Preliminary geothermobarometric and metasomatism studies on mantle xenoliths of kimberlites and associated rocks from the Alto Paranaiba, SE Brazil

Keyword(s):  
Author(s):  
Stefan Bernstein ◽  
C. Kent Brooks

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Bernstein, S., & Brooks, C. K. (1998). Mantle xenoliths from Tertiary lavas and dykes on Ubekendt Ejland, West Greenland. Geology of Greenland Survey Bulletin, 180, 152-154. https://doi.org/10.34194/ggub.v180.5099 _______________ Mantle xenoliths were found in Tertiary alkaline (basanitic) lavas on Ubekendt Ejland in West Greenland in the mid 1970s by J.G. Larsen. Microprobe analyses of olivine, pyroxene and spinel in two mantle xenoliths, suggested that the xenoliths on Ubekendt Ejland are highly depleted and have high modal olivine contents, and low modal orthopyroxene and clinopyroxene (Larsen 1982). In this respect the mantle xenoliths from Ubekendt Ejland are very similar to the spinel harzburgites from Wiedemann Fjord, in the Tertiary volcanic province of East Greenland (Brooks & Rucklidge 1973; Bernstein et al. 1998). Larsen (1981) also reported dykes containing mantle nodules and a varied suite of cumulates and megacrysts, one of which has subsequently been dated to 34.1 ± 0.2 Ma (Storey et al. 1998) The basalt flow that carries the xenoliths is from what is defined as the Erqua Formation which occurs at the top of the lava succession in western Ubekendt Ejland (Fig. 1; Drever & Game 1948; Larsen 1977a, b). The basalts have not been dated, but are younger than 52.5 Ma, which is the date obtained for the underlying formation (Storey et al. 1998). During July 1997, we spent three weeks collecting xenoliths and prospecting for xenolith-bearing dykes in the Uummannaq district of central West Greenland. The field work resulted in an extensive collection of xenoliths from an alkaline basalt flow described by Larsen (1977a, b), as well as the discovery of a dyke carrying a large number of ultramafic xenoliths of various origins. 


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Costanza Bonadiman ◽  
Valentina Brombin ◽  
Giovanni B. Andreozzi ◽  
Piera Benna ◽  
Massimo Coltorti ◽  
...  

AbstractThe occurrence of phlogopite and amphibole in mantle ultramafic rocks is widely accepted as the modal effect of metasomatism in the upper mantle. However, their simultaneous formation during metasomatic events and the related sub-solidus equilibrium with the peridotite has not been extensively studied. In this work, we discuss the geochemical conditions at which the pargasite-phlogopite assemblage becomes stable, through the investigation of two mantle xenoliths from Mount Leura (Victoria State, Australia) that bear phlogopite and the phlogopite + amphibole (pargasite) pair disseminated in a harzburgite matrix. Combining a mineralogical study and thermodynamic modelling, we predict that the P–T locus of the equilibrium reaction pargasite + forsterite = Na-phlogopite + 2 diopside + spinel, over the range 1.3–3.0 GPa/540–1500 K, yields a negative Clapeyron slope of -0.003 GPa K–1 (on average). The intersection of the P–T locus of supposed equilibrium with the new mantle geotherm calculated in this work allowed us to state that the Mount Leura xenoliths achieved equilibrium at 2.3 GPa /1190 K, that represents a plausible depth of ~ 70 km. Metasomatic K-Na-OH rich fluids stabilize hydrous phases. This has been modelled by the following equilibrium equation: 2 (K,Na)-phlogopite + forsterite = 7/2 enstatite + spinel + fluid (components: Na2O,K2O,H2O). Using quantum-mechanics, semi-empirical potentials, lattice dynamics and observed thermo-elastic data, we concluded that K-Na-OH rich fluids are not effective metasomatic agents to convey alkali species across the upper mantle, as the fluids are highly reactive with the ultramafic system and favour the rapid formation of phlogopite and amphibole. In addition, oxygen fugacity estimates of the Mount Leura mantle xenoliths [Δ(FMQ) = –1.97 ± 0.35; –1.83 ± 0.36] indicate a more reducing mantle environment than what is expected from the occurrence of phlogopite and amphibole in spinel-bearing peridotites. This is accounted for by our model of full molecular dissociation of the fluid and incorporation of the O-H-K-Na species into (OH)-K-Na-bearing mineral phases (phlogopite and amphibole), that leads to a peridotite metasomatized ambient characterized by reduced oxygen fugacity.


2021 ◽  
Vol 41 (3) ◽  
Author(s):  
R. C. Cordeiro ◽  
D. D. dos Santos ◽  
R. E. Santelli ◽  
A. G. Figueiredo ◽  
L. S. Moreira ◽  
...  

2017 ◽  
Vol 579 ◽  
pp. 439-446 ◽  
Author(s):  
Lúcio F. Lourençato ◽  
Pedro P. Caldeira ◽  
Marcelo C. Bernardes ◽  
Andressa C. Buch ◽  
Daniel C. Teixeira ◽  
...  

2013 ◽  
Vol 151 (5) ◽  
pp. 765-776 ◽  
Author(s):  
GI YOUNG JEONG ◽  
CHANG-SIK CHEONG ◽  
KEEWOOK YI ◽  
JEONGMIN KIM ◽  
NAMHOON KIM ◽  
...  

AbstractThe Phanerozoic subduction system of the Korean peninsula is considered to have been activated by at least Middle Permian time. The geochemically arc-like Andong ultramafic complex (AUC) occurring along the border between the Precambrian Yeongnam massif and the Cretaceous Gyeongsang back-arc basin provides a rare opportunity for direct study of the pre-Cretaceous mantle wedge lying above the subduction zone. The tightly constrained SHRIMP U–Pb age of zircons extracted from orthopyroxenite specimens (222.1±1.0 Ma) is indistinguishable from the Ar/Ar age of coexisting phlogopite (220±6 Ma). These ages represent the timing of suprasubduction zone magmatism likely in response to the sinking of cold and dense oceanic lithosphere and the resultant extensional strain regime in a nascent arc environment. The nearly coeval occurrence of a syenite-gabbro-monzonite suite in the SW Yeongnam massif also suggests an extensional tectonic setting along the continental margin side during Late Triassic time. The relatively enriched ɛHf range of dated zircons (+6.2 to −0.6 at 222 Ma) is in contrast to previously reported primitive Sr–Nd–Hf isotopic features of Cenozoic mantle xenoliths from Korea and eastern China. This enrichment is not ascribed to contamination by the hypothetical Palaeozoic crust beneath SE Korea, but is instead attributable to metasomatism of the lithospheric mantle during the earlier subduction of the palaeo-Pacific plate. Most AUC zircons show a restricted core-to-rim spread of ɛHf values, but some grains testify to the operation of open-system processes during magmatic differentiation.


Lithos ◽  
2007 ◽  
Vol 96 (1-2) ◽  
pp. 108-126 ◽  
Author(s):  
Yang Chen ◽  
Youxue Zhang ◽  
David Graham ◽  
Shangguo Su ◽  
Jinfu Deng

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