scholarly journals KARAKTERISTIK PAPAN PARTIKEL DARI LIMBAH KULIT KACANG TANAH DENGAN PEREKAT ALAMI ASAM SITRAT DENGAN PELARUT ASAP CAIR

2018 ◽  
Vol 1 (2) ◽  
Author(s):  
Agus Ngadianto ◽  
Ganis Lukmandaru ◽  
Dhuria Maulidya Sari ◽  
Utari Mardatillah ◽  
Dera Fara Fitria

Binderlessboard is one of the potential eco friendly products that can be developed. Utiliation of natural adhesives for non-wood composite is still very limited. Therefore, this research is focused on effects of citric acid content and pressing time on characteristics of particleboard made from peanut shell including its durability to dry wood termite attacks. Peanut shell particles were used as raw materials. Citric acid dissolved in liquid smoke which functioned as a water substitute solvent under a certain ratio and the concentration of the solution was adjusted to 60%. The use of liquid smoke is expected to increase the durability of the particleboard. Factors used in this research were citric acid content (10-30% based on dry weight particles) and pressing time (10 minutes and 15 minutes). Properties of particleboard were analyed based on Japanese Industrial Standard (JIS) A 5908 for particleboard. The dry wood termite resistance was then analyzed for its weight loss and mortality after 4 weeks. The results showed that the best particleboard was obtained from the treatment of 30% citric acid content with 15 minutes of pressing time where only the modulus of rupture and modulus of elasticity did not met the requirement of JIS A 5908 type 8 with the thickness swelling were 3.276%, water absorption were 44,991%, internal bonding were 4.679 kgf / cm², modulus of rupture were 26.822 kgf / cm², and modulus of elasticity were 8,986,058 kgf / cm². The best value of weight loss and mortality of dry wood termites on particleboard was obtained in a combination of 30% citric acid content with 10 minutes pressing time were 1.083% and 38.67% respectively.

Polymers ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 98
Author(s):  
Zhou Huaxu ◽  
Lee Seng Hua ◽  
Paridah Md Tahir ◽  
Zaidon Ashaari ◽  
Syeed SaifulAzry Osman Al-Edrus ◽  
...  

This study investigated the effects of different citric acid content on the physico-mechanical and biological durability of rubberwood particleboard. Particleboards with density of 700 kg/m3 were produced with three different citric acid contents, namely 10, 15 and 20 wt%. Particleboards made from 10 wt% urea formaldehyde (UF) resin were served as control for comparison purposes. FTIR analysis was carried out and the formation of ester linkages between -OH on cellulose and carbonyl groups of citric acid was confirmed. The peak intensity increased along with increasing citric content, which indicated that a higher amount of ester linkages were formed at higher citric acid content. Citric acid-bonded particleboard had inferior physical properties (water absorption and thickness swelling) and mechanical properties (internal bonding strength, modulus of rupture and modulus of elasticity) compared to that of the UF-bonded particleboard. However, the performance of particleboard was enhanced with increasing citric acid content. Meanwhile, citric acid-bonded particleboard displayed significantly better fungal and termite resistance than UF-bonded particleboard owing to the acidic nature of citric acid. It can be concluded that citric acid is a suitable green binder for particleboard but some improvement is needed during the particleboard production process.


2016 ◽  
Vol 9 (1) ◽  
pp. 12
Author(s):  
Ragil Widyorini ◽  
Ari Puspa Yudha ◽  
Ganis Lukmandaru ◽  
Tibertius Agus Prayitno

Penelitian mengenai penggunaan asam sitrat sebagai agen pengikat alami masih relatif sedikit. Oleh karena itu penelitian ini difokuskan pada pengaruh jumlah asam sitrat dan suhu pengempaan terhadap sifat papan partikel bambu, termasuk ketahanannya terhadap serangan rayap kayu kering. Bahan penelitian adalah partikel bambu petung. Komposisi kimia bahan baku bambu diuji untuk kadar ekstraktif, holoselulosa, lignin, dan alfa selulosa. Faktor pada penelitian ini adalah jumlah asam sitrat (0 - 40%) berdasarkan berat kering udara partikel) dan suhu pengempaan (200 oC dan 220 oC). Sifat fisika dan mekanika papan partikel diuji berdasarkan standar pengujian JIS A 5908. Analisis menggunakan Fourier transform infrared spectroscopy (FTIR) juga dilakukan untuk mengetahui perubahan gugus ester pada berbagai jumlah asam sitrat dan suhu pengempaan. Pengujian ketahanan terhadap serangan rayap kayu kering juga dilakukan dengan menghitung nilai pengurangan berat dan mortalitas rayap setelah 6 minggu. Hasil pengujian menunjukkan bahwa interaksi kedua faktor berpengaruh nyata terhadap nilai pengembangan tebal, penyerapan air, modulus elastisitas dan modulus patah. Intensitas gugus C=O yang ditunjukkan pada puncak 1720 cm-1 semakin bertambah besar seiiring dengan semakin banyaknya jumlah asam sitrat, yang menyebabkan kekuatan perekatan dan stabilitas dimensi papan partikel menjadi semakin kuat. Kondisi optimum pada penelitian ini adalah papan partikel dengan penambahan jumlah asam sitrat 20 % pada suhu pengempaan 200 oC dengan kualitas yang dapat memenuhi standar JIS A 5908 tipe 8. Penambahan asam sitrat dapat meningkatkan mortalitas rayap kayu kering secara nyata. Penambahan 20 % asam sitrat pada suhu pengempaan 200 oC menghasilkan nilai pengurangan berat 0,9 % dan mortalitas rayap 57 %.Kata kunci: bambu petung, asam sitrat, suhu pengempaan, jumlah asam sitrat. Mechanical properties and durability against the dry termite attacks of particleboard made from bamboo with citric acid as adhesive AbstractResearch on development of citric acid as natural adhesive are still limited. Therefore this research focused on effects of citric acid content and pressing temperature on properties of particleboard made from bamboo, including its durability to the dry termite attacks. Petung bamboo particles were used as raw materials. Chemical characteristics of petung bamboo were analyzed for its extractive, lignin, holocellulose and alpha cellulose. Factors used in this research were citric acid content (0 - 40 %) based on dry weight particles and pressing temperature (200 oC dan 220 oC). Properties of the particleboard were analyzed based on Japanese Industrial Standard (JIS) A 5908 for particleboard. Fourier transform infrared spectroscopy (FTIR) analysis was used for investigating the changes of ester groups at various citric acid content and pressing temperature. The dry termite resistance was then analyzed for its weight loss and mortality after 6 weeks. The results showed that interaction between two factors affected significantly on thickness swelling, water absorption, modulus of elasticity, and modulus of rupture. Intensity of C=O groups became stronger as increasing citric acid content, providing high mechanical properties and high dimensional stability. Optimum condition in this research was achieved at 20 % of citric acid content and 200 oC of pressing temperature, which the board properties met the requirement of JIS A 5908 type 8. Increasing of citric acid content would also increase the dry termite mortality. Addition of 20 % citric acid at 200 oC of pressing temperature produced particleboard with the weight loss was 0.9 % and 57 % of the dry termite mortality. 


1921 ◽  
Vol 48 (2) ◽  
pp. 453-461
Author(s):  
G.C. Supplee ◽  
B. Bellis

1918 ◽  
Vol 35 (2) ◽  
pp. 313-318
Author(s):  
H.H. Sommer ◽  
E.B. Hart

1964 ◽  
Vol 116 (3) ◽  
pp. 622-623 ◽  
Author(s):  
F. D. Griffith ◽  
H. E. Parker ◽  
J. C. Rogler

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