scholarly journals Bottom sediments as a potential source of phosphorus in the riverine-lacustrine system of the Kośna River (Northeastern Poland)

2012 ◽  
Vol 12 (3) ◽  
pp. 115-124 ◽  
Author(s):  
Izabela Bigaj ◽  
Michał Łopata ◽  
Julita Dunalska ◽  
Daniel Szymański ◽  
Rafał Zieliński
Keyword(s):  
Rank Order ◽  
Inorganic Phosphorus ◽  
P Fractions ◽  
Iron Compounds ◽  
Inorganic P ◽  
Potential Source ◽  
Northeastern Poland ◽  
P Fraction ◽  
Labile P ◽  
P Budget

AbstractSediments from hypereutrophic Lake Łajskie localized in northeastern Poland were examined on the basis of P-fraction. The sediments were collected at five sampling sites. In the investigated lake, the rank order of P-fractions was HCl-P > BD-P > NH4Cl-P > NaOH - nrP. The loosely sorbed phosphorus NH4Cl-P represented < 3% of the sedimentary inorganic phosphorus, while the reductant phosphorus (BD-P) ranged from 2 to 10%. The calcium bound phosphorus (HCl-P) showed considerable contribution (59-74%) to the sedimentary inorganic P-loads. BDP was the most reactive fraction in Lake Łajskie. Iron compounds and organic matter seem to play a significant role in regulating this labile P-budget.

Phosphorus Leaching Under Cut Grassland

1999 ◽  
Vol 39 (12) ◽  
pp. 63-67 ◽  
Author(s):  
B. L. Turner ◽  
P. M. Haygarth
Keyword(s):  
Surface Waters ◽  
Large Scale ◽  
Agricultural Land ◽  
Algal Growth ◽  
Soil Types ◽  
P Fractions ◽  
Inorganic P ◽  
Potential Source ◽  
Significant Mechanism ◽  
Total P

Phosphorus (P) transfer from agricultural land to surface waters can contribute to eutrophication, excess algal growth and associated water quality problems. Grasslands have a high potential for P transfer, as they receive P inputs as mineral fertiliser and concentrates cycled through livestock manures. The transfer of P can occur through surface and subsurface pathways, although the capacity of most soils to fix inorganic P has meant that subsurface P transfer by leaching mechanisms has often been perceived as negligible. We investigated this using large-scale monolith lysimeters (135 cm deep, 80 cm diameter) to monitor leachate P under four grassland soil types. Leachate was collected during the 1997–98 drainage year and analysed for a range of P fractions. Mean concentrations of total P routinely exceeded 100 μg l−1 from all soil types and, therefore, exceeded P concentrations above which eutrophication and algal growth can occur. The majority of the leachate P was in algal-available Mo-reactive (inorganic) forms, although a large proportion occurred in unreactive (organic) forms. We suggest that subsurface transfer by leaching can represent a significant mechanism for agricultural P transfer from some soils and must be given greater consideration as a potential source of diffuse P pollution to surface waters.

scholarly journals Influence of Application of Organic Residues of Different Biochemical Quality on Phosphorus Fractions in a Tropical Sandy Soil

Agronomy ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 248
Author(s):  
Tanabhat-Sakorn Sukitprapanon ◽  
Metawee Jantamenchai ◽  
Duangsamorn Tulaphitak ◽  
Nattaporn Prakongkep ◽  
Robert John Gilkes ◽  
...  
Keyword(s):  
Leaf Litter ◽  
Sandy Soil ◽  
Organic Residue ◽  
Residue Quality ◽  
Organic Residues ◽  
P Fractions ◽  
Residual P ◽  
Extractable P ◽  
P Fraction ◽  
Labile P

