scholarly journals Bio-Mediated Synthesis of Nanomaterials for Electrochemical Sensor Applications

2021 ◽  
pp. 224-262
Keyword(s):  
Electron Transfer ◽  
Surface Functionalization ◽  
Electrochemical Sensing ◽  
Electron Transfer Mechanism ◽  
Final Point ◽  
Sensor Applications ◽  
Nanomaterial Synthesis ◽  
Sensing Technology ◽  
Physical And Chemical ◽  
Synthesis Of Nanomaterials

The bio-mediated nanomaterials have expected growing responsiveness due to an increasing requirement to develop naturally nonthreatening technologies in nanomaterial synthesis. Biotic ways to prepare nanomaterials through extracts from the plant (includes stems, leaves, flowers, and roots) and microorganisms were recommended as likely replacements for physical and chemical routes due to their solvent medium and environment eco-friendliness and nontoxicity. This chapter focuses on electrocatalyst prepared by various bio-mediated synthetic ways and used as a green and eco-friendly electrocatalyst to recognize extensive chemical and biologically essential molecules with improved selectivity and sensitivity with low detection limit. The bio-mediated nanocomposite formation processes and their unique properties surface functionalization and electron transfer mechanism discussed in connection with the design and fabrication of sensors. As a final point, the encounters and prospects in developing bio-mediated nanomaterials-based electrochemical sensing technology was outlined.

Improving peroxymonosulfate activation by copper ion-saturated adsorbent-based single atom catalysts for the degradation of organic contaminants: electron-transfer mechanism and the key role of Cu single atoms

2021 ◽  
Author(s):  
Jingwen Pan ◽  
Baoyu Gao ◽  
Pijun Duan ◽  
Kangying Guo ◽  
Muhammad Akram ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Organic Contaminants ◽  
High Salinity ◽  
Copper Ion ◽  
Single Atom ◽  
Electron Transfer Mechanism ◽  
Persulfate Oxidation ◽  
Single Atoms ◽  
Oxidation Technology

Nonradical pathway-based persulfate oxidation technology is considered to be a promising method for high-salinity organic wastewater treatment.

Graphene: An Insight Into Electrochemical Sensing Technology

Monoelements ◽  
2020 ◽  
pp. 169-233
Author(s):  
Anantharaman Shivakumar ◽  
Honnur Krishna
Keyword(s):  
Electrochemical Sensing ◽  
Sensing Technology ◽  
Insight Into

THEORETICAL STUDIES ON THE COUPLING INTERACTIONS AND SELF-EXCHANGE REACTION MECHANISMS IN THE COMPLEXES OF NO WITH ONH AND NOH

2008 ◽  
Vol 07 (03) ◽  
pp. 435-446 ◽  
Author(s):  
PING LI ◽  
XIAOYAN XIE ◽  
YUXIANG BU ◽  
WEIHUA WANG ◽  
NANA WANG ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Exchange Reaction ◽  
Reaction Mechanisms ◽  
Natural Bond Orbital ◽  
Theoretical Studies ◽  
Exchange Reactions ◽  
Electron Transfer Mechanism ◽  
Proton Coupled Electron Transfer ◽  
Planar Geometries ◽  
Transfer Mechanisms

The coupling interactions and self-exchange reaction mechanisms between NO and ONH (NOH) have been systematically investigated at the B3LYP/6-311++G** level of theory. All the equilibrium complexes are characterized by the intermolecular H-bonds and co-planar geometries. The cisoid NOH/ON species is the most stable one among all the complexes considered due to the formation of an N – N bond. Moreover, all the cisoid complexes are found to be more stable than the corresponding transoid ones. The origin of the blueshifts occurring in the selected complexes has been explored, employing the natural bond orbital (NBO) calculations. Additionally, the proton transfer mechanisms for the self-exchange reactions have been proposed, i.e. they can proceed via the three-center proton-coupled electron transfer or five-center cyclic proton-coupled electron transfer mechanism.

Fluoreszenzlöschung alternierender und nicht-alternierender polycyclischer aromatischer Kohlenwasserstoffe durch Nitroverbindungen / Fluorescence Quenching of Alternant and Non-alternant Polycyclic Hydrocarbons by Nitro Compounds

1977 ◽  
Vol 32 (12) ◽  
pp. 1561-1563 ◽  
Author(s):  
M. Zander
Keyword(s):  
Electron Transfer ◽  
Fluorescence Quenching ◽  
Excitation Energy ◽  
Reduction Potential ◽  
Nitro Compounds ◽  
Polycyclic Hydrocarbons ◽  
Electron Transfer Mechanism ◽  
Diffusion Controlled ◽  
Polycyclic Aromatic ◽  
Alternant Hydrocarbons

Abstract Fluorescence Quenching of Alternant and Non-alternant Polycyclic Hydrocarbons by Nitro Compounds Fluorescence quenching of polycyclic aromatic hydro­ carbons by nitromethane or nitrobenzene in fluid solutions is due to an electron transfer mechanism. The non diffusion controlled rate constant of quenching is very much greater for alternant than for non-alternant hydrocarbons with equal singlet excitation energy. This is explained by the known more positive reduction potential of non-alternant compared to alternant hydrocarbons.

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