With the rapid development of economic globalization and the increasing international competition, enterprises pay more and more attention to external resources in order to save costs and strengthen their core competitiveness. Thus, the supplier becomes one important competitive factor for manufacturing industry. Combining with the characteristics of the triple-A supply chain, enterprises are helped to evaluate and select suppliers with scientific and effective ways. Firstly, the three characteristics of the triple-A supply chain, including the agility, adaptability and alignment, were analyzed and studied; Secondly, a set of supplier performance evaluation system was designed on the basis of the triple-A supply chain theory, and the weight of index system was designed by using EAHP. Finally, numerical examples show that the selection of superior suppliers is provided a good support by the supplier performance evaluation system based on the triple-A supply chain.