Self-assembly and photocatalytic property of a new inorganic-organic hybrid material based on 1,4-bis(4-pyridylthio)butane

2020 ◽  
Vol 19 (3) ◽  
pp. 227-235
Author(s):  
Yan-Qi Lu
Keyword(s):  
Self Assembly ◽  
Diffuse Reflectance Spectrum ◽  
Photocatalytic Property ◽  
Chain Structure ◽  
Monoclinic Space Group ◽  
Hybrid Compound ◽  
Organic Hybrid ◽  
Uv Visible ◽  
Degradation Effect ◽  
Visible Diffuse Reflectance Spectrum

A new hybrid compound consisting of 1,4-bis(4-pyridylthio)butane ([Bpytb]) ligand, namely {[Bpytb]Ag2I3}n (1), has been prepared and characterized by IR spectroscopy, solid UV-visible diffuse reflectance spectrum, X-ray Powder Diffraction (PXRD) and TG. Compound 1 consists of 1D anion chain structure. Crystal system: Monoclinic, Space group: P2/c, a = 4.5092(3), b = 11.1895(9), c = 21.3893(14), α= 90°, β= 92.907(2)°, γ= 90°, V = 1077.82(13) Å3, Z = 2, Dcalc = 2.693 g cm–3. The photocatalytic property of compound 1 was also studied and it exhibits a better degradation effect on organic dye MB.

One new copper iodide coordination polymer directed by 4-pyridyl dithioether ligand: Syntheses, structures, and photocatalysis

2020 ◽  
Vol 19 (3) ◽  
pp. 217-225
Author(s):  
Gui-Ying Qiao ◽  
Su-Min Li ◽  
Yun-Yin Niu
Keyword(s):  
Diffuse Reflectance ◽  
Reflectance Spectrum ◽  
Diffuse Reflectance Spectrum ◽  
Monoclinic Space Group ◽  
Copper Iodide ◽  
Tetrahedral Configuration ◽  
X Ray ◽  
Uv Visible ◽  
Dithioether Ligand ◽  
Visible Diffuse Reflectance Spectrum

One new compound consisting of 1,1-bis(4-pyridylthio)methylene ([Bpytm]) ligand, namely [Bpytm]CuI (1), has been prepared and characterized by IR spectroscopy, solid Uv-visible diffuse reflectance spectrum, and X-ray Powder Diffraction (PXRD). Compound 1 is a 2D MOF and ligand [Bpytm] coordinate with metal ions to form tetrahedral configuration. For compound 1: Crystal system: Monoclinic, Space group: C2/c, a = 13.6671(11), b = 11.6075(11), c = 17.1225(12), α= 90°, β= 93.707(3)°, γ= 90°, V = 2710.6(4) Å3, Z = 8, Dcalc = 2.082 g cm–3. The photocatalytic properties and thermal stability have been researched.

An organic–inorganic hybrid compound containing imidazolium cations and a one-dimensional lithium hexacyanidocobaltate-based anionic framework

2014 ◽  
Vol 70 (6) ◽  
pp. 603-605 ◽  
Author(s):  
Xiu-Dan Shao ◽  
Chun-Hua Yu
Keyword(s):  
Three Dimensional ◽  
Chain Structure ◽  
Supramolecular Network ◽  
Monoclinic Space Group ◽  
Zigzag Chain ◽  
Imidazolium Chloride ◽  
Hybrid Compound ◽  
Inorganic Hybrid ◽  
One Dimensional ◽  
Imidazolium Cations

An organic–inorganic hybrid compound,catena-poly[bis(3H-imidazol-1-ium) [[tetracyanido-κ4C-cobalt(III)]-μ-cyanido-κ2C:N-[diaqualithium(I)]-μ-cyanido-κ2N:C]], {(C3H5N2)2[CoLi(CN)6(H2O)2]}n, was synthesized by the reaction of Li3[Co(CN)6] with imidazolium chloride in aqueous solution. The compound crystallizes in the monoclinic space groupC2/c(data collected at 273 K). In the crystal structure, neighbouring [Co(CN)6]3−anionic units are linked by Li+cations through the cyanide groups in atransmode, forming a one-dimensional zigzag chain structure extending along thecaxis. A three-dimensional supramolecular network is formed through hydrogen-bonding interactions and is further stabilized by weak CN...π interactions between the cyanide groups and the imidazolium cations.

