Pollution Assessment of Surface and Drainage Water by Heavy Elements in Al Ahrar District, Wasit Governorate, Iraq

2018 ◽  
Vol 59 (2B) ◽  
1988 ◽  
Vol 132 ◽  
pp. 501-506
Author(s):  
C. Sneden ◽  
C. A. Pilachowski ◽  
K. K. Gilroy ◽  
J. J. Cowan

Current observational results for the abundances of the very heavy elements (Z>30) in Population II halo stars are reviewed. New high resolution, low noise spectra of many of these extremely metal-poor stars reveal general consistency in their overall abundance patterns. Below Galactic metallicities of [Fe/H] Ã −2, all of the very heavy elements were manufactured almost exclusively in r-process synthesis events. However, there is considerable star-to-star scatter in the overall level of very heavy element abundances, indicating the influence of local supernovas on element production in the very early, unmixed Galactic halo. The s-process appears to contribute substantially to stellar abundances only in stars more metal-rich than [Fe/H] Ã −2.


Author(s):  
T. Oikawa ◽  
M. Inoue ◽  
T. Honda ◽  
Y. Kokubo

EELS allows us to make analysis of light elements such as hydrogen to heavy elements of microareas on the specimen. In energy loss spectra, however, elemental signals ride on a high background; therefore, the signal/background (S/B) ratio is very low in EELS. A technique which collects the center beam axial-symmetrically in the scattering angle is generally used to obtain high total intensity. However, the technique collects high background intensity together with elemental signals; therefore, the technique does not improve the S/B ratio. This report presents the experimental results of the S/B ratio measured as a function of the scattering angle and shows the possibility of the S/B ratio being improved in the high scattering angle range.Energy loss spectra have been measured using a JEM-200CX TEM with an energy analyzer ASEA3 at 200 kV.Fig.l shows a typical K-shell electron excitation edge riding on background in an energy loss spectrum.


Author(s):  
Noriyuki Kuwano ◽  
Masaru Itakura ◽  
Kensuke Oki

Pd-Ce alloys exhibit various anomalies in physical properties due to mixed valences of Ce, and the anomalies are thought to be strongly related with the crystal structures. Since Pd and Ce are both heavy elements, relative magnitudes of (fcc-fpd) are so small compared with <f> that superlattice reflections, even if any, sometimes cannot be detected in conventional x-ray powder patterns, where fee and fpd are atomic scattering factors of Ce and Pd, and <f> the mean value in the crystal. However, superlattices in Pd-Ce alloys can be analyzed by electron microscopy, thanks to the high detectability of electron diffraction. In this work, we investigated modulated superstructures in alloys with 12.5 and 15.0 at.%Ce.Ingots of Pd-Ce alloys were prepared in an arc furnace under atmosphere of ultra high purity argon. The disc specimens cut out from the ingots were heat-treated in vacuum and electrothinned to electron transparency by a jet method.


Author(s):  
Saulius GUŽYS ◽  
Stefanija MISEVIČIENĖ

The use of nitrogen fertilizer is becoming a global problem; however continuous fertilization with nitrogen ensures large and constant harvests. An 8 year research (2006–2013) was conducted to evaluate the relationships between differently fertilized cultivated plant rotations. The research was conducted in Lipliunai (Lithuania) in the agroecosystem with nitrogen metabolism in fields with deeper carbonaceous soil, i.e. Endocalcari Endohypogleyic Cambisol (CMg-n-w-can). The research area covered three drained plots where crop rotation of differently fertilized cereals and perennial grasses was applied. Samples of soil, water and plants were investigated in the Chemical Analysis Laboratory of the Aleksandras Stulginskis University certified by the Environment Ministry of the Republic of Lithuania. The greatest productivity was found in a crop rotation with higher fertilization (N32-140). In crop rotation with lower fertilization (N24-90) productivity of cereals and perennial grasses (N0-80) was 11–35 % lower. The highest amount of mineral soil nitrogen was found in cereal crop rotation with higher fertilization. It was influenced by fertilization and crop productivity. The lowest Nmin and Ntotal concentrations in drainage water were found in grasses crop rotation. Crop rotations of differently fertilized cereals increased nitrogen concentration in drainage water. Nmin concentration in water depended on crop productivity, quantity of mineral soil nitrogen, fertilization, and nitrogen balance. The lowest nitrogen leaching was found in the crop rotation of grasses. Cereal crop rotation increased nitrogen leaching by 12–42 %. The usage of all crop rotations resulted in a negative nitrogen balance, which essentially depended on fertilization with nitrogen fertilizer.


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