scholarly journals Diamond formation and mantle metasomatism: a trace element perspective

2019 ◽  
Keyword(s):  
Trace Element ◽  
Mantle Metasomatism ◽  
Diamond Formation

Mantle metasomatism: Isotope and trace-element trends in xenoliths from Kimberley, South Africa

1990 ◽  
Vol 85 (1-2) ◽  
pp. 19-34 ◽  
Author(s):  
C.J. Hawkesworth ◽  
A.J. Erlank ◽  
P.D. Kempton ◽  
F.G. Waters
Keyword(s):  
South Africa ◽  
Trace Element ◽  
Mantle Metasomatism

Isotopic analyses of clinopyroxene in mantle xenoliths demonstrate the effects of kimberlite melt metasomatism upon the lithospheric mantle

2020 ◽  
Author(s):  
Angus Fitzpayne ◽  
Andrea Giuliani ◽  
Janet Hergt ◽  
Jon Woodhead ◽  
Roland Maas
Keyword(s):  
Trace Element ◽  
Lithospheric Mantle ◽  
Mantle Metasomatism ◽  
Mantle Xenoliths ◽  
Isotopic Compositions ◽  
Isotopic Analyses ◽  
Cretaceous Magmatism

<p>As clinopyroxene is the main host of most lithophile elements in the lithospheric mantle, the trace element and radiogenic isotope systematics of this mineral have frequently been used to characterise mantle metasomatic processes. To further our understanding of mantle metasomatism, both solution-mode Sr-Nd-Hf-Pb and in situ trace element and Sr isotopic data have been acquired for clinopyroxene grains from a suite of peridotite (lherzolites and wehrlites), MARID (Mica-Amphibole-Rutile-Ilmenite-Diopside), and PIC (Phlogopite-Ilmenite-Clinopyroxene) rocks from the Kimberley kimberlites (South Africa). The studied mantle samples can be divided into two groups on the basis of their clinopyroxene trace element compositions, and this subdivision is reinforced by their isotopic ratios. Type 1 clinopyroxene, which comprises PIC, wehrlite, and some sheared lherzolite samples, is characterised by low Sr (~100–200 ppm) and LREE concentrations, moderate HFSE contents (e.g., ~40–75 ppm Zr; La/Zr < 0.04), and restricted isotopic compositions (e.g., <sup>87</sup>Sr/<sup>86</sup>Sr<sub>i</sub> = 0.70369–0.70383; εNd<sub>i</sub> = +3.1 to +3.6) resembling those of their host kimberlite magmas. Available trace element partition coefficients can be used to show that Type 1 clinopyroxenes are close to equilibrium with kimberlite melt compositions, supporting a genetic link between kimberlites and these metasomatised lithologies. Thermobarometric estimates for Type 1 samples indicate equilibration depths of 135–155 km within the lithosphere, thus showing that kimberlite melt metasomatism is prevalent in the deeper part of the lithosphere beneath Kimberley. In contrast, Type 2 clinopyroxenes occur in MARID rocks and coarse granular lherzolites, which derive from shallower depths (<130 km), and have higher Sr (~350–1000 ppm) and LREE contents, corresponding to higher La/Zr of >~0.05. The isotopic compositions of Type 2 clinopyroxenes are more variable and extend from compositions resembling the “enriched mantle” towards those of Type 1 rocks (e.g., εNd<sub>i</sub> = -12.7 to -4.4). To constrain the source of these variations, in situ Sr isotope analyses of clinopyroxene were undertaken, including zoned grains in Type 2 samples. MARID and lherzolite clinopyroxene cores display generally radiogenic but variable <sup>87</sup>Sr/<sup>86</sup>Sr<sub>i</sub> values (0.70526–0.71177), which might be explained by the interaction between peridotite and melts from different enriched sources with the lithospheric mantle. In contrast, the rims of these Type 2 clinopyroxenes trend towards compositions similar to those of the host kimberlite and Type 1 clinopyroxene from PIC and wehrlites. These results are interpreted to represent clinopyroxene overgrowth during late-stage (shortly before/during entrainment) metasomatism by kimberlite magmas. Our study shows that an early, pervasive, alkaline metasomatic event caused MARID and lherzolite genesis in the lithospheric mantle beneath the Kimberley area, which was followed by kimberlite metasomatism during Cretaceous magmatism. This latter event is the time at which discrete PIC, wehrlite, and sheared lherzolite lithologies were formed, and MARID and granular lherzolites were partly modified.</p>

