Role and Effect of Ionic Groups of Polymer as a Surface Sizing Agent

2007 ◽  
Vol 61 (5) ◽  
pp. 556-561
Author(s):  
Takahiro Fujiwara
Keyword(s):  
TAPPI Journal ◽  
2010 ◽  
Vol 9 (7) ◽  
pp. 15-21 ◽  
Author(s):  
JI-YOUNG LEE ◽  
CHUL-HWAN KIM ◽  
JEONG-MIN SEO ◽  
HO-KYUNG CHUNG ◽  
KYUNG-KIL BACK ◽  
...  

Eco-friendly cushioning materials were made with thermomechanical pulps (TMPs) from waste woods collected from local mountains in Korea, using a suction-forming method without physical pressing. The TMP cushions had superior shock-absorbing performance, with lower elastic moduli than expanded polystyrene (EPS) or molded pulp. Even though the TMP cushions made using various suction times had many voids in their inner fiber structure, their apparent densities were a little higher than that of EPS and much lower than that of molded pulp. The addition of cationic starch contributed to an increase in the elastic modulus of the TMP cushions without increasing the apparent density, an effect which was different from that of surface sizing with starch. In the impact test, the TMP cushions showed a more ductile pattern than the brittle EPS. The porosity of the TMP cushion was a little less than that of EPS and much greater than that of molded pulp. The porous structure of the TMP cushions contributed to their excellent thermal insulating capacity, which was equivalent to that of EPS. In summary, the TMP packing cushions showed great potential for surviving external impacts during product distribution.


TAPPI Journal ◽  
2009 ◽  
Vol 8 (2) ◽  
pp. 33-38 ◽  
Author(s):  
ANNA JONHED ◽  
LARS JÄRNSTRÖM

The aim of this study was to investigate the properties of hydrophobically modified (HM) quaterna-ry ammonium starch ethers for paper sizing. These starches possess temperature-responsive properties; that is, gelation or phase separation occurs at a certain temperature upon cooling. This insolubility of the HM starches in water at room temperature improved their performance as sizing agents. The contact angles for water on sized liner were substantially larger than on unsized liner. When the application temperature was well above the critical phase-separation temperature, larger contact angles were obtained for liner independently of pH compared with those at the lower application temperature. Cobb60 values for liner decreased upon surface sizing, with a low pH and high application temperature giving lower water penetration. Contact angles on greaseproof paper decreased upon sur-face sizing as compared to unsized greaseproof paper, independently of pH and temperature. Greaseproof paper showed no great difference between unsized substrates and substrates sized with HM starch at different pH. This is probably due to the already hydrophobic nature of greaseproof paper. However, the Cobb60 values increased at low pH and low application temperature. Surfactants were added to investigate how they affect the sized surface. Addition of surfactant reduces the contact angles, in spite of indications of complex formation.


1964 ◽  
Vol 18 (4) ◽  
pp. 161-168
Author(s):  
Ten Yoshii ◽  
Shigehiko Yoshioka ◽  
Keisaburo Tabuchi

2012 ◽  
Vol 66 (8) ◽  
pp. 844-851
Author(s):  
Mitsuhiro Yamazaki
Keyword(s):  

2017 ◽  
Vol 71 (4) ◽  
pp. 388-393
Author(s):  
Shiro Umeuchi

2018 ◽  
Vol 20 (1) ◽  
pp. 14-21 ◽  
Author(s):  
Xavier Santarelli ◽  
Charlotte Cabanne

Mixed mode chromatography offers a diversity of ligands, each providing a new selectivity. This allows the design of novel purification processes with reduced column steps. Structure of ligands is based on both hydrophobic and ionic groups. Thanks to its salt tolerance, crude extracts or post-IEX samples can be loaded directly without conditioning. The selectivity could be enhanced by modulating elution parameters or by using additives. More importantly, mixed mode chromatography could be as effective as affinity chromatography for mAb purification processes. Mixed mode chromatography opens the way to short and economical processes.


1956 ◽  
Vol 145 (921) ◽  
pp. 554-563 ◽  

The proteins concerned have been spread at the air/water interface on a substrate at physio­logical ionic strengths. Spread protein A has been ‘injected’ with dissolved protein B , and the increase in pressure observed has been attributed to adsorption. This adsorption has been found to depend on the area per molecule of the spread protein, reaching a maximum value at an intermediate area value. It is postulated that adsorption occurs by hydrogen bonds between B and A , and that at a certain stage of compression the bonding groups in A turn so as to form hydrogen bonds within the monolayer, a theory which accords with compressibility and viscosity data on the monolayers. The rate of increase of pressure depends markedly on ionic strength suggesting that the rate of adsorption is influenced by the interaction of ionic groups in A and B . No evidence was obtained for a surface clotting reaction or specific interaction between fibrinogen and thrombin, whichever protein formed the monolayer, suggesting that the specific interaction involves at least two groups in each protein held at a critical spacing.


2012 ◽  
Vol 200 ◽  
pp. 287-291 ◽  
Author(s):  
Quan Xiao Liu ◽  
Wen Cai Xu ◽  
Yan Na Yin

Cationic polyacrylate emulsion was used as surface sizing agent and the effects of emulsion properties on paper mechanical properties were studied. The mechanical properties of sized paper gradually increased with the increase of solid content, viscosity and positive charge density of emulsion and decreased with the increase of particle size of emulsion. Tensile strength, folding endurance and tearing strength on machine direction were increased 33.62%, 11.99%, 6.79% respectively when the paper with single emulsion layer was used oven drying methods.


ACS Nano ◽  
2014 ◽  
Vol 8 (7) ◽  
pp. 6663-6670 ◽  
Author(s):  
Lu Zhang ◽  
Zijian Zhang ◽  
Chaozheng He ◽  
Liming Dai ◽  
Jun Liu ◽  
...  
Keyword(s):  

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