Understanding phosphorus (P) dynamics in tropical sandy soil treated with organic residues of contrasting quality is crucial for P management using organic amendments. This research determined P fractions in a tropical sandy soil under the application of organic residues of different quality, including groundnut stover (GN), tamarind leaf litter (TM), dipterocarp leaf litter (DP), and rice straw (RS). The organic residues were applied at the rate of 10 t DM ha−1 year−1. The P fractions were examined by a sequential extraction procedure. Organic residue application, regardless of residue quality, resulted in P accumulation in soils. For unamended soil, 55% of total P was mainly associated with Al (hydr)oxides. Organic residue application, regardless of residue quality, diminished the NH4F-extractable P (Al-P) fraction, but it had a nonsignificant effect on NaOH-extractable P (Fe-P). The majority of Al-P and Fe-P fractions were associated with crystalline Al and Fe (hydr)oxides. NH4Cl-extractable P (labile P), NaHCO3-extractable P (exchangeable P and mineralizable organic P), HCl-extractable P (Ca-P), and residual P fractions in soil were significantly increased as a result of the incorporation of organic residues. The application of organic residues, particularly those high in ash alkalinity, increase soil pH, labile P, and Ca-P fractions. In contrast, applications of residues high in lignin and polyphenols increase residual P fraction, which is associated with organo-mineral complexes and clay mineral kaolinite.

scholarly journals Comparison of phosphorus fraction distribution and influencing factors of suspended and surface sediments in the Tiaoxi watershed, China

2017 ◽  
Vol 75 (9) ◽  
pp. 2108-2118 ◽  
Author(s):  
Hongmeng Ye ◽  
Xuyin Yuan ◽  
Lei Han ◽  
Heng Yin ◽  
Jing Jin
Keyword(s):  
Surface Sediments ◽  
Anthropogenic Activities ◽  
Principal Component ◽  
Suspended Sediments ◽  
Inorganic Phosphorus ◽  
P Fractions ◽  
Fraction Distribution ◽  
Inorganic P Fractions ◽  
P Fraction ◽  
Major Factors

Suspended and surface sediments from the Tiaoxi watershed, fed by the Xitiaoxi and Dongtiaoxi rivers, were analyzed for total phosphorus (TP) and the inorganic P fractions of loosely adsorbed P that were extractable with NH4Cl (NH4Cl-P), reductant P (BD-P), metal oxide-bound P extractable with NaOH (NaOH-P), and calcium-bound, HCl-extractable P (HCl-P), while other physicochemical compositions were also determined. The spatial variations of P fractions in these sediments were investigated, and the major factors influencing the various fractions were explored by multivariate statistics. Compared to surface sediments, suspended sediments contained considerably higher concentrations of total nitrogen, TP, organic matter, Al, Fe, Mn and biologically available P (BAP, given as NH4Cl-P, BD-P and NaOH-P combined) and lower concentrations of Si, Ca and HCl-P in the studied catchments. Dongtiaoxi sediments had higher TP, inorganic phosphorus and HCl-P concentrations and a lower BAP content compared with Xitiaoxi sediments, trends that were associated with local geological backgrounds, landscapes and anthropogenic characteristics. The results of principal component analysis showed different effects of sediment properties on P fraction distributions for Xitiaoxi and Dongtiaoxi sediments. The sediment components and structure exert a strong influence on BAP in Xitiaoxi sediments, in contrast to Dongtiaoxi sediments, where P fractions are mainly affected by urbanization and other anthropogenic activities such as shipping.

scholarly journals Effect of cumulative fertilizer dressings on the phosphorus status of mineral soils I Changes in inorganic phosphorus fractions

1989 ◽  
Vol 61 (2) ◽  
pp. 55-59 ◽  
Author(s):  
Helinä Hartikainen
Keyword(s):  
Inorganic Phosphorus ◽  
Soluble Form ◽  
P Fertilization ◽  
P Fractions ◽  
Inorganic P ◽  
Extractable P ◽  
Inorganic P Fractions ◽  
Phosphorus Status ◽  
Mineral Soils ◽  
Inorganic Phosphorus Fractions

Surface soil samples were collected from 16 P fertilization trials before onset of the experiments and after seven years of cultivation. The changes in the inorganic P fractions were investigated in plots amended annually with 0, 30 or 60 kg of P ha-1. In the clay soils, cultivation without P fertilization depleted the NH4F-extractable and NaOH-extractable P reserves by 22—69 kg ha-1 ; in the coarser soils, the respective depletion was 8—140 kg ha-1. H2S04-soluble P decreased in seven soils by 16—34 kg ha-1. In the plots amended totally with 210 or 420 kg of P ha-1, on the other hand, these P fractions increased by 24—174 and 46—368 kg ha-1, respectively. The higher the P dressing was, the more the added P tended to accumulate in the fluoride-soluble form as compared to the alkali-soluble form.