SYNTHESIS OF CROSS Bi2 WO6 MICROWAFERS WITH ENHANCED PHOTOCATALYTIC ACTIVITY UNDER VISIBLE LIGHT IRRADIATION

2012 ◽  
Vol 19 (01) ◽  
pp. 1250005 ◽  
Author(s):  
GUIZHEN WANG ◽  
GENGPING WAN ◽  
SHIWEI LIN
Keyword(s):  
Electron Microscopy ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Diffuse Reflectance Spectrum ◽  
Orthorhombic Phase ◽  
Transmission Electron ◽  
Light Region ◽  
Uv Visible ◽  
Visible Diffuse Reflectance Spectrum ◽  
Better Than

Novel cross Bi2 WO6 microwafers have been fabricated by a facile acetone-assisted solvothermal method in high quantity. The structure characterizations of the microwafers were investigated in detail by means of X-ray powder diffraction, scanning electron microscopy, and high-resolution transmission electron microscopy. The results indicate that the orthorhombic phase of Bi2 WO6 with high crystallinity can be obtained and each microwafer is polycrystalline in nature and organized by the nanoflake subunits. UV-visible diffuse reflectance spectrum of the prepared Bi2 WO6 microwafers demonstrates that they have absorption in the visible light region. The photocatalytic activity of cross Bi2 WO6 microwafers toward (Rhodamine B) RhB degradation under visible light was investigated, and it was found to be significantly better than that of Bi2 WO6 sample prepared by solid-state reaction (SSR-Bi2 WO6) .

Synthesis, Crystal Structure and Luminescence Properties of the Inorganic-Organic Hybrid Compound [FTMA]2[CdI4] (FTMA = Ferrocenylmethyltrimethylammonium Cation)

2011 ◽  
Vol 66 (5) ◽  
pp. 549-552
Author(s):  
Yan Bai ◽  
Guo Qiang Zhang ◽  
Dong Bin Dang ◽  
Ze Yan Qi ◽  
Li Zhang
Keyword(s):  
Solid State ◽  
Title Compound ◽  
Chain Structure ◽  
Luminescence Properties ◽  
X Ray Diffraction ◽  
Hybrid Compound ◽  
X Ray ◽  
Organic Hybrid ◽  
A Chain ◽  
Distorted Tetrahedral Coordination

The title compound [FTMA]2[CdI4] has been synthesized from [FTMA]I (ferrocenylmethyltrimethylammonium iodide) and 3CdSO4・8H2O and was characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The Cd(II) atom has a slightly distorted tetrahedral coordination sphere. In the solid state there are C-H・ ・ ・π interactions between adjacent ferrocenyl cations to generate a chain structure. The luminescence properties of the title compound were investigated in the solid state at room temperature

Self-assembly of long-chain quaternary ammonium cations in a hybrid inorganic–organic material with one-dimensional polymeric tribromidoplumbate(II)

2012 ◽  
Vol 68 (7) ◽  
pp. m173-m176 ◽  
Author(s):  
Maciej A. Hodorowicz ◽  
Agata Piaskowska ◽  
Katarzyna M. Stadnicka
Keyword(s):  
Quaternary Ammonium ◽  
Self Assembly ◽  
Organic Material ◽  
Group Symmetry ◽  
Monoclinic Space Group ◽  
Space Group Symmetry ◽  
One Dimensional ◽  
Organic Hybrid ◽  
Quaternary Ammonium Cations ◽  
Long Chain

catena-Poly[benzyldecyldimethylammonium [plumbate(II)-tri-μ-bromido]], {(C19H34N)[PbBr3]}n, crystallizes as an inorganic–organic hybrid following monoclinic space-group symmetryP21/c. The structure consists of extended chains running along the [001] direction and built of [PbBr3]−units. These inorganic chains are separated by interdigitated ammonium cations which form hydrophilic layers through weak C—H...Br interactions. The architecture is essentialy the same as found forn-alkylbenzyldimethylammonium bromides.

Micro-Columnar Crystals with (-O=V-Pd-)n Infinite Chain Structures Assembled by Hetero-Dinuclear Metal Complexes

2006 ◽  
Vol 11-12 ◽  
pp. 273-276
Author(s):  
Yasuhiro Funahashi ◽  
Tetsuya Kamimura ◽  
M. Mizutani ◽  
Y. Wasada-Tsutsui ◽  
M. Sakai ◽  
...  
Keyword(s):  
Monomer Unit ◽  
Chain Structure ◽  
Infinite Chain ◽  
Hybrid Compound ◽  
X Ray ◽  
Organic Hybrid ◽  
Ir Studies ◽  
Dinuclear Metal Complexes ◽  
X Ray Absorption ◽  
Palladium Ion

The inorganic and organic hybrid compound, [O=VPd(2-Pyd-)4]n (2-Pyd- = 2-pyridonate) (1), was synthesized by assembling its monomer units in the organic solution. X-ray absorption spectroscopic (XAFS) studies indicated that oxidation states of the vanadium and palladium ions in 1 were +IV and +II, and the distance between them was estimated to be 2.698-2.700 Å. Scanning electron microscope (SEM) observation revealed that the compound 1 shapes in long columnar crystals with micrometer-sized cross section. EXAFS and IR studies suggested that the O=V oxygen atom interacted to the central palladium ion in the neighboring monomer unit, forming the inorganic infinite chain structure, -(O=V-Pd)n-, in the columnar crystals of 1.

