scholarly journals Current Status, Opportunities and Challenges of Green Corrosion Inhibitors

Author(s):  
S. Kundu

The term ‘Corrosion’ is associated with the deterioration of materials. To get rid of this problem corrosion inhibitors are commonly used. Though many conventional corrosion inhibitors can efficiently reduce corrosion, their disposal often adversely affects the environment. However, there are many natural products that have the potential of reducing corrosion and they are referred to as green corrosion inhibitors. They are much safer to use and most importantly cost-effective. This chapter deals with the current development of the use of green corrosion inhibitors, their opportunities and challenges.

Molecules ◽  
2021 ◽  
Vol 26 (24) ◽  
pp. 7417
Author(s):  
Carlos Cevallos-Morillo ◽  
Pablo Cisneros-Pérez ◽  
Roxana Llive ◽  
Marvin Ricaurte ◽  
Carlos Reinoso ◽  
...  

Croton lechleri, commonly known as Dragon’s blood, is a tree cultivated in the northwest Amazon rainforest of Ecuador and Peru. This tree produces a deep red latex which is composed of different natural products such as phenolic compounds, alkaloids, and others. The chemical structures of these natural products found in C. lechleri latex are promising corrosion inhibitors of admiralty brass (AB), due to the number of heteroatoms and π structures. In this work, three different extracts of C. lechleri latex were obtained, characterized phytochemically, and employed as novel green corrosion inhibitors of AB. The corrosion inhibition efficiency (IE%) was determined in an aqueous 0.5 M HCl solution by potentiodynamic polarization (Tafel plots) and electrochemical impedance spectroscopy, measuring current density and charge transfer resistance, respectively. In addition, surface characterization of AB was performed by scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy techniques. Chloroform alkaloid-rich extracts resulted in IE% of 57% at 50 ppm, attributed to the formation of a layer of organic compounds on the AB surface that hindered the dezincification process. The formulation of corrosion inhibitors from C. lechleri latex allows for the valorization of non-edible natural sources and the diversification of the offer of green corrosion inhibitors for the chemical treatment of heat exchangers.


2018 ◽  
Vol 3 (2) ◽  
pp. 158 ◽  
Author(s):  
Yuli Panca Asmara ◽  
Tedi Kurniawan ◽  
Agus Geter Edy Sutjipto ◽  
Jamiluddin Jafar

High requirements in protection of steel reinforcing bar (steel rebar) from corrosion are necessary since there are multi interaction of corrosive chemicals which cause early damage of concrete buildings. Corrosion of steel in concrete can destroy the concretes and reduce concrete strength. To protect rebar from corrosion, application of corrosion inhibitor is believed to have higher performance compared to other protection systems. To date, organic inhibitors have promising methods in steel rebar protection as they are environment-friendly, compatible with concrete, cost effective and applicable in any various concrete conditions. Thus, demands in using these inhibitors tend to increase significantly. This paper reviews the applications of green corrosion inhibitor specifically highlighted in protecting mechanisms, typical plants extracted, performance in corrosion protection, and classification of green corrosion inhibitors. The corrosion resistances of carbon steels in concrete protected by green inhibitors are in focus. As summary, it can be confidently notified that green corrosion inhibitors for steel in concrete will have a prospect to be used as corrosion prevention in the future with further improvements.


Author(s):  
Y.V.D. Nageswar

Plants are a rich source of different varied organic compounds. Due to the important applications of naturally occurring chemicals their derivatives are also pursued for modifying and potentiating the activities of natural products. Metallic corrosion is a natural process resulting in heavy losses in various fields. Non hazardous and non toxic corrosion inhibitors gained significance due to the environmental regularities and guidelines issued in the course of saving the pristine nature of environment and to maintain the sustainability of our earth. Green corrosion inhibitors play a potential role for the above said cause. Recent research contributions on green corrosion inhibitors from the active researchers in the concerned expertise are presented briefly here to give an idea about the current research activity across the world.


