Reductive Electrophotocatalysis: Merging Electricity and Light to Achieve Extreme Reduction Potentials
Keyword(s):
We describe a new electrophotocatalytic strategy that harnesses the power of light and electricity to generate an excited radical anion with a reducing potential of –3.2 V vs. SCE, which can be used to activate substrates with very high reduction potentials (<i>E</i><sub>red</sub> ~ –1.9 to –2.9 V). The resultant aryl radicals can be engaged in various synthetically useful transformations to furnish arylboronate, arylstannane, and biaryl products.<br>
2021 ◽
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2021 ◽
Keyword(s):
2020 ◽
Keyword(s):
2011 ◽
Vol 1
(3)
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pp. 241-255
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Keyword(s):
2008 ◽
Vol 584-586
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pp. 327-332
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2013 ◽
Vol 21
(2)
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pp. 73-78
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