New Trends in the Development of C-P Bond Forming Reactions

2021 ◽  
Vol 25 ◽  
Author(s):  
Vadim D. Romanenko
Keyword(s):  
Heterocyclic Carbenes ◽  
The State ◽  
Organic Substrates ◽  
Elemental Phosphorus ◽  
Multiple Bonds ◽  
Bond Forming ◽  
Phosphorus Containing ◽  
Direct Functionalization ◽  
Synthetic Approaches ◽  
State Of Art

: This article provides reviews related to some innovative (“non-classical”) synthetic strategies for the formation of CP bonds developed during the last decades. It provides examples of the most important milestones in this field, highlighting the state-of-art of functional phosphorus-containing molecules. Among these are the direct functionalization of organic substrates through chlorine-free reactions with elemental phosphorus, syntheses based on phosphinidene (RP) transfer, phosphorylating methodology employing multiple bonds containing P(III) compounds, reactions with stable heterocyclic carbenes, and synthetic approaches using phosphaethynolate and bis(trichlorosilyl)phosphide salts.

Opponent Center-Surround Contrast: Colour to Grey Conversion

2020 ◽  
Vol 2020 (1) ◽  
pp. 105-108
Author(s):  
Ali Alsam
Keyword(s):  
Evolutionary Algorithms ◽  
Three Dimensional ◽  
The State ◽  
Colour Space ◽  
Vision Science ◽  
State Of Art ◽  
Over Time

Vision is the science that informs us about the biological and evolutionary algorithms that our eyes, opticnerves and brains have chosen over time to see. This article is an attempt to solve the problem of colour to grey conversion, by borrowing ideas from vision science. We introduce an algorithm that measures contrast along the opponent colour directions and use the results to combine a three dimensional colour space into a grey. The results indicate that the proposed algorithm competes with the state of art algorithms.

Aryl-substituted Triarsiranes: Synthesis and Reactivity

2020 ◽  
Author(s):  
André Schumann ◽  
Jonas Bresien ◽  
Malte Fischer ◽  
Christian Hering-Junghans
Keyword(s):  
Organic Chemistry ◽  
Electronic Structure ◽  
Heterocyclic Carbenes ◽  
Synthetic Approaches ◽  
Inorganic And Organic

Cyclotriarsanes are rare and limited synthetic approaches have hampered reactivity studies on these systems. Described in here is a scalable synthetic protocol towards (AsAr)<sub>3</sub> (Ar = Dip, 2,6-<sup>i</sup>Pr<sub>2</sub>-C<sub>6</sub>H<sub>3</sub>; Tip, 2,4,6-<sup>i</sup>Pr<sub>3</sub>-C<sub>6</sub>H<sub>2</sub>), which allowed to study their reactivity towards [Cp<sub>2</sub>Ti(C<sub>2</sub>(SiMe<sub>3</sub>)<sub>2</sub>], affording titanocene diarsene complexes and towards N-heterocyclic carbenes (NHCs) to give straightforward access to a variety of NHC-arsinidene adducts. The electronic structure of the titanium diarsene complxes has been studied and they are best described as Ti(IV) species with a doubly reduced As<sub>2</sub>Ar<sub>2</sub> ligand. These findings will make (AsAr)<sub>3</sub> valuable precursors in the synthetic inorganic and organic chemistry.

Kidney transplantation in identical twins: the state of art and a case report

2019 ◽  
Vol 21 (4) ◽  
pp. 458-465
Author(s):  
A.I. Sushkov ◽  
◽  
T.A. Astrelina ◽  
E.V. Shestero ◽  
V.A. Nikitina ◽  
...  
Keyword(s):  
Kidney Transplantation ◽  
Case Report ◽  
The State ◽  
Identical Twins ◽  
State Of Art

scholarly journals A Review of Size Engineering-Enabled Electrocatalysts for Li–S Chemistry

2021 ◽  
Author(s):  
Xi Zhang ◽  
Yaping Zhang ◽  
xijun wei ◽  
Chaohui Wei ◽  
Yingze Song
Keyword(s):  
Energy Density ◽  
High Energy ◽  
The State ◽  
High Energy Density ◽  
State Of Art

Li–S batteries (LBSs) have received extensive attention owing to their remarkable theoretical capacity (1672 mA h g–1) and high energy density (2600 Wh kg–1), far beyond the state of art...

Revealing the structural transformation of rutile RuO2via in situ X-ray absorption spectroscopy during the oxygen evolution reaction

2019 ◽  
Vol 48 (21) ◽  
pp. 7122-7129 ◽  
Author(s):  
Chia-Jui Chang ◽  
You-Chiuan Chu ◽  
Hao-Yu Yan ◽  
Yen-Fa Liao ◽  
Hao Ming Chen
Keyword(s):  
Oxygen Evolution ◽  
Structural Transformation ◽  
Absorption Spectroscopy ◽  
Oxygen Evolution Reaction ◽  
The State ◽  
X Ray ◽  
Alkaline Conditions ◽  
X Ray Absorption ◽  
State Of Art

The state-of-art RuO2 catalyst for the oxygen evolution reaction (OER) is measured by using in situ X-ray absorption spectroscopy (XAS) to elucidate the structural transformation during catalyzing the reaction in acidic and alkaline conditions.

scholarly journals Art Criticism and the State of Feminist Art Criticism

Arts ◽  
2020 ◽  
Vol 9 (1) ◽  
pp. 28
Author(s):  
Katy Deepwell
Keyword(s):  
Women Artists ◽  
Art Criticism ◽  
The State ◽  
Art World ◽  
Feminist Art ◽  
The Gaze ◽  
The Third ◽  
Fourth Part ◽  
State Of Art ◽  
First Offers

This essay is in four parts. The first offers a critique of James Elkins and Michael Newman’s book The State of Art Criticism (Routledge, 2008) for what it tells us about art criticism in academia and journalism and feminism; the second considers how a gendered analysis measures the “state” of art and art criticism as a feminist intervention; and the third, how neo-liberal mis-readings of Linda Nochlin and Laura Mulvey in the art world represent feminism in ideas about “greatness” and the “gaze”, whilst avoiding feminist arguments about women artists or their work, particularly on “motherhood”. In the fourth part, against the limits of the first three, the state of feminist art criticism across the last fifty years is reconsidered by highlighting the plurality of feminisms in transnational, transgenerational and progressive alliances.

scholarly journals Inflammation and compression: the state of art

2016 ◽  
Vol 5 (1) ◽  
Author(s):  
Daniela Ligi ◽  
Lidia Croce ◽  
Ferdinando Mannello
Keyword(s):  
The State ◽  
State Of Art

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