scholarly journals The influences of historic lake trophy and mixing regime changes on long-term phosphorus fractions retention in sediments of deep, eutrophic lakes: a case study from Lake Burgäschi, Switzerland

2019 ◽  
Author(s):  
Luyao Tu ◽  
Paul Zander ◽  
Sönke Szidat ◽  
Ronald Lloren ◽  
Martin Grosjean
Keyword(s):  
Binding Capacity ◽  
Redox Conditions ◽  
P Availability ◽  
P Fractions ◽  
Eutrophic Lakes ◽  
Anoxic Hypolimnion ◽  
P Fraction ◽  
Labile P ◽  
Total P

Abstract. Hypolimnetic anoxia in eutrophic lakes can delay lake recovery to lower trophic states via the release of sediment phosphorus (P) to surface waters on short time scales. However, the effects of hypolimnetic redox conditions and eutrophication on long-term sediment P-fraction retention are not clear yet. In this study, we investigated the sediment profiles since the early 1900s from Lake Burgäschi, a deep, eutrophic lake on the Swiss Plateau. The changes of sediment P-fraction retention were assessed with respect to lake trophic evolution (sedimentary green-pigments proxy), hypolimnetic oxygenation regime (Fe / Mn ratio proxy), sediment geochemical characteristics, and lake restoration history. Results showed that long-term retention of total P and labile P-fractions in sediments was predominantly affected by autochthonous Fe and Mn preserved in anoxic sediments, which were controlled by past hypolimnetic redox conditions. By contrast, refractory HCl-P (Ca-P) fraction retention largely resulted from authigenic CaCO3-P precipitation and increased with higher eutrophic levels. The retention of total P and labile P fractions was considerably reduced in surface sediments from 1977–2017 when Lake Burgäschi had the highest eutrophic levels and a persistent anoxic hypolimnion. We attributed the phenomenon to reduced sediment P-binding capacity (Mn and Fe oxyhydroxides) under the eutrophication-induced anoxic hypolimnion and decreased water-P concentrations due to hypolimnetic withdrawal. Our study implies that in seasonally stratified deep lakes like Lake Burgäschi, hypolimnetic withdrawal of P-enriched water can effectively reduce P retention in sediments and potentials of sediment-P release (seen from low P availability after 1977). However, the restoration has not improved lake trophic state, similarly to the findings from lake limnological survey.

scholarly journals Phosphorus saturation of Finnish soils: evaluating an easy oxalate extraction method

2000 ◽  
Vol 9 (1) ◽  
pp. 61-70 ◽  
Author(s):  
R. UUSITALO ◽  
H.-R. TUHKANEN
Keyword(s):  
Clay Content ◽  
P Fractions ◽  
Runoff Water ◽  
Inorganic P ◽  
P Concentration ◽  
Extractable P ◽  
Inorganic P Fractions ◽  
Phosphorus Saturation ◽  
Labile P ◽  
Oxalate Extraction

The aim of this study was to test whether phosphorus saturation of surface sorption sites of (oxyhydr)oxides of aluminium (Al) and iron (Fe) in Finnish soils can be assessed using a single oxalate extraction and, if so, whether the results are closely related to the P forms likely to influence the P concentration in runoff waters. Ten soil samples with varying clay content and P status were studied. Desorption tests were conducted by submitting the soils sequentially to nine anion exchange resin (AER) extractions. Sorption of P was studied by shaking the soils in P standard solutions (0-250 ppm). Soil inorganic P was characterised by sequentially extracting P from the fractions assumed to be connected to Al and Fe compounds and present as the stable apatitic form. The desorption studies and the fractioning of inorganic P suggested that oxalate solution dissolves apatitic P and/or other relatively stable P-bearing compounds, probably referring to the sum of inorganic P fractions rather than labile P. The amount of P desorbed in the nine AER extractions was about 80-280 mg/kg, whereas oxalate extracted about 490-1100 mg P/kg, which approximated the sum of the inorganic P fractions. Therefore, in soils high in apatitic P, oxalate-extractable P does not seem to be a reliable measure of the P saturation of Al and Fe oxide surfaces that regulate the P concentration in soil solution and runoff water.;

scholarly journals Utilisation of inorganic and organic soil phosphorus in a hill country soil

