The Use of Oxidation-Reduction Potential as a Means of Controlling Effluent Ammonia Concentration in an Extended Aeration Activated Sludge System

2006 ◽  
Vol 2006 (6) ◽  
pp. 5901-5926 ◽  
Author(s):  
Matthew Myers ◽  
Leland Myers ◽  
Robert Okey
2016 ◽  
Vol 75 (2) ◽  
pp. 247-254 ◽  
Author(s):  
F. Friedrichs ◽  
K. U. Rudolph ◽  
Bich Hanh Nguyen ◽  
D. Meinardi ◽  
W. Genthe ◽  
...  

The inhibition of activated sludge respiration is one of the most important parameters for monitoring wastewater toxicity. The main objective of this study was to improve respiration inhibition testing in order to protect the biological degradation within the aerobic process in a wastewater treatment plant more efficiently. In order to influence the sensitivity of the testing bacteria, two different nutrient solutions were selected for biological testing, synthetic wastewater according to ISO 8192 and NaAc (sodium acetate). The effects of the nutrient solutions on heavy metal speciation and their respiration inhibition were investigated. The toxicants Zn(II), Cu(II), Cr(VI) and 3,5 DCP (3,5-dichlorophenol) were used as standards to determine toxicities and to study the influence of nutrient solutions. Results have shown that NaAc as a nutrient solution sensitized the respiration inhibition test up to a factor of 7.7. Furthermore, an oxidation reduction potential electrode can be used as an alternative tool to verify the results obtained with an oxygen sensor.


1989 ◽  
Vol 21 (10-11) ◽  
pp. 1209-1223 ◽  
Author(s):  
J. Charpentier ◽  
H. Godart ◽  
G. Martin ◽  
Y. Mogno

The control of aeration by measuring the oxidation reduction potential (ORP) of activated sludge, conducted at the YFFINIAC (West of France) sewage plant in 1983, showed this type of regulation to be attractive in that it can optimize energy costs and perfect the removal of carbonaceous and nitrogenous pollutants (CHARPENTIER et al, 1987). From a practical point of view, this new, inexpensive means of regulation has moreover proved easier to implement than the method based on measuring Dissolved Oxygen (D.O.). Before implementingthis process, we undertoook a pilot study that enabled us to make more accurate the ORP values for activated sludge that must be observed in order to achieve the satisfactory removal of carbonaceous and nitrogen pollutants. Furthermore, the ORP readings revealed points of inflection that can be used for regulation purposes. These have been related to the disappearance either of the ammonia or the nitrates with release of phosphates. The experience gained with 7 ORP regulating systems, most of them in operation now for several years, and installed in works with vastly different characteristics, shows that the range of ORP values used corresponds to the pilot-scale experiments. It also shows the attractive features of the ORP signal, compared with that of D.O., when used for the regulation and interpretation of the phenomena involved in the biological treatment. This type of regulation leads to improvements in the annual electricity balance, expressed in terms of kWh v. kg of treated BOD5, and has proved to be compatible with a programmed shutdown of the aerators during the winter peak hours when the tariff per kWh is particularly expensive. In conclusion, the diversity of experiments on site has largely contributed towards the definition of those practical methods upon which depends the success of the system.


1994 ◽  
Vol 30 (6) ◽  
pp. 91-100 ◽  
Author(s):  
Ewa Lie ◽  
Thomas Welander

The influence of low concentrations of dissolved oxygen (DO) and the oxidation-reduction potential (ORP) on the denitrification activity of activated sludge has been studied in batchwise experiments. The ORP was maintained at different levels by automatic titration with air and the denitrification activity was determined by following the disappearance of nitrate. Oxygen was found to have a negative effect on denitrification even at lower concentrations than can be measured with conventional oxygen probes (<0.1 mg/L). The ORP was found to be a useful indicator of the DO concentration at this low level and the denitrification rate was found to decrease linearly with increasing ORP. However, the effect of the ORP on denitrification differed between sludges from different treatment plants. A linear relationship was also found between the ORP and the DO concentration in the region of measurable DO concentrations. Extrapolation of this straight line into the region where DO was under the detection limit indicated that oxygen exerts an inhibitory effect on denitrification at such low concentrations as a few μg/L.


2016 ◽  
Vol 7 (3) ◽  
pp. 264-271 ◽  
Author(s):  
Qingfeng Cheng ◽  
Lichao Nengzi ◽  
Dongying Xu ◽  
Junyuan Guo ◽  
Jing Yu

Two pilot-scale biofilters were used to systematically investigate the influence of nitrite on biological Mn(II) removal. Gibbs free energy change (ΔG) of the redox reaction between MnO2 and NO2– was 122.28 kJ mol–1 in 298 K, suggesting that MnO2 could not react with NO2–. When nitrite in the influent was increased from 0.05 to 0.5 mg L–1, manganese oxides did not react with nitrite in anaerobic conditions; nitrite was quickly oxidized and biological Mn(II) removal was slightly affected in 2 h in aerobic conditions. When nitrite was accumulated in the biofilter by increasing ammonia concentration, nitrite existed for more than 3 d and biological Mn(II) removal was affected in 3 d. When Mn(II) and ammonia in the influent were about 2 and 1.5 mg L–1, respectively, both of them were completely removed and the oxidation-reduction potential was increased with the depth of the filter from 16 to 122 mV. Biological Mn(II) removal followed the first-order reaction, and the k-value was 0.687 min–1.


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