Stability constants and thermodynamic parameters of cadmium complexes with sulfonamides and cephapirin
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Stability constant (log ) and thermodynamic parameters of Cd2+ complexes with sulfonamide and cephapirin were determined by Polarographic technique at pH = 7.30 ± 0.01 and μ = 1.0 MKNO3 at 250°C. The sulfonamides were sulfadiazine, sulfisoxazole, sulfamethaxazole, sulfamethazine, sulfathiazole, sulfacetamide and sulfanilamide used as primary ligands and cephapirin as secondaryligand. Cd2+ formed 1:1:1, 1:2:1 and 1:1:2 complexes. The nature of electrode processes were reversible and diffusion controlled. The stability constants and thermodynamic parameters (G, Hand S) were determined. The formation of the metal complexes has been found to be spontaneous, exothermic in nature, and entropically unfavourable at higher temperature.
1988 ◽
Vol 119
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pp. 1263-1278
1980 ◽
pp. 865
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1970 ◽
Vol 25
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pp. 19-28
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2021 ◽
Vol 18
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pp. 14-32
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2003 ◽
Vol 68
(10)
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pp. 729-749
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