1992 ◽  
pp. 65-69 ◽  
Author(s):  
K.W. Perrott
Keyword(s):  
Phosphate Rock ◽  
Organic Phosphorus ◽  
Soil Phosphorus ◽  
Organic Soil ◽  
Inorganic Phosphorus ◽  
P Fractions ◽  
Inorganic P ◽  
Soil P ◽  
Hill Country ◽  
Phosphate Rock Residues

Changes in phosphorus (P) fractions of unfertilised and fertilised (superphosphate) soil were investigated over five years at a hill country site near Te Kuiti. Only soil inorganic P (Pi) reserves were utilised for plant uptake when superphosphate was withheld at the site. Immobilisation of P as soil organic P (PO) contributed to depletion of the soil Pi reserves during the first two years of this trial. Where superphosphate was applied, immobilisation of P as PO amounted to about 25% of applied P during the five years measurements were made. Changes in soil P fractions indicated that all forms of soil Pi were utilised when superphosphate was withheld. These included readily available Pi, Al- Pi, Fe-Pi, and residual phosphate rock from previous fertiliser applications. Depletion of the phosphate rock residues in the soil also occurred where superphosphate was applied and appears to have been completed within about two years. The phosphate rock residues had probably accumulated because of the relatively high amounts of unacidulated phosphate rock in superphosphate manufactured before 1983. Accumulation of Po associated with humic acid, or adsorbed on surfaces of hy drous oxides of Al and Fe, occurred in both fertilised and unfertilised soils. The more labile forms of PO also increased in the fertilised soil. Keywords inorganic phosphorus, organic phosphorus, phosphorus immobilisation, soil phosphorus, soil phosphorus fractions, soil phosphorus utilisation.

Soil P fractions as affected by on-farm composts in a controlled incubation study

2003 ◽  
Vol 83 (2) ◽  
pp. 223-226 ◽  
Author(s):  
B. Gagnon and R. R. Simard
Keyword(s):  
Poultry Litter ◽  
Extraction Procedure ◽  
Dairy Manure ◽  
P Availability ◽  
P Fractions ◽  
P Fractionation ◽  
Soil P ◽  
P Fraction ◽  
Labile P ◽  
On Farm

Information on the different forms and availability of P following compost addition to soil may help to better manage manure in respect to plant growth and the environment. An experiment was conducted to investigate through a sequential extraction procedure the availability of P of fresh dairy manure and several on-farm compost-soil mixtures after a 13 wk incubation in glass jars at 35°C. Materials were mixed at a rate of 200 mg N kg-1 with an Arago sandy loam (Humo-Ferric Podzol), supplying from 64 to 301 mg P kg-1. Fresh dairy manure gave the highest net increase of resin-P and labile P fractions in terms of percentage of total P added, whereas poultry litter compost was the most efficient in increasing NaHCO3-inorganic P (-Pi). Among compost materials, poultry litter, vegetable residue and sheep manure increased labile P fraction the most. The contribution of the young dairy manure compost to this fraction was largely negative, and lower than those of fresh manure or partially and well-decomposed manure composts. A large part of added P was found in the moderately labile P fraction. The organic P (Po) fractions in the soil were less affected by manure or compost addition. This study indicated that the material P availability was reduced by composting, and was more affected by the origin of residue than by manure management. Key words: Composting, farm manure, soil P fractionation

scholarly journals The influences of historic lake trophy and mixing regime changes on long-term phosphorus fraction retention in sediments of deep eutrophic lakes: a case study from Lake Burgäschi, Switzerland

2020 ◽  
Vol 17 (10) ◽  
pp. 2715-2729 ◽  
Author(s):  
Luyao Tu ◽  
Paul Zander ◽  
Sönke Szidat ◽  
Ronald Lloren ◽  
Martin Grosjean
Keyword(s):  
Trophic State ◽  
Surface Sediments ◽  
P Fractions ◽  
Deep Lakes ◽  
Eutrophic Lakes ◽  
P Fraction ◽  
Labile P ◽  
Total P ◽  
P Retention

