Here we developed a hot-pressed molded resin-based brake pad material reinforced by a nano sodium titanate whisker in comparison with nano potassium titanate whisker. The effect of the whiskers on the tribology behavior was investigated. Though nano sodium titanate whisker reinforced brake material showed higher porosity (+12.29% averagely) and lower hardness (-25.8% averagely) caused by the impurities, it exhibited improved ability in stabilizing the friction coefficient and enhancing 25.5%, 31.1%, 25.9% higher wear resistance, when the volume contents of whisker are 7.5%, 15% and 22.5%, respectively, compared to the nano potassium titanate whisker reinforced brake material. The wear mechanisms of the nano sodium titanate whisker reinforced brake materials were determined as embedded debris, delaminated crater, moderate layers transfer, uniform furrows, primary plateaus and secondary plateaus in similar size, indicating a main wear form of abrasive wear instead of adhesive wear.