Composition and origin of kelyphitic rims around garnets in fresh sheared lherzolite from the Udachnaya-East kimberlite pipe, the Siberian Craton

2020 ◽  
Author(s):  
Konstantin Solovev ◽  
Igor Sharygin ◽  
Alexander Golovin
Keyword(s):  
Chemical Composition ◽  
Trace Element ◽  
Inductively Coupled Plasma ◽  
Wave Length ◽  
Kimberlite Pipe ◽  
Mantle Metasomatism ◽  
Material Transfer ◽  
Mineral Association ◽  
Russian Science ◽  
Wide Range

<p>A zoned reaction rim (kelyphite) around garnet of xenolith of fresh sheared lherzolite from the Udachnaya-East kimberlite pipe, Russia, has been investigated. The aim of the study is a detailed characterization of bulk major and trace element compositions of the kelyphite zones, kelyphite-forming minerals and theirs relationships with each other and with rock-forming minerals of the lherzolite. <br>There are three point of possible origin of the kelyphite: 1) a solid-solid reaction (between garnets and rock-forming minerals) during transporting to the surface and modifying by a kimberlite melt (introduction of Na, K, Ca and H<sub>2</sub>O into the kelyphite) after reaction, 2) a reaction between garnets and a kimberlite melt, 3) mantle metasomatism.<br>Scanning electron microscopy coupled with energy dispersive spectrometry was used for phase determination and chemical analyses. Chemical composition of large grains (>6 μm) was also examined with wave-length-dispersive spectrometry on electron probe micro-analyzer. Raman spectroscopy was used for phase verification. Bulk trace element composition of reaction rim was studied by laser ablation‐inductively coupled plasma‐mass spectrometry.<br>Garnet forms rounded grains up to 4 mm in size, which are surrounded by the kelyphitic rim. The kelyphite has a concentric structure forming three distinct textural and chemical zones, which are extremely fine-grained aggregates of Cr- and Al-rich orthopyroxene, spinel with a wide range of Cr#, Cr and Al-rich clinopyroxene, amphibole, phlogopite, sodalite and olivine. Veinlets, which traverse the reaction rim and the garnet, are composed of the kelyphite-like mineral aggregate.<br>The kelyphite formation took place after the lherzolite was entrapped by the kimberlite magma during ascent and emplacement. Orthopyroxene, clinopyroxene and spinel were primarily formed (hereafter the first association). Known limits of pressure-temperature stability of sodalite, phlogopite and amphibole suggest their low-pressure crystallization in the kelyphite (hereafter the second association). The kimberlite melt participated in the formation of both the first mineral association and the second mineral association of the kelyphite. Olivine is believed to be result from a reaction between the kimberlite melt and the kelyphite after forming of the first association but before forming of the second association. On the basis of bulk chemical composition for each zone of the kelyphite and chemical composition of the precursor garnet, a material transfer into the kelyphite during the formation was quantitatively evaluated. Introduction of Mg, Fe, Ti and Ca in the kelyphite occured before formation of the second mineral association and introduction of Na, K, Ca, Cl, F and H<sub>2</sub>O due to formation of the second mineral association. Therefore, we can expect that the kimberlite melt was a diffusion agent during formation of the first mineral association (the garnet and rock-forming minerals are considered as reactants) and was a reactant during formation of the second mineral association.<br>This study was supported by the Russian Science Foundation (grant No 18-77-10062).</p>