Synthesis and Crystal Structure of a New Copper(II) Coordination Polymer [CuC16 H18 N4O4S]n*

2012 ◽  
Vol 554-556 ◽  
pp. 268-272
Author(s):  
Jia Gui Li ◽  
Wan Ren Zhu ◽  
Shu Hong Ding ◽  
Yuan Chen ◽  
Yu Lin Zhu ◽  
...  
Keyword(s):  
Self Assembly ◽  
Chain Structure ◽  
Distorted Octahedral Geometry ◽  
Polymeric Chain ◽  
Monoclinic Space Group ◽  
X Ray Diffraction ◽  
Synthesis And Crystal Structure ◽  
One Dimensional ◽  
Cell Parameters ◽  
Distorted Octahedral

A new one-dimensional [CuC16H18N4O4S]n(1) was synthesized by the self-assembly of a ligand 2,5-thiophenediformates, 3,5-dimethylpyrazole and copper(II), and characterized by elemental analysis, IR and single-crystal X-ray diffraction. 1 crystallizes in monoclinic, space group C2/c with unit cell parameters, a=18.6156(4), b=5.96110(10), c= 18.1598(4)Å, =115.467(2)°, Z=4, V=1819.37(7)Å3, Mr = 425.94, Dc = 1.555g/cm3, μ=1.345mm-1, and F(000)= 876. The final R and wR are 0.0328 and 0.0816 for 7611 observed reflections with I>2σ(I). 1 shows an infinite 1-D polymeric chain structure based on the repeated basic units Cu(II)(3,5-dimethylpyrazole)2(2,5-thiophene diformate). The Cu(II)center acts as the joint of the unit, and is coordinated in a slightly distorted octahedral geometry comprised of four O atoms from two different 2,5-thiophenediformate ligands and two N atoms of two trans 3,5-dimethylpyrazole ligands.

A New POM-Based Supramolecular Compound: Synthesis, Structure and Adsorptive Property of [Cu(phen)2]3[W6O19]

2014 ◽  
Vol 919-921 ◽  
pp. 2013-2016 ◽  
Author(s):  
Ya Bing Liu ◽  
Hong Jie Wang ◽  
Hong Kai Zhao
Keyword(s):  
Three Dimensional ◽  
Building Blocks ◽  
Monoclinic Space Group ◽  
X Ray Diffraction ◽  
Hybrid Compound ◽  
Adsorptive Property ◽  
X Ray ◽  
Hydrogen Bonding Interactions ◽  
Compound Synthesis ◽  
Metal Organic

A POM - based organice - inorganic hybrid compound with the chemical formula of[Cu (phen)2]3[W6O19] (phen = 1,10-phenanthroline) (1) has been hydrothermally synthesized andstructurally characterized by the elemental analysis, and single crystal X-ray diffraction. Compound 1 crystallizes in the monoclinic space groupC2/c witha=18.319(4) Å,b= 17.311(4) Å,c= 22.248(4) Å,β= 112.40(3) o,V= 6523(2) Å3,Z= 4, R1= 0.0448, andwR2=0.1218. Compound 1 consists of the [W6O19]3-building blocks and [Cu (phen)2]+metal organic cationic moieties, which are packed together via the extensive hydrogen-bonding interactions to form a three-dimensional supramolecular framework. The adsorption of methylene blue (MB) under UV irradiation with 1 as the heterogeneous adsorbent has been investigated, showing a good adsorptive property of 1 for MB degradation.

scholarly journals 1-(4-Hydroxyphenyl)piperazine-1,4-diium tetrachloridocobalt(II) monohydrate

2014 ◽  
Vol 70 (2) ◽  
pp. m75-m75 ◽  
Author(s):  
Marwa Mghandef ◽  
Habib Boughzala
Keyword(s):  
Hydrogen Bonds ◽  
Water Molecule ◽  
Three Dimensional ◽  
Organic Cations ◽  
Water Molecules ◽  
Asymmetric Unit ◽  
Hybrid Compound ◽  
Organic Hybrid ◽  
Compound C ◽  
Dimensional Network

The asymmetric unit of the title inorganic–organic hybrid compound, (C10H16N2O)[CoCl4]·H2O, consists of a tetrahedral [CoCl4]2−anion, together with a [C10H18N2O]2+cation and a water molecule. Crystal cohesion is achieved through N—H...Cl, O—H...Cl and N—H...O hydrogen bonds between organic cations, inorganic anions and the water molecules, building up a three-dimensional network.

A smart sensing Zn (Ⅱ) coordination polymer based on a new viologen ligand exhibiting photochromic and thermochromic and multiple solid detection properties

2021 ◽  
Author(s):  
Heyi Zhang ◽  
Fangyuan He ◽  
Xiaonan Li ◽  
Zhi-Hui Wang ◽  
Hong Zhang
Keyword(s):  
Electron Transfer ◽  
Coordination Polymer ◽  
Self Assembly ◽  
Chain Structure ◽  
The Self ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Smart Sensing

Through the self-assembly of 1,1'-bis(3-cyanobenzyl)-[4,4'-bipyridine] dichloride ligand, m-H2BDC and Zn(NO3)2·6H2O, a novel one-dimensional chain structure multifunctional coordination polymer was successfully synthesized. Due to electron transfer during irradiation and heating to...

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