Enhancement of Chemical-Oxygen Demand and Color Removal of Distillery Spent-Wash by Ozonation

2006 ◽  
Vol 78 (4) ◽  
pp. 409-420 ◽  
Author(s):  
S. Srivastava ◽  
P. Bose ◽  
V. Tare
2020 ◽  
Vol 197 ◽  
pp. 213-223
Author(s):  
Manoj Pandurang Wagh ◽  
Pravin Dinkar Nemade ◽  
Uday Naik ◽  
Ayan Sengupta

2017 ◽  
Vol 11 (1) ◽  
pp. 36
Author(s):  
Melly Mellyanawaty ◽  
Chandra Wahyu Purnomo ◽  
Wiratni Budhijanto

Penelitian ini bertujuan untuk mengetahui pengaruh penambahan zeolit alam termodifikasi sebagai media imobilisasi terhadap dekomposisi material organik pada proses anaerobic digestion. Modifikasi yang dilakukan adalah dengan cara mengimpregnasi ion besi(Fe2+)ke dalam zeolit yang telah dibentuk menjadi cincin Raschig. Impregnasi yang dilakukan adalah impregnasi basah. Dalam penelitian ini digunakan 3 variasi konsentrasi larutan Fe2+ yaitu 10 mg/L; 100 mg/L dan 2000 mg/L. Dari hasil impregnasi zeolit menggunakan ketiga konsentrasi tersebut diperoleh kadar Fe2+ yang terdeposit ke dalam zeolit berturut-turut: 0,0016 mgFe2+/gZeo; 0,0156 mgFe2+/gZeo; 0,3125 mgFe2+/gZeo dan 0 mgFe2+/gZeo digunakan sebagai kontrol. Zeolit termodifikasi Fe2+ kemudian ditambahkan ke dalam reaktor anaerobik yang dijalankan secara batch. Perbandingan volume media zeolit dan cairan adalah 1:1. Substrat yang digunakan berupa campuran limbah distillery spent wash dengan konsentrasi soluble Chemical Oxygen Demand (sCOD) 10.000 mg/L dan keluaran dari digester aktif kotoran sapi sebagai inokulum. Perbandingan volume distillery spent wash terhadap inokulum sebesar 2:1. Proses anaerobik dijalankan selama 28 hari.Jika dibandingkan dengan data Total Solid (TS) dan Volatile Solid (VS), hasil percobaan menunjukkan bahwa data analisis sCOD memberikan data yang lebih akurat dan konklusif untuk mengukur perubahan material organik dalam proses peruraian anaerobik menggunakan media imobilisasi. Dari keempat variasi kadar Fe2+ yang digunakan dalam penelitian ini, Fe2+ dengan kadar 0,0156 mgFe/gZeo memberikan efisiensi penurunan material organik (sCOD) tertinggi yaitu 66,73%. Sedangkan Fe2+ dengan kadar 0,3125 mgFe/gZeo mampu meningkatkan produksi biogas sebesar 43%. Namun secara keseluruhan proses peruraian anaerobik yang menggunakan zeolit termodifikasi Fe2+ menghasilkan biogas lebih banyak daripada kontrol (zeolit tanpa Fe2+).


2021 ◽  
Vol 2 (1) ◽  
pp. 8-17
Author(s):  
Sukanya Pujari ◽  
Manoj Wagh ◽  
Shila Dare

In waste treatment and water management issues, electrocoagulation (EC) is the most cost-effective and environmentally friendly option. In the study, EC treatment of distillery spent wash was carried out using new electrodes packed with aluminium foil scraps. These metal scraps were packed in a mesh to function as anode and cathode electrodes. Electrochemical treatment was carried out for 150 minutes, and samples were analysed regularly to determine the colour and chemical oxygen demand (COD). The impact of operating parameters such as pH, applied current, electrolysis time, agitation speed, and electrode distance on colour and COD removal was investigated. The EC processes were carried out in monopolar parallel (MP-P) and monopolar series (MP-S). The MP-S connection measured the potential difference between the amplified pair of electrodes, whereas the output signals in the MP-P connection were formed by several input electrodes, resulting in a high removal rate. The results indicated that the MP-P relationships enhance the COD removal rate by 4.16 to 8.06 %. An optimum chemical oxygen demand degradation is 77.29 % at pH 3, and decolourisation is 76.55 % at pH 8.3. TDS is reduced to a maximum of 58.32 %, while sulfate and chloride are reduced to 64.72 and 20.44 %, respectively.


Author(s):  
Gabriela Roa-Morales ◽  
Carlos Barrera-Díaz ◽  
Patricia Balderas-Hernández ◽  
Francisco Zaldumbide-Ortiz ◽  
Horacio Reyes Perez ◽  
...  

Industrial offset printing processes generate wastewater with highly colored obtaining values of 5x10<sup>6</sup> Pt-Co units and great values of chemical oxygen demand (COD) 5.3x10<sup>-5</sup> mg L<sup>-1</sup>. Thus, conventional technologies such as biologicals treatment fail in reaching the discharge limits. In this research, a sequential treatment was applied: coagulation with aluminum hydroxychloride (AHC), electrocoagulation with Al anodes and finally ozonation. Optimal conditions are found when adding 20 mg L<sup>-1</sup> AHC, followed by electrocoagulation at 4 A for 50 min, and finally alkaline ozonation for 15 min, resulting in an overall color removal of 99.99% color and 99.35% COD.


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