Metasomatic Processes in the Lithospheric Mantle Beneath the No. 30 Kimberlite (Wafangdian Region, North China Craton)

2019 ◽  
Vol 57 (4) ◽  
pp. 499-517 ◽  
Author(s):  
Ren Z. Zhu ◽  
Pei Ni ◽  
Jun Y. Ding ◽  
Guo G. Wang ◽  
Ming S. Fan ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Trace Element ◽  
North China Craton ◽  
Lithospheric Mantle ◽  
North China ◽  
Compositional Data ◽  
Early Stage ◽  
Mantle Metasomatism ◽  
Element Data

AbstractThis paper presents the first major and trace element compositions of mantle-derived garnet xenocrysts from the diamondiferous No. 30 kimberlite pipe in the Wafangdian region, and these are used to constrain the nature and evolution of mantle metasomatism beneath the North China Craton (NCC). The major element data were acquired using an electron probe micro-analyzer and the trace element data were obtained using laser ablation inductively coupled plasma-mass spectrometry. Based on Ni-in-garnet thermometry, equilibrium temperatures of 1107–1365 °C were estimated for peridotitic garnets xenocrysts from the No. 30 kimberlite, with an average temperature of 1258 °C, and pressures calculated to be between 5.0 and 7.4 GPa. In a CaO versus Cr2O3 diagram, 52% of the garnets fall in the lherzolite field and 28% in the harzburgite field; a few of the garnets are eclogitic. Based on rare earth element patterns, the lherzolitic garnets are further divided into three groups. The compositional variations in garnet xenocrysts reflect two stages of metasomatism: early carbonatite melt/fluid metasomatism and late kimberlite metasomatism. The carbonatite melt/fluids are effective at introducing Sr and the light rare earth elements, but ineffective at transporting much Zr, Ti, Y, or heavy rare earth elements. The kimberlite metasomatic agent is highly effective at element transport, introducing, e.g., Ti, Zr, Y, and the rare earth elements. Combined with compositional data for garnet inclusions in diamonds and megacrysts from the Mengyin and Wafangdian kimberlites, we suggest that these signatures reflect a two-stage evolution of the sub-continental lithospheric mantle (SCLM) beneath the NCC: (1) early-stage carbonatite melt/fluid metasomatism resulting in metasomatic modification of the SCLM and likely associated with diamond crystallization; (2) late-stage kimberlite metasomatism related to the eruption of the 465 Ma kimberlite.

Trace element partitioning between silicate minerals and carbonatite at 25 kbar and application to mantle metasomatism

1992 ◽  
Vol 46 (3) ◽  
pp. 179-184 ◽  
Author(s):  
T. H. Green ◽  
J. Adam ◽  
S. H. Siel
Keyword(s):  
Trace Element ◽  
Mantle Metasomatism ◽  
Trace Element Partitioning ◽  
Silicate Minerals ◽  
Element Partitioning

Conditions for the origin of oxidized carbonate-silicate melts: Implications for mantle metasomatism and diamond formation

Lithos ◽  
2012 ◽  
Vol 128-131 ◽  
pp. 113-125 ◽  
Author(s):  
Y.V. Bataleva ◽  
Y.N. Palyanov ◽  
A.G. Sokol ◽  
Y.M. Borzdov ◽  
G.A. Palyanova
Keyword(s):  
Mantle Metasomatism ◽  
Silicate Melts ◽  
Diamond Formation

Halogen and trace-element chemistry in the Gardar Province, South Greenland: Subduction-related mantle metasomatism and fluid exsolution from alkalic melts

Lithos ◽  
2009 ◽  
Vol 113 (3-4) ◽  
pp. 731-747 ◽  
Author(s):  
Jasmin Köhler ◽  
Johannes Schönenberger ◽  
Brian Upton ◽  
Gregor Markl
Keyword(s):  
Trace Element ◽  
Mantle Metasomatism ◽  
Trace Element Chemistry ◽  
Element Chemistry
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