In loop heat pipes (LHPs), wick materials and their structures are important in achieving continuous heat transfer with a favorable distribution of the working fluid. This article introduces the characteristics of loop heat pipes with different wicks: (i) sintered stainless steel and (ii) ceramic. The evaporator has a flat-rectangular assembly under gravity-assisted conditions. Water was used as a working fluid, and the performance of the LHP was analyzed in terms of temperatures at different locations of the LHP and thermal resistance. As to the results, a stable operation can be maintained in the range of 50 to 520 W for the LHP with the stainless-steel wick, matching the desired limited temperature for electronics of 85 °C at the heater surface at 350 W (129.6 kW·m−2). Results using the ceramic wick showed that a heater surface temperature of below 85 °C could be obtained when operating at 54 W (20 kW·m−2).