scholarly journals Heavy Oil Residue Upgrading With Iron Based Catalysts Under High Hydrogen Pressure

Author(s):  
Savaş GÜRDAL ◽  
Kadir YILMAZ ◽  
Muzaffer YAŞAR
Energies ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3557
Author(s):  
Athina Mandalenaki ◽  
Nicolas Kalogerakis ◽  
Eleftheria Antoniou

Typically, oil pollution cleanup procedures following first response actions include dispersion. Crude oil is biodegradable, and its bioavailability can be increased when dispersed into very fine droplets by means of chemical surfactants. Although their use is widely spread in many applications, the latter may prove toxic, depending on the extent of use. The use of biological means, such as bioremediation and biosurfactants, has emerged over the past years as a very promising ‘green’ alternative technology. Biosurfactants (BSs) are amphiphilic molecules produced by microorganisms during biodegradation, thus increasing the bioavailability of the organic pollutants. It is their biodegradability and low toxicity that render BSs as a very promising alternative to the synthetic ones. Alcanivorax borkumensis SK2 strain ability to produce BSs, without any impurities from the substrate, was investigated. The biosurfactant production was scaled up by means of a sequencing batch reactor (SBR) and a heavy oil residue substrate as the carbon source. The product is free from substrate impurities, and its efficiency is tested on oil bioremediation in the marine environment. The product’s dispersion efficiency was determined by the baffled flask test. The production method proposed can have a significant impact to the market, given the ever-increasing demand for ecologically friendly, reliable, commercially viable and economically competitive environmental cleanup techniques.


Physica B+C ◽  
1986 ◽  
Vol 139-140 ◽  
pp. 694-697 ◽  
Author(s):  
A. Driessen ◽  
H. Hemmes ◽  
R. Griessen

2016 ◽  
Vol 388 ◽  
pp. 723-730 ◽  
Author(s):  
S.M. Filipek ◽  
V. Paul-Boncour ◽  
R.S. Liu ◽  
I. Jacob ◽  
T. Tsutaoka ◽  
...  

2008 ◽  
Vol 23 (5) ◽  
pp. 1393-1397 ◽  
Author(s):  
Yongzhen Yang ◽  
Xuguang Liu ◽  
Bingshe Xu

Fe-encapsulating carbon nano onionlike fullerenes (NOLFs) were obtained by chemical vapor deposition (CVD) using heavy oil residue as carbon source and ferrocene as catalyst precursor in an argon flow of 150 mL/min at 900 °C for 30 min. Field-emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HRTEM), energy-dispersive spectroscopy (EDS), x-ray diffraction (XRD), and Raman spectroscopy were used to characterize morphology and microstructure of the products. The results show that Fe-encapsulating NOLFs collected at the outlet zone of quartz tube had core/shell structures with sizes ranging from 3 to 6 nm and outer shells composed of poorly crystallized graphitic layers. Their growth followed particle self-assembling growth mechanism, and all atoms in the graphite sheets primarily arose from Fe-carbide nanoparticles.


2002 ◽  
Vol 14 (44) ◽  
pp. 11151-11156 ◽  
Author(s):  
M Dorogova ◽  
T Hirata ◽  
S M Filipek ◽  
H Bala

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