organic phosphorus
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CATENA ◽  
2022 ◽  
Vol 211 ◽  
pp. 106000
Author(s):  
Xin Tian ◽  
Haijian Bing ◽  
Yanhong Wu ◽  
He Zhu ◽  
Wei Zhao ◽  
...  

2022 ◽  
Vol 9 ◽  
Author(s):  
Wei Yu ◽  
Haiquan Yang ◽  
Jingan Chen ◽  
Peng Liao ◽  
Quan Chen ◽  
...  

Macrophyte-dominated eutrophication (MDE) lakes have attracted wide attention due to the high phosphorus (P) loading in sediments that poses a wide spread risk for P release and pollution management. However, because of the superior productivity characteristics, the role of organic P mineralization in sediments in the internal P loading of MDE lake is still under debate. This study investigated the release dynamic of P in the sediments of Lake Caohai, a MDE lake in southwest of China, using a combination of the modified Huffer sequential extraction method, 31P nuclear magnetic resonance spectroscopy (NMR), and composite diffusive gradient in thin films (DGT) technology. Results showed that the apparent P diffusion flux at the sediment-water interface was remarkably high, with a mean value of 0.37 mg m−2 d−1. The phosphate ester organophosphorus components (i.e., Mono-P and Diester-P) continuously deposited and degraded in the sediments maintained the high productivity of the lake, and the mineralization process plays a critical role in the release of internal P. Although the content of inorganic P in sediment is relatively high (accounting for approximately 60% of total P), the reductive mechanism based on P-containing iron oxide/hydroxide has a low contribution to the internal P loading, as was indicated by the low release rate of P-combination iron-manganese (Fe-Mn)/iron-aluminum (Fe-Al) (BD-P and NaOH-P) and the insignificant positive correlations between DGT-labile P and DGT-labile Fe in the sediment cores. Additionally, organic P in sediments could transfer to P-combination Fe-Al/Fe-Mn. However, in severely expropriated environments, the enrichment of P-combination Fe-Al/Fe-Mn in surface sediments inhibited the mineralization of monophosphate to some degree. Taken together, this study emphasized the impact of sediment organic P loading on the release of internal P in lake, highlighting that organic P is also the valuable objects for avoiding eutrophication of MDE lakes.


Author(s):  
Mengke Zhu ◽  
Bocong Huang ◽  
Zongyang Liu ◽  
yue Wang ◽  
jiao Teng ◽  
...  

The distribution and availability of phosphorus (P) fractions in restored cut slope soil aggregates along altitude gradients were studied. We examined soil aggregates total phosphorus (TP), available phosphorus (AP) and phosphorus activation coefficient (PAC), and discovered that there was no significant difference in TP at four altitudes (p> 0.05), but there was a significant difference in AP at 3009 m, 3347 m and 3980 m (p< 0.05). At 3009 m, 3347 m and 3654 m, the AP accumulation in small size aggregates were more advantageous. Overall, PAC dropped steadily as aggregate size increased, as shown by PAC (3654 m)> PAC (3347 m)> PAC (3009 m)> PAC (3980 m) in altitudes. In all particle size soil aggregates, total inorganic phosphorus (TPi) > total organic phosphorus (TPo) > residual phosphorus (R-P) at 3009 m, 3347 m and 3654 m; TPo> TPi> R-P at 3980 m. Through correlation and multiple stepwise regression analysis, we concluded that active NaHCO3-Pi was the main AP source. It was suggested that more attention should be paid to the ratio of small particle size aggregates, so as to increase soil AP storage. At low (3009 m) and high altitude (3980 m), inorganic P fertilizer and P activator were added into soil to improve the activation ability of soil P and the AP supply, so as to promote the healthy development of slope soils ecosystem.