Abstract. Hypolimnetic anoxia in eutrophic lakes can delay lake recovery to lower trophic states via the release of sediment phosphorus (P) to surface waters on short timescales in shallow lakes. However, the long-term effects of hypolimnetic redox conditions and trophic state on sedimentary P fraction retention in deep lakes are not clear yet. Hypolimnetic withdrawal of P-rich water is predicted to diminish sedimentary P and seasonal P recycling from the lake hypolimnion. Nevertheless, there is a lack of evidence from well-dated sediment cores, in particular from deep lakes, about the long-term impact of hypolimnetic withdrawal on sedimentary P retention. In this study, long-term sedimentary P fraction data since the early 1900s from Lake Burgäschi provide information on benthic P retention under the influence of increasing lake primary productivity (sedimentary green-pigment proxy), variable hypolimnion oxygenation regimes (Fe∕Mn ratio proxy), and hypolimnetic withdrawal since 1977. Results show that before hypolimnetic withdrawal (during the early 1900s to 1977), the redox-sensitive Fe∕Mn-P fraction comprised ∼50 % of total P (TP) in the sediment profile. Meanwhile, long-term retention of total P and labile P fractions in sediments was predominantly affected by past hypolimnetic redox conditions, and P retention increased in sedimentary Fe- and Mn-enriched layers when the sediment-overlaying water was seasonally oxic. However, from 1977 to 2017, due to eutrophication-induced persistent anoxic conditions in the hypolimnion and to hypolimnetic water withdrawal increasing the P export out of the lake, net burial rates of total and labile P fractions decreased considerably in surface sediments. By contrast, refractory Ca–P fraction retention was primarily related to lake primary production. Due to lake restoration since 1977, the Ca–P fraction became the primary P fraction in sediments (representing ∼39 % of total P), indicating a lower P bioavailability of surface sediments. Our study implies that in seasonally stratified eutrophic deep lakes (like Lake Burgäschi), hypolimnetic withdrawal can effectively reduce P retention in sediments and potential for sediment P release (internal P loads). However, after more than 40 years of hypolimnetic syphoning, the lake trophic state has not improved nor has lake productivity decreased. Furthermore, this restoration has not enhanced water column mixing and oxygenation in hypolimnetic waters. The findings of this study are relevant regarding the management of deep eutrophic lakes with mixing regimes typical for temperate zones.

scholarly journals Distribution of Phosphorus Fractions down the Soil Depth in the Savanna Zone of Nigeria

2017 ◽  
Vol 9 (9) ◽  
pp. 94
Author(s):  
A. O. Ojo ◽  
V. O. Aduramigba-Modupe ◽  
O. D. Adeoyolanu ◽  
O. A. Denton ◽  
A. O. Oyedele ◽  
...  
Keyword(s):  
Management Practices ◽  
Soil Depth ◽  
Soil Management ◽  
Soil Series ◽  
P Fractions ◽  
Inorganic P ◽  
Extractable P ◽  
Initial Decrease ◽  
P Fraction ◽  
Savanna Zone

The distribution of phosphorus (P) fractions down the soil depth varies depending on the soil type as being affected by the surrounding soil management practices. A 10 km by 10 km site was chosen in the savanna zone of Nigeria for the study. Modal soil profile pits were dug to identify the different soil types while soil sampling was done at 0-20 cm, 20-40 cm, 40-80 cm and 80-120 cm depth. Resin P was the largest extractable P fraction while residual P was the least in the soil series characterized, down the soil depth. Fractionation results showed that there was variation down the soil depth. The conc. HCl-Pi was not observed at the 0-20 cm depth, NaHCO3-Pi and Po was small while NaOH-Pi and Po was observed at this depth. Initial decrease at the 20-40 cm depth was observed for most of the P fractions while more of the P fractions were observed at the 40-80 cm depth. The values observed at the 80-120 cm depth was however small compared to other soil depth. Resin P was the sink of P and would serve as a reserve of P in the soil series. However, organic and inorganic P extractable with NaOH i.e. NaOH Pi and Po which were high at the 0-20 cm depth would be mainly responsible for the availability of P in the soil solution for plant uptake.

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