scholarly journals The Influence of Tobacco Blend Composition on Carbon Monoxide Formation in Mainstream Cigarette Smoke

2013 ◽  
Vol 64 (1) ◽  
pp. 107-113 ◽  
Author(s):  
Nermina Djulančić ◽  
Vesna Radojičić ◽  
Marija Srbinovska

The aim of this study was to examine the impact of three main tobacco types (flue-cured FC, air-cured AC and sun-cured SC) and two tobacco-based materials (reconstituted tobacco - recon RT and expanded stem) on the formation of carbon monoxide (CO) in the gas phase of mainstream cigarette smoke. The results showed that the type of tobacco examined had a significant impact on the amount of carbon monoxide production in the gas phase of cigarette smoke. AC and SC tobaccos had the most evident impact. The amount of tobacco in mixtures M1, M2 and M3 as well as the addition of expanded stems had an impact on the amount of CO formed in the cigarette smoke. There is weak correlation between CO content in the smoke and the chemical composition of the tobacco. Draw resistance had an impact on CO production. The research results are of great importance, since tobacco selection is the first step in the production of cigarettes with reduced emission of harmful elements contained in the smoke.

2008 ◽  
Vol 17 (Supplement 1) ◽  
pp. i10-i16 ◽  
Author(s):  
G M Polzin ◽  
L Zhang ◽  
B A Hearn ◽  
A D Tavakoli ◽  
C Vaughan ◽  
...  

2020 ◽  
Author(s):  
Panayotis Lavvas ◽  
Anthony Arfaux

<p>Transit observations reveal that a significant population of the detected exoplanets has hazy atmospheres (Sing et al. 2016). Although the relative contribution of clouds and photochemical aerosols is not yet fully clarified, the impact of haze particles on the thermal structure could be significant, as such particles can efficiently scatter and absorb radiation over a large part of the electromagnetic spectrum. Particularly, photochemical aerosols are anticipated to be present at pressures lower than those of cloud formation. The transit observations of HD 189733 b indicate that the haze opacity responsible for the UV-Visible slope is located at pressures between 1μbar and 1 mbar. As such low pressures, the presence of hazes could allow for strong temperature inversions due to the low atmospheric density. We investigate here the implications of such hazes on the exoplanet atmospheric thermal structure.</p> <p>We simulate the atmospheric thermal structure using a 1D radiative-convective model. The model utilizes non-equilibrium chemical composition results (Lavvas et al. 2014) for the gas phase composition, and haze particle size distributions calculated from an aerosol microphysical growth model (Lavvas & Koskinen 2017, Lavvas et al. 2019). We do not yet consider the non-LTE effects for the gases, but we do take into account the impact of temperature disequilibrium between the particles and the gas envelope that can strongly affect the heating efficiency of the particles. We consider various gas phase opacities from atomic and molecular contributions calculated through correlated-k coefficients.</p> <p>Our results demonstrate that in the lower atmosphere the simulated temperature profiles provide emission spectra that are in good agreement with the eclipse observations for the simulated targets (HD 209458 b and HD 189733 b). In the upper atmosphere of the hazy HD 189733 b the simulated haze distribution, which fits the transit observations, results in a strong temperature inversion. On the contrary, the upper atmosphere of the clear HD 209458 b, is significantly colder compared to previous evaluations based on equilibrium chemistry assumption. The implications of these results on the chemical composition will be discussed, as well as results from other exoplanet cases.</p> <p> </p>


2011 ◽  
Vol 23 (sup1) ◽  
pp. 172-183 ◽  
Author(s):  
Charles L. Gaworski ◽  
Karl A. Wagner ◽  
Michael J. Morton ◽  
Michael J. Oldham

2010 ◽  
Vol 43 (3) ◽  
pp. 446-454 ◽  
Author(s):  
Xin Shen ◽  
Kejun Zhong ◽  
Xianjun Sun ◽  
Hongbing Lu ◽  
Yu Shen ◽  
...  

Author(s):  
I. Michelson ◽  
G. Rathkamp

AbstractTreatment of cigarette paper with ammonium sulfamate was found to cause changes in the composition of cigarette smoke, in the concentrations of components of both the gas and particulate phases. The concentrations of several polycyclic hydrocarbons were reduced by over 25 %, though benzo[a]pyrene was virtually unchanged. The concentrations of two nitrosamines were also reduced more than 25 %, while indole and skatole concentrations were reduced about 15 %. Among the gas phase components, acetaldehyde, acrolein and formaldehyde were reduced about 20 %; only carbon monoxide was moderately increased. Since these tests explored only small segments of the spectrum of cigarette smoke components, it is not known which of the observed reductions, if any, contributed to the reduction of biological activity of the smoke of treated cigarettes reported by Bock et al. (8). The tests indicate only that the nature of the smoke has been modified in several respects. The tar and nicotine yield of the treated cigarette was higher than that of the control cigarette, but this can be compensated for by reducing the diameter or length of tobacco rod available to be smoked


1974 ◽  
Vol 57 (1) ◽  
pp. 1-7
Author(s):  
Arthur D Horton ◽  
Michael R Guerin

Abstract Gas-solid chromatographic methods are presented for the determination of carbon monoxide, carbon dioxide, or both simultaneously in the gas phase of cigarette smoke. The methods are optimized to allow quantitative determinations on the entire gas phase delivery of the cigarettes rather than single puffs and to allow the use of small numbers of cigarettes. Shortcomings of several sampling techniques are defined, and evidence is presented supporting the utility of Saran bag sampling and containment. Carbon monoxide and carbon dioxide analyses may be performed with relative standard errors of 2—3% and relative confidence intervals (95%) of 6—9% for determinations involving 4—6 cigarettes.


2002 ◽  
Vol 65 (2) ◽  
pp. 137-145 ◽  
Author(s):  
S Li ◽  
J.L Banyasz ◽  
M.E Parrish ◽  
J Lyons-Hart ◽  
K.H Shafer

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