading rate of 0.10 kg BOD m−3 d−1 (biochemical oxygen demand). The average concentrations obtained at the OTF effluent were 48 mg TSS L−1 (total suspended solids), 132 mg COD L−1 (chemical oxygen demand), 51 mg BOD L−1, 19 mg TKN L−1 (total Kjeldahl nitrogen), 16 mg NH4+-N L−1 and 10 mg NO3−-N L−1, complying with local discharge standards. Analysis of the construction costs indicated savings of 74% compared to conventional TF. Based on the performance, compactness, simplicity and reduced capital costs, it is believed that the proposed OTF is a good alternative for small communities, especially in developing countries.

Impact of microaeration bioreactor on dissolved sulfide and methane removal from real UASB effluent for sewage treatment

2020 ◽  
Vol 81 (9) ◽  
pp. 1951-1960 ◽  
Author(s):  
C. S. Cabral ◽  
A. L. Sanson ◽  
R. J. C. F. Afonso ◽  
C. A. L. Chernicharo ◽  
J. C. Araújo
Keyword(s):  
Sewage Treatment ◽  
Oxygen Demand ◽  
Post Treatment ◽  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Sulfide Removal ◽  
Dissolved Sulfide ◽  
Removal Efficiencies ◽  
Anaerobic Sludge Blanket

Abstract Two bioreactors were investigated as an alternative for the post-treatment of effluent from an upflow anaerobic sludge blanket (UASB) reactor treating domestic sewage, aiming at dissolved sulfide and methane removal. The bioreactors (R-control and R-air) were operated at different hydraulic retention times (HRT; 6 and 3 h) with or without aeration. Large sulfide and methane removal efficiencies were achieved by the microaerated reactor at HRT of 6 h. At this HRT, sulfide removal efficiencies were equal to 61% and 79%, and methane removal efficiencies were 31% and 55% for R-control and R-air, respectively. At an HRT of 3 h, sulfide removal efficiencies were 22% (R-control) and 33% (R-air) and methane removal did not occur. The complete oxidation of sulfide, with sulfate formation, prevailed in both phases and bioreactors. However, elemental sulfur formation was more predominant at an HRT of 6 h than at an HRT of 3 h. Taken together, the results show that post-treatment improved the anaerobic effluent quality in terms of chemical oxygen demand and solids removal. However, ammoniacal nitrogen was not removed due to either the low concentration of air provided or the absence of microorganisms involved in the nitrogen cycle.

Toxicity and treatability of leachate: application of UASB reactor for leachate treatment from Okhla landfill, New Delhi

2012 ◽  
Vol 65 (10) ◽  
pp. 1887-1894 ◽  
Author(s):  
V. Singh ◽  
A. K. Mittal
Keyword(s):  
Oxygen Demand ◽  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Organic Loading Rate ◽  
Anaerobic Sludge ◽  
New Delhi ◽  
Leachate Treatment ◽  
Feed Composition ◽  
Laboratory Scale Reactor ◽  
Anaerobic Sludge Blanket

This study reports applicability of upflow anaerobic sludge blanket (UASB) process to treat the leachate from a municipal landfill located in Delhi. A laboratory scale reactor was operated at an organic loading rate of 3.00 kg chemical oxygen demand (COD)/m3 d corresponding to a hydraulic retention time (HRT) of 12 h for over 8 months. The effect of toxicity of leachate, and feed composition on the treatability of leachate was evaluated. Average COD of the leachate, during the study period varied between 8,880 and 66,420 mg/l. Toxicity of the leachate used during a period of 8 months varied from LC50 1.22 to 12.35 for 96 h. The removal efficiency of soluble COD ranged between 91 and 67% for fresh leachate and decreased drastically from 90 to 35% for old leachate having high toxicity. The efficiency varied from 81 to 65%. The reactor performed more efficiently for the treatment of fresh leachate (less toxic, LC50 11.64, 12.35, and 12.15 for 96 h) as compared with old leachate (more toxic, LC50 1.22 for 96 h). Toxicity of the leachate affected its treatment potential by the UASB.

Effect of micro-nutrients in anaerobic degradation of sulfate laden organics

2004 ◽  
Vol 31 (3) ◽  
pp. 420-431 ◽  
Author(s):  
S K Patidar ◽  
Vinod Tare
Keyword(s):  
Anaerobic Degradation ◽  
Oxygen Demand ◽  
Cod Removal ◽  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Sulfide Concentration ◽  
Anaerobic Baffled Reactor ◽  
Sulfide Toxicity ◽  
Anaerobic Sludge Blanket

The effect of micro-nutrients, such as Fe, Ni, Zn, Co, and Mo, on anaerobic degradation of sulfate laden organics was investigated using bench-scale models of upflow anaerobic sludge blanket (UASB) reactor, anaerobic baffled reactor (ABR), and hybrid anaerobic baffled reactor (HABR), operating in varying conditions in ten phases (organic loading of 1.9–5.75 kg COD/(m3·d), sulfate loading of 0.54–1.88 kg SO42–/(m3·d), chemical oxygen demand (COD):SO42–ratio of 2.0–8.6). In the initial phase, no nutrient limitation was observed with COD removal of more than 94% in all three systems. Subsequently, increase in sulfate loading resulted in Ni and Co limitation and their supplementation restored COD removal in UASB system. However, baffled systems did not recover because of severe inhibition by sulfide. Results indicate that precipitation of nutrients could seriously deteriorate process performance, leading to failure even before sulfide concentration attains toxic level. The limitation of Fe coupled with high sulfate loading (1.88 kg SO42–/(m3·d)) resulted in growth of low-density, fragile, hollow, and granular biomass in UASB that washed out and caused process instability. Supplementation of Fe with other nutrients stabilized UASB process and also improved COD removal.Key words: anaerobic degradation, nutrients, UASB, ABR, HABR, sulfide toxicity, sulfate laden organics.

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