heavy oil residues
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2021 ◽  
Vol 9 (11) ◽  
pp. 1235
Author(s):  
Ksenia I. Smyshlyaeva ◽  
Viacheslav A. Rudko ◽  
Vladimir G. Povarov ◽  
Alina A. Shaidulina ◽  
Ignaty Efimov ◽  
...  

The effects of asphaltenes from two heavy oil residues on the sedimentation stability of residual marine fuels were assessed and compared. As base components of residual marine fuels, the vacuum residue (VacRes) and visbreaking residue (VisRes) were taken. The heptane-insoluble fractions (HI-fractions), including asphaltenes, isolated from vacuum residue and visbreaking residue, were analyzed to determine the elemental composition (XRF) and cluster parameters (XRD). The results of the analysis of the parameters of the asphaltene cluster (HI-fraction) for vacuum residue and visbreaking residue showed that dγ – 6.1 and 5.9 Å, Lc – 26.72 and 20.78 Å, and La – 7.68 and 7.20 Å. The sedimentation stability of residual marine fuel was determined according to the ISO 10307-1-2009 (TSA) method and described using ternary phase diagrams. The ratio of stable compositions to the total number of possible compositions (with a step of 10 wt%) was 65/66 or 98.5% for residual marine fuel comprising a mixture VacRes/ULSD/LCGO (vacuum residue/ultra-low sulphur diesel/light catalytic gas oil). Meanwhile, the ratio of stable compositions to the total number of possible compositions was 38/66 or 57.6% for residual marine fuel comprising a mixture VisRes/ULSD/LCGO (visbreaking residue/ultra-low sulphur diesel/light catalytic gas oil).


Energies ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3557
Author(s):  
Athina Mandalenaki ◽  
Nicolas Kalogerakis ◽  
Eleftheria Antoniou

Typically, oil pollution cleanup procedures following first response actions include dispersion. Crude oil is biodegradable, and its bioavailability can be increased when dispersed into very fine droplets by means of chemical surfactants. Although their use is widely spread in many applications, the latter may prove toxic, depending on the extent of use. The use of biological means, such as bioremediation and biosurfactants, has emerged over the past years as a very promising ‘green’ alternative technology. Biosurfactants (BSs) are amphiphilic molecules produced by microorganisms during biodegradation, thus increasing the bioavailability of the organic pollutants. It is their biodegradability and low toxicity that render BSs as a very promising alternative to the synthetic ones. Alcanivorax borkumensis SK2 strain ability to produce BSs, without any impurities from the substrate, was investigated. The biosurfactant production was scaled up by means of a sequencing batch reactor (SBR) and a heavy oil residue substrate as the carbon source. The product is free from substrate impurities, and its efficiency is tested on oil bioremediation in the marine environment. The product’s dispersion efficiency was determined by the baffled flask test. The production method proposed can have a significant impact to the market, given the ever-increasing demand for ecologically friendly, reliable, commercially viable and economically competitive environmental cleanup techniques.


2021 ◽  
Vol 248 ◽  
pp. 272-280
Author(s):  
Natalya Kondrasheva ◽  
Elizaveta Kireeva ◽  
Olga Zyryanova

Dust control in summer and winter periods is a topical problem associated with conducting open pit mining operations; however, at negative temperatures the additional requirements are imposed on dust suppressants. Preventive compositions are proposed, in which light and heavy gas oils, obtained from catalytic cracking and delayed coking, are used as base components. Involvement of heavy fractions allows to increase the flash point, thereby reducing the flammability of dust suppressant, improve its adhesion properties by increasing the content of polyaromatic hydrocarbons and reduce the cost of the final product. In order to improve low-temperature and adsorption properties of developed dust suppressants, heavy oil residues (cracking residue and tar) are included in their composition in various concentrations: 2-10 wt.%. Alternative compositions of dust suppressants, obtained by water emulsification of vinylated alkyd oligomer, are developed; the ability of this dispersion to form strong films on dusty surfaces is examined. The efficiency of using aqueous solution of vinylated alkyd oligomer as a summer dust suppressant is demonstrated. The results of this study include the development of new preventive compositions with improved low-temperature properties and confirmation of the theoretical part of the study by the results of performance tests on a laboratory facility.Alternative compositions of dust suppressors have been developed, which were obtained by emulsifying a vinyl alkyd oligomer (VAO) in water; the ability of this dispersion to form strong films on dusty surfaces has been studied. The efficiency of using an aqueous solution of vinyl alkyd oligomer in the summer period as a dust suppressant is shown. The results of this study are the development of new prophylactic formulations with improved low-temperature properties and confirmation of the theoretical part of the study by the results of tests of operational characteristics in a laboratory facility.


Author(s):  
Igor' Kuzora ◽  
Elena Simonova ◽  
Stepan Uhanev

The physicochemical and chemmotological characteristics of bottom sediment oil sludge were studied to determine the optimal processing conditions. The possibility of obtaining light distillates using the thermal method of exposure to oil sludge is investigated. A variant of the involve ment of bottom sediments in the installation of delayed coking is proposed


Author(s):  
Igor' Kuzora ◽  
Elena Simonova ◽  
Stepan Uhanev

The physicochemical and chemmotological characteristics of oil sludge from treat ment facilities were studied to determine the optimal conditions for their dewatering. The possibility of using them as a component in various fuel compositions is investigated.


2021 ◽  
Vol 73 (1) ◽  
pp. 63-69
Author(s):  
S. S. Satayeva ◽  
◽  
K.A. Mikhailova ◽  

The most urgent in the oil refining industry, along with the deepening of oil refining, are the problems of improving the quality of oil products, which include heavy oil residues, such as bitumen. Despite the widespread use of petroleum bitumen in road construction, the demand for bitumen is not fully satisfied, because the quality of many bituminous materials does not fully meet the modern requirements of the construction industry.Conformance of bitumen obtained by synthetic method for using it in road construction was reviewed in this article. Some main physical and chemical properties of bitumen were described. Received results meet with specification and we can make the conclusion that synthesized bitumen can be used for road surface.


2021 ◽  
Vol 340 ◽  
pp. 01017
Author(s):  
Tatyana Shakiyeva ◽  
Larissa Sassykova ◽  
Anastassiya Khamlenko ◽  
Binara Dossumova ◽  
Albina Sassykova ◽  
...  

The paper describes the catalytic cracking of heavy petroleum feedstock on catalysts based natural Taizhuzgen zeolite and Narynkol clay (Kazakhstan). Catalytic cracking was studied on fuel oil of the M-100 brand taken from the LLP Pavlodar Oil Chemistry Refinery (Kazakhstan). Air was added into the reaction medium. It was found that under optimal conditions, the conversion of the heavy residue of M-100 fuel oil reaches 46.2%, when cracking the initial fuel oil, the yield of the middle distillate fraction is 85.7 wt. % due to the content of 41.1 wt. % residual light gas oil in the resulting products. The optimal composite catalyst allows carry out the cracking of heavy oil residues without preliminary purification and with a high degree ofconversion to diesel fraction.


Author(s):  
Z. A. MANSUROV ◽  
E. K. ONGARBAEV ◽  
G. T. SMAGULOVA ◽  
E. TILEUBERDI ◽  
M. I. BAYKENOV ◽  
...  

2021 ◽  
Vol 29 (5) ◽  
pp. 562-575
Author(s):  
Z. A. MANSUROV ◽  
E. K. ONGARBAEV ◽  
G. T. SMAGULOVA ◽  
E. TILEUBERDI ◽  
M. I. BAYKENOV ◽  
...  

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