3-Methylpiperidinyl Carbodithioates as Building Blocks for 1,3-Dithiolium Derivatives
Keyword(s):
Abstract New 1,3-dithiolium derivatives have been synthesized by heterocyclocondensation of various 3-methylpiperidinyl carbodithioates derived from 2-hydroxypropiophenones. Thus, 1,3-dithiolium perchlorates have been obtained by the treatment of the corresponding dithiocarbamates with a mixture of acetic and sulfuric acid, followed by the addition of perchloric acid. 1,3-Dithiolium perchlorates have been converted to the corresponding 2-(1,3-dithiolium) phenolates under weak basic conditions. These phenolates exhibit mesoionic character with an internal charge transfer absorption band.
1983 ◽
Vol 48
(8)
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pp. 2376-2385
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2021 ◽
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2016 ◽
Vol 152
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pp. 1-7
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2010 ◽
Vol 16
(2)
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pp. 568-572
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1982 ◽
pp. 906-907
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1993 ◽
pp. 1611
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