scholarly journals Characterization of RuO2, Ru and Ru0.3Ti0.7O2 materials and their behaviour in hydrogen evolution reaction

2005 ◽  
Vol 11 (3) ◽  
pp. 114-123 ◽  
Author(s):  
Ivo Paseka

Polarization characteristics of the hydrogen evolution reaction were studied at RuO2 Ru0.3Ti0.7O2 and Ru electrodes prepared by various methods. The initial activity of all oxide electrodes, related to the real surface area, was comparable. After a long-term cathodic loading of electrodes the change of physical-chemical properties occurred. Voltametric curves of electrodes showed that ad- and absorption of hydrogen occurred after a long-term cathodic loading. Absorbed hydrogen caused changes of RuO2 lattice parameters and even changes of lattice parameters of the Ti support on which the RuO2 layer was deposited. Arisen stresses in the Ru - oxides layers caused the destruction of the electrode layer and limited life-time of these electrodes.

Nano Energy ◽  
2020 ◽  
Vol 68 ◽  
pp. 104335 ◽  
Author(s):  
Zhigang Chen ◽  
Wenbin Gong ◽  
Shan Cong ◽  
Zhen Wang ◽  
Ge Song ◽  
...  

2015 ◽  
Vol 51 (86) ◽  
pp. 15716-15719 ◽  
Author(s):  
S. S. Shinde ◽  
Abdul Sami ◽  
Dong-Hyung Kim ◽  
Jung-Ho Lee

The scalable hydrothermal synthesis of the SnS/N-rGr hybrid is presented for the first time, which is used as a highly-active electrocatalyst with long-term stability in different media.


RSC Advances ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 5947-5957
Author(s):  
Yun-Wu Li ◽  
Qian Wu ◽  
Rui-Cong Ma ◽  
Xiao-Qi Sun ◽  
Dan-Dan Li ◽  
...  

A porous Co9S8@NS-C-900 composite was fabricated by the pyrolysis of crystal Co-MOF involving thiourea. The composite exhibits efficient electrocatalytic activities and long-term durabilities towards HER in alkaline electrolytes.


2021 ◽  
pp. 116868
Author(s):  
Bashir Adegbemiga Yusuf ◽  
Meng Xie ◽  
Waleed Yaseen ◽  
Chidinma Judith Oluigbo ◽  
Jimin Xie ◽  
...  

Author(s):  
Weilai Yu ◽  
Matthias H Richter ◽  
Ethan D Simonoff ◽  
Bruce S Brunschwig ◽  
Nathan S. Lewis

The long-term stability of p-GaAs photocathodes has been investigated for the hydrogen-evolution reaction (HER) in contact with either 1.0 M H2SO4(aq) or 1.0 M KOH(aq). Stability for the HER was...


Author(s):  
Yong Tan ◽  
Linghan Deng ◽  
Kai Qi ◽  
Chuanxiang Qin ◽  
Si Cheng

Reducing the overpotential and achieving long-term stability of electrocatalysts are vital for facilitating the catalytic activity of hydrogen evolution reaction (HER). Herein, two-dimensional dendritic PdPtCu nanosheets were prepared and further...


Author(s):  
Yanlong Lv ◽  
Jian Ru Gong

The design of a universal synthesize strategy of long-term durable transition metal carbides catalysts with controllable nanostructure and sufficient active sites for hydrogen evolution reaction is challenging. Herein, the in-situ...


2016 ◽  
Vol 4 (10) ◽  
pp. 3947-3954 ◽  
Author(s):  
Xiaojian Yang ◽  
Xiaojia Feng ◽  
Huaqiao Tan ◽  
Hongying Zang ◽  
Xinlong Wang ◽  
...  

New N-doped graphene-coated molybdenum carbide nanoparticles are prepared, which exhibit superior electrocatalytic activity and long-term durability for the hydrogen evolution reaction.


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