Geoderma ◽  
2022 ◽  
Vol 405 ◽  
pp. 115462
Author(s):  
Metawee Jantamenchai ◽  
Tanabhat-Sakorn Sukitprapanon ◽  
Duangsamorn Tulaphitak ◽  
Wanwimon Mekboonsonglarp ◽  
Patma Vityakon

2021 ◽  
Vol 14 (1) ◽  
pp. 387
Author(s):  
Yan-Jhang Chen ◽  
Li-Pang Wang ◽  
Sandhya Babel

In a world with a growing human population, resources are becoming increasingly scarce. To ensure food supply, fertilizers are often used to accelerate growth when planting agricultural products. Sewage sludge (SS), containing as high as 10–15 wt% Phosphorus (P), can be synthesized into liquid fertilizer. P species in SS can generally be classified into four types: inorganic phosphorus (IP), organic phosphorus (OP), nonapatite inorganic phosphorus (NAIP), and apatite phosphorus (AP). However, OP is not leached out by wet chemical methods and NAIP is not bioavailable. This study investigated the P-form conversion (OP and NAIP to AP) in SS by adding 8 wt% CaO at 300 °C. SS through pretreatment can easily leach out P when combined with organic acid. The content of heavy metals is in accordance with fertilizer regulations in a leaching solution. The solution was mixed with potassium and ammonia compounds to synthesize a liquid fertilizer. To ensure the safe and efficient use of liquid fertilizer and undertake an analysis of heavy metals, an aquatic organisms (D. magna) toxicity test, and the growth of plants test were both used. The liquid fertilizer can be demonstrated to accelerate the growth of plants while not causing the death of D. magna in short time, as the liquid fertilizer has enough nutrients to help the D. magna to survive.


Water ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 27
Author(s):  
Dandan Liu ◽  
Xueying Li ◽  
Yue Zhang ◽  
Zhibo Lu ◽  
Lu Bai ◽  
...  

Understanding the distribution and transportation of phosphorus is vital for the sustainable development of aquatic environmental protection and ecological security. The spatial–temporal distribution of phosphorus fractions in water–sediment phases in river systems and their relationships remain unclear in Southwest China. In this study, the spatial and temporal distribution of phosphorus fractions in water–sediment phases in the Tuojiang River, a primary tributary of the Yangtze River which plays important roles in the economy and ecology of the region, and the relationships among the different phosphorus fractions were analyzed. These fractions were soluble reactive phosphorus (SRP), dissolved organic phosphorus (DOP), and total particulate phosphorus (PP) fractions in water, and exchangeable phosphorus (Ex-P), organic phosphorus (Or-P), phosphorus bound by Fe oxides (Fe-P), authigenic phosphorus (Ca-P), detrital phosphorus (De-P), and refractory phosphorus (Res-P) fractions in sediment. The SPR and Fe-P were the dominant phosphorus fractions in the water and sediment, respectively. The TP content was greater in the lower reaches than in the middle and upper reaches. The average abundances of most phosphorus fractions in water–sediment phases showed significant seasonal variations. The Fe-P, Org-P, and TP in sediments were released to the water interface, resulting in the increase of phosphorus in the overlying water. Redundancy analysis (RDA) indicated that the physicochemical properties of water and sediment have a certain influence on the spatial–temporal distribution of the phosphorus fractions. Principal component analysis (PCA) revealed that the main phosphorus source was anthropogenic activities. These results provide primary data regarding phosphorus fractions and contribute to understanding phosphorus cycling and controlling phosphorus pollution in the Tuojiang River.


Author(s):  
Junqiu Wu ◽  
Yue Zhao ◽  
Ran Zhao ◽  
Liming Jia ◽  
Zimin Wei

To explore the eutrophication degree in the typical lakes and reservoirs of the northeast region of China, the bioavailability of dissolved organic phosphorus (DOP) of the lakes has been examined in this study. The laboratory incubation was carried out at 20 °C for 55 days and the concentrations of total dissolved phosphorus (TDP), dissolved reactive phosphorus (DRP), DOP and the microbial biomass have been detected. Results showed that, during the process of incubation, the concentrations of TDP and DRP were increased, whereas the DOP was decreased, which leads to the decreased mineralization rate. In addition, the changes of microbial biomass were fluctuant, but they had significantly positive effects on the concentration changes and mineralization rate of DOP (p < 0.05). The correlation analysis among the phosphate fractions showed that the TDP significantly promoted the DRP concentration, mineralization rate of DOP and the cumulative mineralization of DOP. The kinetics model was conducted to predict the further mineralization of DOP and to analyze the pollution degree of the eight lakes and reservoirs. Accordingly, the lakes with high DRP and TDP had worse water quality and are prone to algae blooms.


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