2021 ◽  

The book presents the current status of corrosion inhibitor technology. A special focus is placed on various types of green corrosion inhibitors and their applications.


Author(s):  
B. Chugh

Green chemistry and sustainability encourages the significance of preserving the nature and individual’s wellbeing in cost effective way that intends to avoid toxicity and reduction of wastes. Therefore, the implication of green corrosion inhibitors in the field of concrete protection has also received immense attention these days. Indeed, the usage of such inhibitors is a well-known strategy for producing high performance concrete. In view of this, the present chapter discusses the research in the area of sustainable corrosion inhibitors for concrete assurance used commercially in various industries. It also highlights the concrete corrosion mechanisms and its protective measures, recent advances in this field.


2016 ◽  
Vol 70 (9) ◽  
Author(s):  
Shi Mo ◽  
Hong-Qun Luo ◽  
Nian-Bing Li

AbstractIn recent years, plant extracts have become the focus of corrosion inhibitor research due to their low toxicity, easy availability and economical preparation. This review presents most of the recent contributions made to the application of plant extracts as corrosion inhibitors for steel in sulphuric acid, as well as in both hydrochloric acid and sulphuric acid. The constituents, properties, adsorption modes and inhibition mechanisms of these natural products are discussed. Evaluation methods and the factors that influence the corrosion-inhibition efficiency of plant extracts are also summarised.


Author(s):  
R. Payal

Corrosion is emerging as a potential hazard which abolishes metals and their structures and hence become an imperative menace. It is an omnipotent and omnipresent process which is present in every environment, i.e., air, soil, water. Green chemistry is one of the notable branches of chemistry that focuses on the protection of environment and human well–being in an economically viable approach allowing dodging of toxins and reducing hazards due to corrosion. Green chemistry exploited well–known strategy namely green inhibitors to prevent, control or impede the growth of corrosion. Green inhibitors are eco–friendly, cost–effective, renewable natural products which are favourable over toxic synthetic corrosion inhibitors. Extracts of natural products contain natural products containing alkaloids, carboxylic acids, nicotine, polyphenols, quinine, terpenes, and other functional groups possessing elements like C, N, O, S, etc., prompting adsorption via forming a thin layer (coating) on the metallic surface to shield the surface and encumber corrosion. In the field of economical loop, this approach develops various potential applications in manufacturing areas other than ‘Trash to treasure’. Even though a bunch of experiments have been performed and several research articles have been in print, however, the area of green inhibitors is still demanding more investigation on this open issue. More and more interest in the area extended the research, consequentially to a large variety of tried molecules. Nevertheless, the most accepted protocols are classical and, therefore, are incompetent to completely portray the probable worth of inhibitors. Hence all above stated features should be the objective of the contemporary research so that productive analysis to emphasize the weak areas of the green inhibitors field and tackle the prospect research in the field that still requires validation.


Corrosion is an inevitable fact of day-to-day life, and however, because of its technological, economic, and aesthetic significance, it always receives much attention. Most of the corrosion inhibitors are environmentally harmful and toxic synthetic chemicals. In view of the toxicity of the inhibitors, the search for an eco-friendly and non-toxic corrosion inhibitor is of great interest. Green corrosion inhibitors are of concern because of increased awareness and improvements in regulations related to the environment because of their toxicity, restrict regular corrosion inhibitors. The extracts of natural products contain compounds having oxygen, carbon, nitrogen and sulfur. Such elements facilitate compounds to absorb on the surface of metal, forming a protective film to prevent corrosion. The main purpose of this chapter is to provide a comprehensive study of technological applications of green corrosion inhibitors in different industries, such as reinforced concrete, coating, aircraft, oil and gas, acid pickling, and water industry.


2012 ◽  
Vol 13 (1) ◽  
pp. 235-244 ◽  
Author(s):  
Mario Luiz Conte da Frota Junior ◽  
Renata Biegelmeyer da Silva ◽  
Beatriz Mothes ◽  
Amelia Teresinha Henriques ◽  
Jose Claudio Fonseca Moreira

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