scholarly journals Characterization of the surface properties of Illinois Basin Coals

1991 ◽  
Author(s):  
I. Demir
2016 ◽  
Vol 1133 ◽  
pp. 547-551 ◽  
Author(s):  
Ali E.I. Elkhalifah ◽  
Mohammad Azmi Bustam ◽  
Azmi Mohd Shariff ◽  
Sami Ullah ◽  
Nadia Riaz ◽  
...  

The present work aims at a better understanding of the influences of the intercalated mono-, di- and triethanolamines on the characteristics and CO2 adsorption ability of sodium form of bentonite (Na-bentonite). The results revealed that the molar mass of intercalated amines significantly influenced the structural and surface properties as well as the CO2 adsorption capacity of Na-bentonite. In this respect, a stepwise increase in the d-spacing of Na-bentonite with the molar mass of amine was recorded by XRD technique. However, an inverse effect of the molar mass of amine on the surface area was confirmed by BET method. CO2 adsorption experiments on amine-bentonite hybrid adsorbents showed that the CO2 adsorption capacity inversly related to the molar mass of amine at 25 ͦC and 101 kPa. Accordingly, Na-bentonite modified by monoethanolammonium cations adsorbed as high as 0.475 mmol CO2/g compared to 0.148 and 0.087 mmol CO2/g for that one treated with di- and triethanolammonium cations, respectively.


2021 ◽  
Vol 40 (11) ◽  
pp. 823-830
Author(s):  
Nikita Bondarenko ◽  
Sherilyn Williams-Stroud ◽  
Jared Freiburg ◽  
Roman Makhnenko

Carbon sequestration activities are increasing in a global effort to mitigate the effects of greenhouse gas emissions on the climate. Injection of wastewater and oil-field fluids is known to induce seismic activity. This makes it important to understand how that risk relates to CO2 injection. Injection of supercritical CO2 into the Cambrian Mt. Simon sandstone in Illinois Basin induced microseismicity that was observed below the reservoir, primarily in the Precambrian crystalline basement. Geomechanical and flow properties of rock samples from the involved formations were measured in the laboratory and compared with geophysical log data and petrographic analysis. The controlling factors for induced microseismicity in the basement seem to be the hydraulic connection between the reservoir and basement rock and reactivation of pre-existing faults or fractures in the basement. Additionally, the presence of a laterally continuous low-permeability layer between reservoir and basement may have prevented downward migration of pore pressure and reactivation of critically stressed planes of weakness in the basement. Results of the geomechanical characterization of this intermediate layer indicate that it may act as an effective barrier for fluid penetration into the basement and that induced microseismicity is likely to be controlled by the pre-existing system of faults. This is because the intact material is not expected to fail under the reservoir stress conditions.


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