scholarly journals SOME ISSUES OF THE MECHANISM OF DEEP OXIDATION OF ETHANOL ON THE SURFACE OF THE CATALYST OF A THERMOCATALYTIC SENSOR

Author(s):  
Z. Murodova ◽  
M. Hushvaktov ◽  
Z. Abdurahmanova

In this work, the effect of the partial pressures of the starting materials and reaction products on the patterns of deep oxidation of ethanol on the surface of the catalyst of the thermocatalytic sensor was studied experimentally. At the same time, the regularities of the oxidation of combustible substances on selected catalysts have been established and the optimal conditions have been identified that ensure the flow of the process under study in the kinetic region. It is shown that the reaction on the sensor catalyst surface proceeds along two kinetically independent (basic) routes. Taking into account the above, a more detailed scheme of the heterogeneous catalytic oxidation of ethanol in the presence of a sensor catalyst is proposed.

1988 ◽  
Vol 36 (2) ◽  
pp. 301-305 ◽  
Author(s):  
P. A. Awasarkar ◽  
A. Y. Sonsale ◽  
A. K. Chatterjee

1990 ◽  
Vol 45 (4) ◽  
pp. 955-964 ◽  
Author(s):  
H. Engel-Herbert ◽  
P.J. Plath ◽  
R. Ottensmeyer ◽  
Th. Schnelle ◽  
J. Kaldasch

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Tao Gan ◽  
Jingxiu Yang ◽  
David Morris ◽  
Xuefeng Chu ◽  
Peng Zhang ◽  
...  

AbstractActivation of O2 is a critical step in heterogeneous catalytic oxidation. Here, the concept of increased electron donors induced by nitrogen vacancy is adopted to propose an efficient strategy to develop highly active and stable catalysts for molecular O2 activation. Carbon nitride with nitrogen vacancies is prepared to serve as a support as well as electron sink to construct a synergistic catalyst with Pt nanoparticles. Extensive characterizations combined with the first-principles calculations reveal that nitrogen vacancies with excess electrons could effectively stabilize metallic Pt nanoparticles by strong p-d coupling. The Pt atoms and the dangling carbon atoms surround the vacancy can synergistically donate electrons to the antibonding orbital of the adsorbed O2. This synergistic catalyst shows great enhancement of catalytic performance and durability in toluene oxidation. The introduction of electron-rich non-oxide substrate is an innovative strategy to develop active Pt-based oxidation catalysts, which could be conceivably extended to a variety of metal-based catalysts for catalytic oxidation.


2003 ◽  
Vol 91 (9) ◽  
Author(s):  
A. V. Ananiev ◽  
V.P. Shilov ◽  
Ph. Moisy ◽  
Charles Madic

SummaryNeptunium(IV), being quite stable in 0.5–3M HNO


Sign in / Sign up

Export Citation Format

Share Document